Trimethylstannanylium;chloride

Base Information

• Chemical Name: Trimethylstannanylium;chloride
• CAS No.: 1066-45-1
• Molecular Formula: C3H9 Cl Sn
• Molecular Weight: 199.267
• Hs Code.: 2931900090
• Mol file: 1066-45-1.mol

Synonyms:Trimethylstannanylium;chloride;SCHEMBL151358;AKOS032949810;T0958

Chemical Property of Trimethylstannanylium;chloride

Chemical Property:

• Appearance/Colour: WHITE CRYSTALS
• Melting Point: 37-39 °C(lit.)
• Boiling Point: 148
• Flash Point: 207 °F
• PSA: 0.00000
• Density: 0.988 g/mL at 25 °C
• LogP: 2.06010
• Storage Temp.: Poison room
• Sensitive.: Moisture Sensitive
• Water Solubility.: Soluble in water, chloroform and organic solvents.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 199.941481
• Heavy Atom Count: 5
• Complexity: 8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trimethyltin chloride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T+,N,F
• Statements: 26/27/28-50/53-51/53-36/37-19-11-34-40-65-62-48/23/25-36/37/38
• Safety Statements: 28-36/37-45-61-27-26-16-60-62

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Sn+](C)C.[Cl-]
• Uses: Trimethyltin chloride is an organotin reagent widely used in transferring trimethylstannyl groups onto the substrates to synthesize various organostannanes. Trimethylstannyl compounds derived from this reagent, are extensively used in the palladium-catalyzed Stille coupling reactions.

Technology Process of Trimethylstannanylium;chloride

There total 402 articles about Trimethylstannanylium;chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

tris(1,10-phenantholine)iron(III) perchlorate + (t-butyl)trimethylstannane (3531-47-3) + acetonitrile (75-05-8,26809-02-9) → tris(1,10-phenanthroline)iron(II) perchlorate (14586-54-0) + N-tert-butylacetamide (762-84-5) + trimethyltin(IV)chloride (1066-45-1) + isobutene (115-11-7,15220-85-6)

Guidance literature:

With ammonia; In acetonitrile; t-BuSnMe3 in CH3CN added to Fe(phen)3(ClO4)3 in CH3CN at 22°C under Ar and soln. stirred for 2 h, drop water added, Fe(II) complex filtered, filtrate dried with MgSO4 and treated with anhyd. aq. NH3, Sn product treated with HCl and sublimed;

DOI:10.1021/ja00369a030

Reference yield: 55.0%

trimethyl(3-methylphenyl)stannane (937-01-9) + N-methyl-N-phenylformamide (93-61-8) → trimethyltin(IV)chloride (1066-45-1) + m-tolyl aldehyde (620-23-5)

Guidance literature:

With trichlorophosphate; at 50 - 70 ℃; for 3h;

DOI:10.1016/0040-4020(89)80007-9

Reference yield: 51.0%

Pt(Cl)(CH3)2((CH3)3Sn)((C5H4N)2) → dimethyl(2,2'-bipyridine)platinum(II) (52594-52-2) + [PtCl(methyl)(2,2'-bipyridine)] (50726-77-7) + Pt(CH3)3Cl(2,2`-bipyridine) + trimethyltin(IV)chloride (1066-45-1) + tetramethylstannane (594-27-4)

Guidance literature:

In neat (no solvent); NMR tube, 190°C; detd. by (1)H NMR spectroscopyy;

DOI:10.1021/om970204x

upstream raw materials:

diisopropoxyphosphorylsulfenyl chloride

(3-butenyl)trimethylstannane

O,O-dimethylphosphorylsulfenyl chloride

trimethyl(allyl)stannane

Downstream raw materials:

N-Methyl-N-<4-(trimethylstannyl)-1,3-butadiinyl>anilin

1,3-diphenyl-propen-3-one

(Z)-chalcone

2-chloro-1-propanol

Refernces

• 1、 Grant,van Wazer. "". . p. 229. Retrieved 1965.
• 2、 Kosugi et al.. "". . p. C11,C12. Retrieved 1973.
• 3、 Seyferth,White. "". . p. 317. Retrieved 1971.
• 4、 Blaukat,Neumann. "". . p. 323,328,331. Retrieved 1973.
• 5、 Seyferth,Jula. "-". . p. 2938. Retrieved 1968.
• 6、 Abraham, M. H.,Behbahany, F.,Hogarth, M. J.. "". . . Retrieved 1971.
• 7、 Sakurai, H.,Tominaga, K.,Watanabe, T.,Kumada, M.. "". . . Retrieved 1966.
• 8、 Kuivila et al.. "". . p. 6696. Retrieved 1970.
• 9、 Fukuzumi, S.,Kochi, J. K.. "Donor-Acceptor Complexes of Organometals and Iodine. Alkyl Ligands as Probes for Steric Effects in Charge Transfer". . p. 608 - 616. Retrieved 1980.
• 10、 Kuivila, H. G.,Verdone, J. A.. "". . . Retrieved 1964.