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14898-67-0 Usage

Chemical Properties

dark brown to black powder


Different sources of media describe the Uses of 14898-67-0 differently. You can refer to the following data:
1. Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1
2. Oxidation.Ruthenium(III) chloride hydrate is used as a catalyst for alkyne functionalization and oxidation reactions. It is used as key raw materials for the preparation of various ruthenium-based catalysts, including Grubbs? catalysts. It is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for dehydrogenation of alcohols to the corresponding aldehydes. It is also involved in the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.
3. Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.

General Description

soluble form

Purification Methods

Dissolve the salt in H2O, filter and concentrate to crystallisation in the absence of air to avoid oxidation. Evaporate the solution in a stream of HCl gas while being heated just below its boiling point until a syrup is formed and finally to dryness at 80-100o and dried in a vacuum over H2SO4. When heated at 700o in the presence of Cl2 the insoluble -form is obtained [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1598 1965, Carlsen et al. J Org Chem 46 3936 1981].

Check Digit Verification of cas no

The CAS Registry Mumber 14898-67-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,8,9 and 8 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 14898-67:
150 % 10 = 0
So 14898-67-0 is a valid CAS Registry Number.

14898-67-0 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (43364)  Ruthenium(III) chloride hydrate, Premion?, 99.99% (metals basis)   

  • 14898-67-0

  • 2g

  • 1509.0CNY

  • Detail
  • Alfa Aesar

  • (43364)  Ruthenium(III) chloride hydrate, Premion?, 99.99% (metals basis)   

  • 14898-67-0

  • 10g

  • 6625.0CNY

  • Detail
  • Aldrich

  • (463779)  Ruthenium(III)chloridehydrate  99.98% trace metals basis

  • 14898-67-0

  • 463779-1G

  • 804.96CNY

  • Detail
  • Aldrich

  • (463779)  Ruthenium(III)chloridehydrate  99.98% trace metals basis

  • 14898-67-0

  • 463779-5G

  • 2,782.26CNY

  • Detail
  • Aldrich

  • (206229)  Ruthenium(III)chloridehydrate  ReagentPlus®

  • 14898-67-0

  • 206229-1G

  • 590.85CNY

  • Detail
  • Aldrich

  • (206229)  Ruthenium(III)chloridehydrate  ReagentPlus®

  • 14898-67-0

  • 206229-5G

  • 1,691.82CNY

  • Detail
  • Aldrich

  • (206229)  Ruthenium(III)chloridehydrate  ReagentPlus®

  • 14898-67-0

  • 206229-25G

  • 5,823.09CNY

  • Detail
  • Aldrich

  • (84050)  Ruthenium(III)chloridehydrate  38.0-42.0% Ru basis

  • 14898-67-0

  • 84050-1G-F

  • 1,297.53CNY

  • Detail
  • Aldrich

  • (84050)  Ruthenium(III)chloridehydrate  38.0-42.0% Ru basis

  • 14898-67-0

  • 84050-5G-F

  • 4,154.67CNY

  • Detail



According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017


1.1 GHS Product identifier

Product name Ruthenium(III) chloride hydrate

1.2 Other means of identification

Product number -
Other names Ruthenium trichloride Trichlororuthenium hydrate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14898-67-0 SDS

14898-67-0Relevant articles and documents

Accelerated photorelease of NO from {Ru-NO}6 nitrosyls containing carboxamido-N and carboxylato-O donors: Syntheses, structures, and photochemistry

Halpenny, Genevieve M.,Mascharak, Pradip K.

, p. 1490 - 1497 (2009)

Three ruthenium nitrosyls, namely, [(Me2bpb)Ru(NO)(OAc)], [(Me2bpb)Ru(NO)(OBz)] (1), and [(Me2Qb)Ru-(NO)(qca)] (BF4) (2), have been synthesized from designed ligands with carboxamido-N donors. In all three compl

Synthesis and characterisation of some Ru(II) complexes of 2-carbamoylpyridine derivatives

Dutta, Sujit,Pal, Sarbani,Bhattacharya, Pabitra K.

, p. 2157 - 2162 (2008/10/09)

p-Substituted N-phenyl derivatives of 2-carbamoylpyridine (L) have been prepared by the reaction of pyridine-2-carboxylic acid with p-substituted aniline. Five complexes of the type [Ru(L)(DMSO)2Cl2] have been synthesized by the reaction of [Ru(DMSO)4Cl2] with L. The amide ligands have been characterized by elemental analysis, infra red and 1H NMR spectral studies. The complexes are diamagnetic and show intense absorptions due to metal to ligand charge transfer (MLCT) transitions in the UV-visible spectra. The IR spectra of the complexes show that the amide ligands coordinate to the ruthenium (II) ion as a bidentate ligand coordinating from pyridyl nitrogen and from the carbonyl oxygen of the amide group. The complexes undergo a reversible ruthenium (II)-ruthenium (III) oxidation near 0.55 V in acetonitrile solution. The ruthenium (II)-ruthenium (III) oxidation potentials of the complexes are found to be sensitive to the nature of the substituent on the ligand. Elsevier Science Ltd.

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