14898-67-0

Basic information

• Product Name: Ruthenium(III) chloride
• Synonyms: RutheniuM(III) chloride hydrate ReagentPlus(R);Trichlororuthenium hydrate;Ruthenium(III) chloride hydrateride;Ruthenium(III) chloride hydrate, 99.9% trace metals basis;Ruthenium(III) chloride hydrate, 99.99% trace metals basis;Ruthenium(III) chloride hydrate(1:x);Ruthenium(III) chloride hydrate, PGM basis, Ru 38% min.;RUTHENIUM(+3)CHLORIDE HYDRATE
• CAS NO: 14898-67-0
• Molecular Formula: Cl3Ru
• Molecular Weight: 207.43
• EINECS: 233-167-5
• Product Categories: Ru;straight chain compounds;Catalysis and Inorganic Chemistry;Ru CatalystsMetal and Ceramic Science;Ruthenium;Ruthenium Salts;Salts;Hematology StainsCatalysis and Inorganic Chemistry;Hematology and Histology;Ru Catalysts;metal halide;Catalysis and Inorganic Chemistry;Chemical Synthesis;Materials Science;Metal and Ceramic Science;Ru Catalysts;Ruthenium Salts;chemical reaction,pharm,electronic,materials
• Mol File: 14898-67-0.mol

Chemical Properties

• Melting Point: >300°C
• Appearance: Dark brown to black/Powder
• Density: 3.11 g/cm3
• Storage Temp.: Store at +5°C to +30°C.
• Water Solubility: soluble
• Sensitive: Hygroscopic
• Stability: hygroscopic
• Merck: 14,8302
• CAS DataBase Reference: Ruthenium(III) chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Ruthenium(III) chloride(14898-67-0)
• EPA Substance Registry System: Ruthenium(III) chloride(14898-67-0)

Safety Data

• Hazard Codes: C
• Statements: 34-52/53-22
• Safety Statements: 26-36/37/39-45-61
• RIDADR: UN 3260 8/PG 2
• WGK Germany: 2
• RTECS: VM2650000
• TSCA: Yes
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 14898-67-0(Hazardous Substances Data)

Usage

Chemical Properties

dark brown to black powder

Uses

Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1

Purification Methods

Dissolve the salt in H2O, filter and concentrate to crystallisation in the absence of air to avoid oxidation. Evaporate the solution in a stream of HCl gas while being heated just below its boiling point until a syrup is formed and finally to dryness at 80-100o and dried in a vacuum over H2SO4. When heated at 700o in the presence of Cl2 the insoluble -form is obtained [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1598 1965, Carlsen et al. J Org Chem 46 3936 1981].

InChI:InChI=1S/ClH.xH2O.Ru/h1H;3*1H2;/q;;;;+3/p-1

Upstream product

• 14898-52-3 methyl 3-amino-3-phenylpropanoate 
• 1489-84-5 2,3,4,5,8,9-Hexahydro-1,5-diazecine-6,10(1H,7H)-dione 
• 1489-83-4 1-(3-hydroxypropyl)piperidine-2,6-dione 
• 148983-25-9 Carbamic acid, [(2S)-2,3-dihydroxypropyl]-, 1,1-dimethylethyl ester (9CI) 
• 148983-23-7 Carbamic acid, [(2R)-2,3-dihydroxypropyl]-, 1,1-dimethylethyl ester (9CI) 
• 148983-03-3 (S)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)(methyl)amino)-3-cyclohexylpropanoic acid 
• 148982-08-5 [4-(THIOPHENE-2-CARBONYL)-PHENYL]-THIOPHEN-2-YL-METHANONE 
• 14898-12-5 N-methyl-1-phenyl-N-[3-(trifluoromethyl)benzyl]propan-2-amine hydrochloride (1:1) 
• 14898-11-4 N-(4-fluorobenzyl)-N-methyl-1-phenylpropan-2-amine hydrochloride (1:1) 
• 148981-11-7 1-(4-(3-acetyl-2,4,6-trimethylphenyl)-2,6-cyclohexanedionyl)-O-ethyl propionaldehyde oxime 
• 14898-09-0 1-(4-chlorophenyl)-N-(furan-2-ylmethyl)propan-2-aminium chloride 
• 148980-45-4 N,N-Bis[4-(2-3,4-diMethylphenyl)-(2-phenylvinyl)Phenyl]-2,4,6-TriMethylaniline 
• 148980-31-8 TERBIUM (III) TRIFLUOROMETHANESULFONATE 
• 148980-30-7 BOC-D-PHE-PRO-OSU 

Downstream Products

• 221136-66-9 3-BROMO-6-METHYL-2-OXO-1(2H)-PYRAZINEACETIC ACID ETHYL ESTER 
• 50525-27-4 TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE 
• 50982-12-2 Dichloro(cycloocta-1,5-diene)ruthenium(II) 
• 15529-49-4 Tris(triphenylphosphine)ruthenium(II) chloride