7-Oxabicyclo(2.2.1)hept-2-ene, 5,6-bis(methylene)-

Base Information

Chemical Name:7-Oxabicyclo(2.2.1)hept-2-ene, 5,6-bis(methylene)-
CAS No.:56582-02-6
Molecular Formula:C8H8O
Molecular Weight:120.151
Hs Code.:
DSSTox Substance ID:DTXSID70972023

Synonyms:56582-02-6;5,6-dimethylidene-7-oxabicyclo[2.2.1]hept-2-ene;7-Oxabicyclo[2.2.1]hept-2-ene,5,6-bis(methylene)-;7-Oxabicyclo(2.2.1)hept-2-ene, 5,6-bis(methylene)-;SCHEMBL17203485;DTXSID70972023

Suppliers and Price of 7-Oxabicyclo(2.2.1)hept-2-ene, 5,6-bis(methylene)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 7-Oxabicyclo(2.2.1)hept-2-ene, 5,6-bis(methylene)-

Chemical Property:

Vapor Pressure:1.5mmHg at 25°C
Boiling Point:176°Cat760mmHg
Flash Point:52.9°C
Density:1.04g/cm³
XLogP3:1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:120.057514874
Heavy Atom Count:9
Complexity:191

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=C1C2C=CC(C1=C)O2

Technology Process of 7-Oxabicyclo(2.2.1)hept-2-ene, 5,6-bis(methylene)-

There total 2 articles about 7-Oxabicyclo(2.2.1)hept-2-ene, 5,6-bis(methylene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 5-Chloromethanesulfonyl-6-methylene-7-oxa-bicyclo[2.2.1]hept-2-ene

: 56582-02-6
5,6-dimethylidene-7-oxabicyclo<2.2.1>hept-2-ene

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; Yield given;
DOI:10.1021/ja00166a073

Reference yield:

: 56582-02-6
5,6-dimethylidene-7-oxabicyclo<2.2.1>hept-2-ene

Guidance literature:: Aus Furan, 1)Maleinsaeureanhydrid, 2)LiAlH4, 3)p-Methylbenzolsulfonylchlorid, 4)DMSO/t-ButOK;
DOI:10.1016/S0020-1693(00)87425-3

Reference yield: 50.0%

: 56582-02-6
5,6-dimethylidene-7-oxabicyclo<2.2.1>hept-2-ene

: 15321-51-4
diiron nonacarbonyl

: 17685-52-8
triiron dodecarbonyl

: 13463-40-6,71564-23-3,37220-42-1
iron pentacarbonyl

: 12181-95-2
(orthoquinodimethane)tricarbonyliron

: exo-(2,3-η-5,6-dimethylene-7-oxabicyclo[2.2.1]hept-2-ene)Fe(CO)4

Guidance literature:: With Al₂O₃; In diethyl ether; pentane; Ar-atmosphere; pentane/ether=1:1, 36°C, 2 days; decompg. of Fe3(CO)12 by addn. of acid alumina, filtration, solvent removal, dissoln. in hexane, chromy. (Florisil, hexane contg. 5 vol.% ether), recrystn. (pentane), sublimation; elem. anal.;
DOI:10.1016/S0020-1693(00)87425-3