Tripiperidinophosphine oxide

Base Information

• Chemical Name: Tripiperidinophosphine oxide
• CAS No.: 4441-17-2
• Molecular Formula: C15H30N3OP
• Molecular Weight: 299.396
• Hs Code.: 2933399090
• European Community (EC) Number: 224-663-2
• UNII: 50YL4KP63A
• DSSTox Substance ID: DTXSID7063471
• Nikkaji Number: J2.213F
• Wikidata: Q27260835
• Mol file: 4441-17-2.mol

Synonyms:Tripiperidinophosphine oxide;4441-17-2;Tripiperidinephosphine oxide;1-di(piperidin-1-yl)phosphorylpiperidine;Piperidine, 1,1',1''-phosphinylidynetris-;Phosphine oxide, tripiperidino-;1,1',1''-Phosphinoylidynetripiperidine;EINECS 224-663-2;BRN 0234993;UNII-50YL4KP63A;50YL4KP63A;Piperidine, 1,1',1''-phosphinylidynetri-;tri(piperidino)phosphine oxide;C15H30N3OP;SCHEMBL1276982;tri-1-Piperidinophosphine oxide;DTXSID7063471;CPKHPYQIXCUKQJ-UHFFFAOYSA-;1,1',1''-phosphoryltripiperidine;C15-H30-N3-O-P;STL503707;AKOS037487888;TRIPIPERIDINOPHOSPHORIC TRIAMIDE;LS-106045;1-[Di(1-piperidinyl)phosphoryl]piperidine #;Q27260835

Chemical Property of Tripiperidinophosphine oxide

Chemical Property:

• Melting Point: 75.5°C
• Boiling Point: 434°Cat760mmHg
• Flash Point: 216.3°C
• PSA: 36.60000
• Density: 1.13g/cm³
• LogP: 3.36590
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 299.21264959
• Heavy Atom Count: 20
• Complexity: 293

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Other Nitrogen Compounds
• Canonical SMILES: C1CCN(CC1)P(=O)(N2CCCCC2)N3CCCCC3

Technology Process of Tripiperidinophosphine oxide

There total 5 articles about Tripiperidinophosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

piperidine (110-89-4) → trispiperidinylphosphine oxide (4441-17-2)

Guidance literature:

With trichlorophosphate;

Reference yield:

piperidine (110-89-4) → tetrakis(piperidino)phosphonium chloride + trispiperidinylphosphine oxide (4441-17-2)

Guidance literature:

With phosphorus pentachloride; In chlorobenzene;

Reference yield:

tetrakis(cyclohexylamino)phosphonium hexafluorophosphate(V) → trispiperidinylphosphine oxide (4441-17-2)

Guidance literature:

With potassium hydroxide; at 160 ℃; for 4h; Sealed tube; Inert atmosphere;

DOI:10.1021/acs.organomet.7b00663

upstream raw materials:

piperidine

trichlorophosphate

Refernces

• 1、 Henriques, Margarida S.,Gorbunov, Denis I.,Ponomaryov, Alexey N.,Saneei, Anahid,Pourayoubi, Mehrdad,Du?ek, Michal,Zvyagin, Sergey,Uhlarz, Marc,Wosnitza, Joachim. "A monomeric copper-phosphoramide complex: Synthesis, structure, and electronic properties". . p. 154 - 158. Retrieved 2016.
• 2、 -. "Mixtures comprising tetrakis(pyrrolidino/piperdino)phosphonium salts". . . Retrieved 2008/06/13.