2-[(E)-2-(4-methoxyphenyl)ethenyl]-5,5-dimethyl-1,3,2-dioxaborinane

Base Information

Chemical Name:2-[(E)-2-(4-methoxyphenyl)ethenyl]-5,5-dimethyl-1,3,2-dioxaborinane
CAS No.:905966-49-6
Molecular Formula:C14H19BO3
Molecular Weight:246.114
Hs Code.:
DSSTox Substance ID:DTXSID901158469
Nikkaji Number:J1.880.443C,J2.473.332G

Synonyms:905966-49-6;DTXSID901158469;(E)-2-(4-Methoxystyryl)-5,5-dimethyl-1,3,2-dioxaborinane;2-[(1E)-2-(4-Methoxyphenyl)ethenyl]-5,5-dimethyl-1,3,2-dioxaborinane

Suppliers and Price of 2-[(E)-2-(4-methoxyphenyl)ethenyl]-5,5-dimethyl-1,3,2-dioxaborinane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-[(E)-2-(4-methoxyphenyl)ethenyl]-5,5-dimethyl-1,3,2-dioxaborinane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:246.1427246
Heavy Atom Count:18
Complexity:273

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OCC(CO1)(C)C)C=CC2=CC=C(C=C2)OC
Isomeric SMILES:B1(OCC(CO1)(C)C)/C=C/C2=CC=C(C=C2)OC

Technology Process of 2-[(E)-2-(4-methoxyphenyl)ethenyl]-5,5-dimethyl-1,3,2-dioxaborinane

There total 4 articles about 2-[(E)-2-(4-methoxyphenyl)ethenyl]-5,5-dimethyl-1,3,2-dioxaborinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 149777-83-3
2-[(E)-2-(4-methoxyphenyl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 201733-56-4
2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane

: 905966-49-6
5,5-dimethyl-2-[β-(4-methoxyphenylethenyl)]-1,3,2-dioxaborinane

Guidance literature:: In methanol; at 90 ℃; for 16h; Schlenk technique; Inert atmosphere;
DOI:10.1039/d1cc05815k

Reference yield:

: 637-69-4,24936-44-5
4-Methoxystyrene

: 201733-56-4
2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane

: 905966-49-6
5,5-dimethyl-2-[β-(4-methoxyphenylethenyl)]-1,3,2-dioxaborinane

Guidance literature:: trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I); In toluene; acetonitrile; at 80 ℃; for 24h;
DOI:10.1039/b211789d

Reference yield:

: 637-69-4,24936-44-5
4-Methoxystyrene

: 201733-56-4
2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane

: (E)-(4-MeOC₆H₄)CHC(B(neopentylglycolato))2

: 905966-49-6
5,5-dimethyl-2-[β-(4-methoxyphenylethenyl)]-1,3,2-dioxaborinane

Guidance literature:: With trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I); In [D₃]acetonitrile; benzene-d6; at 80 ℃; for 48h;
DOI:10.1039/b715584k