4-methyl-N-(4-methylphenyl)-N-nitrosoaniline

Base Information

• Chemical Name: 4-methyl-N-(4-methylphenyl)-N-nitrosoaniline
• CAS No.: 6947-35-9
• Molecular Formula: C14H14N2O
• Molecular Weight: 226.278
• Mol file: 6947-35-9.mol

Synonyms:Di-p-tolylamine,N-nitroso- (7CI,8CI);N-Nitrosodi-p-tolylamine;NSC 56928;

Chemical Property of 4-methyl-N-(4-methylphenyl)-N-nitrosoaniline

Chemical Property:

• Vapor Pressure: 1.11E-06mmHg at 25°C
• Refractive Index: 1.568
• Boiling Point: 402.3 °C at 760 mmHg
• Flash Point: 197.1 °C
• Density: 1.06 g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-methyl-N-(4-methylphenyl)-N-nitrosoaniline

There total 5 articles about 4-methyl-N-(4-methylphenyl)-N-nitrosoaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N–methyl–di–p–tolylamine (3480-97-5) → nitroso-di-p-tolyl-amine (6947-35-9)

Guidance literature:

With tert.-butylnitrite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; In 1,4-dioxane; at 20 ℃; for 3h; regioselective reaction;

DOI:10.1039/c7gc02775c

Reference yield: 96.0%

di-p-tolylamine (620-93-9) → nitroso-di-p-tolyl-amine (6947-35-9)

Guidance literature:

With hydrogenchloride; sodium nitrite; In methanol; water; Cooling with ice;

DOI:10.3184/174751913X13718370656320

Reference yield:

tetrakis(4-methylphenyl)hydrazine (1807-53-0) → nitroso-di-p-tolyl-amine (6947-35-9)

Guidance literature:

With nitrogen oxides; toluene; at 90 - 95 ℃;

upstream raw materials:

di-p-tolylamine

tetrakis(4-methylphenyl)hydrazine

toluene

N–methyl–di–p–tolylamine

Downstream raw materials:

N'-phenyl-N,N-di-p-tolyl-hydrazine

1,2,1',2'-tetraphenyl-[3,3']azoindole

di-p-tolylamine

N-picryl-N',N'-di-p-tolyl-hydrazine