Methyl(diphenyl)silyl trifluoromethanesulfonate

Base Information

Chemical Name:Methyl(diphenyl)silyl trifluoromethanesulfonate
CAS No.:91158-37-1
Molecular Formula:C14H13F3O3SSi
Molecular Weight:346.402
Hs Code.:
DSSTox Substance ID:DTXSID00577666
Wikidata:Q82467739

Synonyms:Methyl(diphenyl)silyl trifluoromethanesulfonate;91158-37-1;SCHEMBL196247;DTXSID00577666;RMMZVIVQUFAVLE-UHFFFAOYSA-N

Suppliers and Price of Methyl(diphenyl)silyl trifluoromethanesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Methyl(diphenyl)silyl trifluoromethanesulfonate

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:4
Exact Mass:346.03067647
Heavy Atom Count:22
Complexity:443

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C1=CC=CC=C1)(C2=CC=CC=C2)OS(=O)(=O)C(F)(F)F

Technology Process of Methyl(diphenyl)silyl trifluoromethanesulfonate

There total 1 articles about Methyl(diphenyl)silyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 122887-63-2
Diphenyl(trifluormethansulfonyloxymethyl)silan

: 91158-37-1
Methyldiphenyl(trifluormethylsulfonyloxy)silan

Guidance literature:: In benzene-d6; at 135 ℃; Rate constant; Mechanism; τ_1/2;

Reference yield: 76.0%

: 52267-51-3
benzyl diazoacetate

: 91158-37-1
Methyldiphenyl(trifluormethylsulfonyloxy)silan

: benzyl 2-methyl(diphenyl)silyl-2-diazoacetate

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In diethyl ether;
DOI:10.1021/ol025911n

Reference yield: 74.0%

: 1746-23-2,26009-55-2
4-tert-Butylstyrene

: 91158-37-1
Methyldiphenyl(trifluormethylsulfonyloxy)silan

: C₂₄H₃₂

: (E)-(4-(tert-butyl)styryl)(methyl)diphenylsilane

Guidance literature:: With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; triethylamine; tricyclohexylphosphine; In 1,4-dioxane; at 75 ℃; for 24h; Inert atmosphere; Glovebox;
DOI:10.1016/j.tet.2014.03.021