Trimethylstannanylium;chloride

Base Information

• Chemical Name: Trimethylstannanylium;chloride
• CAS No.: 1066-45-1
• Molecular Formula: C3H9 Cl Sn
• Molecular Weight: 199.267
• Hs Code.: 2931900090
• Mol file: 1066-45-1.mol

Synonyms:Trimethylstannanylium;chloride;SCHEMBL151358;AKOS032949810;T0958

Chemical Property of Trimethylstannanylium;chloride

Chemical Property:

• Appearance/Colour: WHITE CRYSTALS
• Melting Point: 37-39 °C(lit.)
• Boiling Point: 148
• Flash Point: 207 °F
• PSA: 0.00000
• Density: 0.988 g/mL at 25 °C
• LogP: 2.06010
• Storage Temp.: Poison room
• Sensitive.: Moisture Sensitive
• Water Solubility.: Soluble in water, chloroform and organic solvents.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 199.941481
• Heavy Atom Count: 5
• Complexity: 8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trimethyltin chloride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T+,N,F
• Statements: 26/27/28-50/53-51/53-36/37-19-11-34-40-65-62-48/23/25-36/37/38
• Safety Statements: 28-36/37-45-61-27-26-16-60-62

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Sn+](C)C.[Cl-]
• Uses: Trimethyltin chloride is an organotin reagent widely used in transferring trimethylstannyl groups onto the substrates to synthesize various organostannanes. Trimethylstannyl compounds derived from this reagent, are extensively used in the palladium-catalyzed Stille coupling reactions.

Technology Process of Trimethylstannanylium;chloride

There total 402 articles about Trimethylstannanylium;chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

tris(1,10-phenantholine)iron(III) perchlorate + (t-butyl)trimethylstannane (3531-47-3) + acetonitrile (75-05-8,26809-02-9) → tris(1,10-phenanthroline)iron(II) perchlorate (14586-54-0) + N-tert-butylacetamide (762-84-5) + trimethyltin(IV)chloride (1066-45-1) + isobutene (115-11-7,15220-85-6)

Guidance literature:

With ammonia; In acetonitrile; t-BuSnMe3 in CH3CN added to Fe(phen)3(ClO4)3 in CH3CN at 22°C under Ar and soln. stirred for 2 h, drop water added, Fe(II) complex filtered, filtrate dried with MgSO4 and treated with anhyd. aq. NH3, Sn product treated with HCl and sublimed;

DOI:10.1021/ja00369a030

Reference yield: 55.0%

trimethyl(3-methylphenyl)stannane (937-01-9) + N-methyl-N-phenylformamide (93-61-8) → trimethyltin(IV)chloride (1066-45-1) + m-tolyl aldehyde (620-23-5)

Guidance literature:

With trichlorophosphate; at 50 - 70 ℃; for 3h;

DOI:10.1016/0040-4020(89)80007-9

Reference yield: 51.0%

Pt(Cl)(CH3)2((CH3)3Sn)((C5H4N)2) → dimethyl(2,2'-bipyridine)platinum(II) (52594-52-2) + [PtCl(methyl)(2,2'-bipyridine)] (50726-77-7) + Pt(CH3)3Cl(2,2`-bipyridine) + trimethyltin(IV)chloride (1066-45-1) + tetramethylstannane (594-27-4)

Guidance literature:

In neat (no solvent); NMR tube, 190°C; detd. by (1)H NMR spectroscopyy;

DOI:10.1021/om970204x

upstream raw materials:

diisopropoxyphosphorylsulfenyl chloride

(3-butenyl)trimethylstannane

O,O-dimethylphosphorylsulfenyl chloride

trimethyl(allyl)stannane

Downstream raw materials:

1,1-dimethoxy-3-trimethylstannyl propane

1,1-dimethylcyclohexane

1,3-diphenyl-propen-3-one

(Z)-chalcone

Refernces

Rational synthesis and complexation behavior of the bidentate lewis acid 1,2-bis(chloromercury)ferrocene

10.1021/om0506567

The research focuses on the synthesis and complexation behavior of 1,2-bis(chloromercury)ferrocene (3), a redox-active bidentate Lewis acid. The study introduces a new rational synthesis of 1,2-bis(trimethylstannyl)ferrocene (2), which is converted to 1,2-bis(chloromercury)ferrocene (3) with high yield. Key chemicals involved in the synthesis include p-tolylsulfinylferrocene, tert-butyllithium, trimethyltin chloride, and mercuric chloride. The complexation behavior of 3 with DMSO and chloride anions was explored, yielding complexes that were characterized by X-ray crystallography. The study reveals different binding modes and supramolecular structures influenced by counterions, highlighting the potential of 3 as a versatile precursor for other bidentate Lewis acids and its applications in supramolecular chemistry.

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