Phosphorodichloridothioic acid, L-alanyl-N-((4-nitrobenzoyl)oxy)-, (6R -(6alpha,7beta(Z)))-

Base Information

• Chemical Name: Phosphorodichloridothioic acid, L-alanyl-N-((4-nitrobenzoyl)oxy)-, (6R -(6alpha,7beta(Z)))-
• CAS No.: 87668-61-9
• Molecular Formula: C₆H₃Cl₄OPS
• Molecular Weight: 295.941
• Mol file: 87668-61-9.mol

Synonyms:2,5-Dichlorophenyl phosphorodichloridothioate;Dcppdct;dichloro-(2,5-dichlorophenoxy)-sulfanylidene;Phosphorodichloridothioic acid,L-alanyl-N-((4-nitrobenzoyl)oxy)-,(6R-(6alpha,7beta(Z)));Dichlorothiophosphorsaeure-O-(2,5-dichlor-phenylester);dichlorothiophosphoric acid O-(2,5-dichloro-phenyl ester);

Chemical Property of Phosphorodichloridothioic acid, L-alanyl-N-((4-nitrobenzoyl)oxy)-, (6R -(6alpha,7beta(Z)))-

Chemical Property:

• Vapor Pressure: 0.000188mmHg at 25°C
• Boiling Point: 338.8°Cat760mmHg
• Flash Point: 158.7°C
• PSA: 51.13000
• Density: 1.685g/cm³
• LogP: 5.72490

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phosphorodichloridothioic acid, L-alanyl-N-((4-nitrobenzoyl)oxy)-, (6R -(6alpha,7beta(Z)))-

There total 3 articles about Phosphorodichloridothioic acid, L-alanyl-N-((4-nitrobenzoyl)oxy)-, (6R -(6alpha,7beta(Z)))- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

2,5-dichlorophenyl phosphorodichloridate (53676-18-9) → 2,5-dichlorophenyl phosphorodichloridothioate (87668-61-9)

Guidance literature:

With trichlorothiophosphine; sulfur;

DOI:10.1039/c39830000591

Reference yield:

2,5-dichlorophenyl phosphorodichloridate (141625-92-5) → 2,5-dichlorophenyl phosphorodichloridothioate (87668-61-9)

Guidance literature:

With trichlorothiophosphine;

DOI:10.1021/jo01105a025

Reference yield:

2,5-dichlorophenol (583-78-8) → 2,5-dichlorophenyl phosphorodichloridothioate (87668-61-9)

Guidance literature:

Multi-step reaction with 2 steps

1: phosphorus (III)-chloride / anschliessend Erwaermen mit wenig Magnesiumchlorid

2: thiophosphoryl chloride

With trichlorothiophosphine; phosphorus trichloride;

DOI:10.1021/jo01105a025

upstream raw materials:

2,5-dichlorophenyl phosphorodichloridate

2,5-dichlorophenyl phosphorodichloridate

2,5-dichlorophenol

Downstream raw materials:

2,5-dichlorophenyl bis<6-(trifluoromethyl)benzotriazolyl> phosphorothioate

<(2',3',4',6'-tetra-O-acetyl-1'-thio-β-D-galactopyranosyl)oxy>ethyl 11-(5-cholesten-3β-yloxy)-3,6,9-trioxaundecanyl 2,5-dichlorophenyl phosphorothioate

<(2',3',4',6'-tetra-O-acetyl-1'-thio-β-D-galactopyranosyl)oxy>-3,6-dioxaoctyl 11-(5-cholesten-3β-yloxy)-3,6,9-trioxaundecanyl 2,5-dichlorophenyl phosphorothioate