Tris(triphenylphosphine)ruthenium(II) chloride

Base Information

• Chemical Name: Tris(triphenylphosphine)ruthenium(II) chloride
• CAS No.: 15529-49-4
• Molecular Formula: C₅₄H₄₅Cl₂P₃Ru
• Molecular Weight: 958.849
• Hs Code.: 28439000
• European Community (EC) Number: 239-569-7
• Wikipedia: Dichlorotris(triphenylphosphine)ruthenium(II)
• Mol file: 15529-49-4.mol

Synonyms:15529-49-4;Tris(triphenylphosphine)ruthenium(II) chloride;Dichlorotris(triphenylphosphine)ruthenium(II);Tris(triphenylphosphine)ruthenium(II) dichloride;MFCD00013077;Dichlorotris(triphenylphosphino)ruthenium (II);C54H45Cl2P3Ru;Ruthenium(II)-tris(triphenylphosphine) dichloride;Dichlorotris(triphenylphosphine)ruthenium;C54-H45-Cl2-P3-Ru;Ruthenium, dichlorotris(triphenylphosphine)-;Tris(triphenylphosphine)dichlororuthenium;RuCl2(PPh3)3;Tris(triphenylphosphine)ruthenium(II)Dichloride;WIWBLJMBLGWSIN-UHFFFAOYSA-L;AMY30968;BCP22514;AKOS015914768;GC10037;BP-12227;SY009924;dichlororuthenium;tris(triphenylphosphane);FT-0624728;Tris(triphenylphosphine) ruthenium dichloride;tris(triphenylphosphine)ruthenium(ii)chloride;dichlorotris(triphenylphosphine) ruthenium(ii);Tris(triphenylphosphine) ruthenium(II)chloride;F11906;EN300-7364412;tris(triphenylphosphine)ruthenium (II) dichloride;A809630;tris (triphenylphosphine) ruthenium (11) chloride;tris(triphenylphosphine) ruthenium (II) dichloride;Tris(triphenylphosphine)ruthenium(II) dichloride, 97%;Dichlorotris(triphenylphosphine)ruthenium(II), Premion?;dichlorotris(triphenylphosphine)ruthenium;Tris(triphenylphosphine)ruthenium(II) Dichloride

Chemical Property of Tris(triphenylphosphine)ruthenium(II) chloride

Chemical Property:

• Appearance/Colour: black crystals
• Vapor Pressure: 4.74E-05mmHg at 25°C
• Melting Point: 159 °C
• Boiling Point: 360 °C at 760 mmHg
• Flash Point: 181.7 °C
• PSA: 40.77000
• LogP: 11.71340
• Storage Temp.: Refrigerator
• Sensitive.: Air & Moisture Sensitive
• Solubility.: Very slightly soluble (with dissociation) in acetone, alcohol, c
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 958.115458
• Heavy Atom Count: 60
• Complexity: 204

Purity/Quality:

99% ^*data from raw suppliers

Dichlorotris(triphenylphosphine)ruthenium(II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-20/21
• Safety Statements: 36/37-22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ru]Cl
• Uses: suzuki reaction Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System

Technology Process of Tris(triphenylphosphine)ruthenium(II) chloride

There total 18 articles about Tris(triphenylphosphine)ruthenium(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

rhodium(III) chloride hydrate + triphenylphosphine (603-35-0) → tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4)

Guidance literature:

In ethanol; for 1h; Reflux; Inert atmosphere;

DOI:10.1021/om400461w

Reference yield: 95.0%

ruthenium(III) chloride trihydrate (14898-67-0) + triphenylphosphine (603-35-0) → tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4)

Guidance literature:

In methanol; RuCl3*3H2O and PPh3 refluxed in anhyd. MeOH for 2.5 h; according to L. A. Ortiz-Frade et al., Inorg. Chem., 2003, 42, 1825-1834 and P. S. Hallman et al., Inorg. Synth., 1970, 12, 237-240; decanted; solid loaded on Schlenk frit; washed with ether; dried under vac. overnight;;

DOI:10.1021/ic700580u

Reference yield: 94.0%

ruthenium(III)(H2O)3 chloride (15203-91-5,16904-21-5,13815-94-6,16904-20-4) + triphenylphosphine (603-35-0) → tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4)

Guidance literature:

In methanol; RuCl3(H2O)3 was dissolved in MeOH, PPh3 was added, heated under reflux for 4 h; filtered, washed with Et2O; elem. anal.;

DOI:10.1021/ic025849q

upstream raw materials:

ruthenium trichloride hydrate

triphenylphosphine

ruthenium(III) chloride trihydrate

Ru(PPh₃)(p-CH₃OC₆H₄CH₂NH₂)(p-CH₃OC₆H₄CN)Cl₂

Downstream raw materials:

cis-dichlorobis(triphenylphosphine)platinum(II)

carbonyldihydridotris(triphenylphosphine)ruthenium(II)

RuH(η5-4-tert-butylphenoxide)(PPh3)2

[Ru(η6-4-tert-butylphenol)(PPh3)2]Cl

Refernces

• 1、 Sharma, Sumeet K.,Srivastava, Vivek K.,Jasra, Raksh V.. "Selective double bond isomerization of allyl phenyl ethers catalyzed by ruthenium metal complexes". . p. 200 - 209. Retrieved 2006.
• 2、 Gericke, Robert,Wagler, J?rg. "Ruthenium complexes of diphenylphosphino derivatives of carboxylic amides: Synthesis and characterization of bidentate P,N- and P,O-chelate ligands and their reactivity towards [RuCl2(PPh3)3]". . p. 134 - 141. Retrieved 2016.
• 3、 Zhang,Zheng,Wong,Wong,Leung. "Ruthenium(II) ammine and hydrazine complexes with [N(Ph2PQ)2]- (Q = S, Se) ligands". . p. 5255 - 5264. Retrieved 2000.
• 4、 Oestreich, Martin,Seliger, Jan. "Dynamic Kinetic Resolution of Alcohols by Enantioselective Silylation Enabled by Two Orthogonal Transition-Metal Catalysts". supporting information. p. 247 - 251. Retrieved 2020/10/29.
• 5、 Ribeiro, Gabriel H.,Colina-Vegas, Legna,Clavijo, Juan C.T.,Ellena, Javier,Cominetti, Marcia R.,Batista, Alzir A.. "Ru(II)/N-N/PPh3 complexes as potential anticancer agents against MDA-MB-231 cancer cells (N-N?=?diimine or diamine)". . p. 70 - 83. Retrieved 2019/01/26.