1-(t-Butyldimethylsilyloxy)cyclopropanecarbaldehyde

Base Information

Chemical Name:1-(t-Butyldimethylsilyloxy)cyclopropanecarbaldehyde
CAS No.:90660-09-6
Molecular Formula:C₁₀H₂₀O₂Si
Molecular Weight:200.353
Hs Code.:
European Community (EC) Number:837-257-0
DSSTox Substance ID:DTXSID50563933
Nikkaji Number:J1.269.331A
Wikidata:Q82448463
Mol file:90660-09-6.mol

Synonyms:90660-09-6;1-(t-Butyldimethylsilyloxy)cyclopropanecarbaldehyde;1-(TERT-BUTYLDIMETHYLSILYLOXY)CYCLOPROPANECARBALDEHYDE;1-[tert-butyl(dimethyl)silyl]oxycyclopropane-1-carbaldehyde;1-[tert-butyl(dimethyl)silyl]oxycyclopropanecarbaldehyde;SCHEMBL5514379;DTXSID50563933;SB73781;EN300-1692196;Z1269222561;1-{[tert-Butyl(dimethyl)silyl]oxy}cyclopropane-1-carbaldehyde;1-[(TERT-BUTYLDIMETHYLSILYL)OXY]CYCLOPROPANE-1-CARBALDEHYDE

Suppliers and Price of 1-(t-Butyldimethylsilyloxy)cyclopropanecarbaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 1-(t-Butyldimethylsilyloxy)cyclopropanecarbaldehyde

Chemical Property:

PSA：26.30000
LogP:2.73970
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:200.123256411
Heavy Atom Count:13
Complexity:212

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OC1(CC1)C=O

Technology Process of 1-(t-Butyldimethylsilyloxy)cyclopropanecarbaldehyde

There total 3 articles about 1-(t-Butyldimethylsilyloxy)cyclopropanecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 130632-73-4
(1-((tert-butyldimethylsilyl)oxy)cyclopropyl)methanol

: 90660-09-6
1-((tert-butyldimethylsilyl)oxy)cyclopropanecarbaldehyde

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; In tetrahydrofuran; at -78 ℃; for 0.5h;

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 90660-09-6
1-((tert-butyldimethylsilyl)oxy)cyclopropanecarbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: imidazole / dimethylformamide

2: 1.) DIBAH; 2.) oxalyl chloride, dimethylsulfoxide / 1.) toluene, -70 deg C

With 1H-imidazole; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(01)80132-5

Reference yield:

: 90660-08-5
1-(tert-butyl-dimethyl-silanyloxy)-cyclopropanecarboxylic acid methyl ester

: 90660-09-6
1-((tert-butyldimethylsilyl)oxy)cyclopropanecarbaldehyde

Guidance literature:: With oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; Yield given. Multistep reaction; 1.) toluene, -70 deg C;
DOI:10.1016/S0040-4039(01)80132-5