1-(Diphenylphosphanyl)-3,3-dimethylbutan-2-one

Base Information

Chemical Name:1-(Diphenylphosphanyl)-3,3-dimethylbutan-2-one
CAS No.:91222-65-0
Molecular Formula:C18H21OP
Molecular Weight:284.338
Hs Code.:
DSSTox Substance ID:DTXSID40514252
Nikkaji Number:J1.579.551D
Wikidata:Q82374459

Synonyms:91222-65-0;1-(Diphenylphosphanyl)-3,3-dimethylbutan-2-one;DTXSID40514252

Suppliers and Price of 1-(Diphenylphosphanyl)-3,3-dimethylbutan-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-(Diphenylphosphanyl)-3,3-dimethylbutan-2-one

Chemical Property:

XLogP3:4.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:5
Exact Mass:284.133002287
Heavy Atom Count:20
Complexity:288

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)C(=O)CP(C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of 1-(Diphenylphosphanyl)-3,3-dimethylbutan-2-one

There total 2 articles about 1-(Diphenylphosphanyl)-3,3-dimethylbutan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 13547-70-1
1-chloro-3,3-dimethyl-butan-2-one

: 96-34-4
methyl chloroacetate

: 91222-65-0
3,3-dimethyl-1-(diphenylphosphino)butan-2-one

Guidance literature:: In toluene; for 2h; Heating;

Reference yield:

: 75-97-8
3,3-dimethyl-butan-2-one

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 91222-65-0
3,3-dimethyl-1-(diphenylphosphino)butan-2-one

Guidance literature:: With d'hexamethyl disilazanylsodium; Yield given. Multistep reaction; 1) ether, -60 deg C, 30 min; 2) ether, -50 deg C;

Reference yield: 95.0%

: tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate

: 91222-65-0
3,3-dimethyl-1-(diphenylphosphino)butan-2-one

: 918134-53-9
(η5-pentamethylcyclopentadienyl)(Ph2PCH2C(t-Bu)O(acetonitrile)ruthenium(II) PF6

Guidance literature:: In dichloromethane; acetonitrile; (Ar), ligand in CH2Cl2 added to Ru complex in cold (-80°C) CH2Cl2and CH3CN, stirred overnight at room temp.; evapd.(vac.), treated with CH2Cl2 and CH3OH, stirred, evapd., treated with CH3OH/Et2O, filtered, washed (Et2O), dried (vac.), elem. anal.;
DOI:10.1002/ejic.200501051