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1,1'-diiodoferrocene, also known as bis(1,1'-diiodoferrocene), is an organometallic compound that features a ferrocene core with two iodine atoms attached to the cyclopentadienyl rings. 1,1'-diiodoferrocene is recognized for its unique properties, including significant steric hindrance and electron density on the ferrocene core, which makes it a versatile building block in the synthesis of various organometallic complexes and polymers. It is also a valuable source of ferrocene-derived ligands for transition metal-catalyzed reactions, facilitating the formation of new C-C and C-X bonds.

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  • 12145-93-6 Structure
  • Basic information

    1. Product Name: 1,1'-diiodoferrocene
    2. Synonyms: 1,1'-diiodoferrocene
    3. CAS NO:12145-93-6
    4. Molecular Formula:
    5. Molecular Weight: 437.83
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 12145-93-6.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1,1'-diiodoferrocene(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1,1'-diiodoferrocene(12145-93-6)
    11. EPA Substance Registry System: 1,1'-diiodoferrocene(12145-93-6)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 12145-93-6(Hazardous Substances Data)

12145-93-6 Usage

Uses

Used in Organic Synthesis:
1,1'-diiodoferrocene is used as a reagent in organic synthesis for its ability to participate in various chemical reactions, contributing to the formation of new compounds and structures.
Used in Catalysis:
In the field of catalysis, 1,1'-diiodoferrocene is used as a catalyst or a catalyst precursor, leveraging its organometallic nature to enhance the efficiency of chemical reactions.
Used in Materials Science:
1,1'-diiodoferrocene is utilized in materials science for the development of new materials, taking advantage of its structural and electronic properties to create innovative polymers and other materials with unique characteristics.
Used in Medicinal Chemistry:
In medicinal chemistry, 1,1'-diiodoferrocene is used as a building block for the synthesis of pharmaceutical compounds, potentially leading to the discovery of new drugs with improved therapeutic properties.
Used in Organometallic Chemistry:
1,1'-diiodoferrocene is employed in organometallic chemistry as a versatile compound for the preparation of organometallic complexes, which are important in various chemical transformations and applications.

Check Digit Verification of cas no

The CAS Registry Mumber 12145-93-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,2,1,4 and 5 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 12145-93:
(7*1)+(6*2)+(5*1)+(4*4)+(3*5)+(2*9)+(1*3)=76
76 % 10 = 6
So 12145-93-6 is a valid CAS Registry Number.

12145-93-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,1'-binaphthalene-2,2'-diyl diacetate

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:12145-93-6 SDS

12145-93-6Relevant articles and documents

Amino ferrocene derivative and organic light emitting diode

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Paragraph 0035; 0037, (2017/07/01)

The invention provides an amino ferrocene derivative. The amino ferrocene derivative is described as in a formula (I) in the specification. In the formula (I), Ar1 and Ar2 are identically or differently selected from substituted or non-substituted aryl groups of C6 to C10. The amino ferrocene derivative provided by the invention can be used as a p-type carrier generation layer in OLED; meanwhile, the OLED connected in series (series type OLED) can obtain the characteristics of high illumination brightness, external quantum efficiency, current efficiency, etc.

Aminoferrocene derivative and tandem organic light-emitting diode containing the same

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Page/Page column 4; 5, (2016/06/28)

An aminoferrocene derivative is represented by the formula (I): wherein Ar1 and Ar2 independently represent a substituted or unsubstituted C6-C10 aryl group. The aminoferrocene derivative is useful for forming a p-type carrier generation layer of a tandem OLED so that the tandem OLED has superior luminous efficiencies in terms of maximum luminance, maximum external quantum efficiency, maximum current efficiency, etc.

Deprotonative metallation of ferrocenes using mixed lithium-zinc and lithium-cadmium combinations

Dayaker, Gandrath,Sreeshailam, Aare,Chevallier, Floris,Roisnel, Thierry,Radha Krishna, Palakodety,Mongin, Florence

, p. 2862 - 2864 (2010/09/03)

A mixed lithium-cadmium amide and a combination of lithium and zinc amides were reacted with a range of ferrocenes; deprotonative mono- or dimetallation in general occurred chemoselectively at room temperature, as evidenced by subsequent quenching with iodine.

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