1,1'':1',1'''-Biferrocene

Base Information

Chemical Name:1,1'':1',1'''-Biferrocene
CAS No.:11105-90-1
Molecular Formula:C₂₀H₁₆Fe₂
Molecular Weight:368.041
Hs Code.:

Synonyms:1,1'':1',1'''-Biferrocene

Suppliers and Price of 1,1'':1',1'''-Biferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 1,1'':1',1'''-Biferrocene

Chemical Property:

Vapor Pressure:0.127mmHg at 25°C
Boiling Point:225.8°C at 760 mmHg
Flash Point:64.9°C
PSA：0.00000
LogP:3.33580
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:0
Exact Mass:367.995072
Heavy Atom Count:22
Complexity:364

Purity/Quality:: 98%,99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[CH-]1[CH-][CH-][C-]([CH-]1)[C-]2C=CC=C2.C1=C[C-](C=C1)[C-]2C=CC=C2.[Fe].[Fe]

Technology Process of 1,1'':1',1'''-Biferrocene

There total 4 articles about 1,1'':1',1'''-Biferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 12145-93-6
1,1'-diiodoferrocene

: 11105-90-1
bis(μ-fulvalenediyl)diiron

Guidance literature:: With copper; biphenyl; In hexane; mixt. of Fe complex, Cu powder and biphenyl heated at 180°C for 18 h; filtered hot into n-hexane; filtered; ppt. purified by sublimation (240°C, 0.07 mbar); elem. anal.;
DOI:10.1021/om201215w

Reference yield: 20.0%

: 1012789-83-1
2,4-dimethylpentadienyl potassium

: 62228-12-0
C₁₀H₈^(2-)

: iron(II) chloride

: 102-54-5,55404-68-7
ferrocene

: 11105-90-1
bis(μ-fulvalenediyl)diiron

: (η(5)-cyclopentadienyl)(η(5)-2,4,-dimethylpentadienyl)iron

: bis(η(5)-2,4,-dimethylpentadienyl)iron

: 250288-62-1
[Fe(C₇H₁₁)]2(C₁₀H₈)

Guidance literature:: In tetrahydrofuran; N2-atmosphere; addn. of equimolar mixt. of ligands to FeCl2 (-78°C), slow warming to room temp., stirring for 1 h; solvent removal (vac.), extn. into hexane, filtration, solvent removal (vac.), chromy. (Al2O3, 2% THF in hexane);
DOI:10.1016/S0022-328X(99)00270-3