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Ruthenium(III) chloride, a soluble form with chemical properties as a dark brown to black powder, is a transition metal compound that plays a significant role in various chemical reactions and industrial applications.

14898-67-0

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14898-67-0 Usage

Uses

Used in Chemical Synthesis:
Ruthenium(III) chloride is used as a catalyst for the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine. This application is crucial in the production of specific organic compounds, which can be further utilized in different industries.
Used in Oxidation Reactions:
In the field of organic chemistry, Ruthenium(III) chloride hydrate serves as a catalyst for alkyne functionalization and oxidation reactions. Its ability to facilitate these reactions makes it a valuable component in the synthesis of various complex organic molecules.
Used in Catalyst Preparation:
Ruthenium(III) chloride is a key raw material for the preparation of various ruthenium-based catalysts, including the well-known Grubbs' catalysts. These catalysts are essential in promoting specific chemical reactions, enhancing the efficiency and selectivity of the processes.
Used in Dehydrogenation Processes:
Ruthenium(III) chloride is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for the dehydrogenation of alcohols to the corresponding aldehydes. This application is vital in the production of aldehydes, which are important intermediates in the synthesis of various chemicals and pharmaceuticals.

Purification Methods

Dissolve the salt in H2O, filter and concentrate to crystallisation in the absence of air to avoid oxidation. Evaporate the solution in a stream of HCl gas while being heated just below its boiling point until a syrup is formed and finally to dryness at 80-100o and dried in a vacuum over H2SO4. When heated at 700o in the presence of Cl2 the insoluble -form is obtained [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1598 1965, Carlsen et al. J Org Chem 46 3936 1981].

Check Digit Verification of cas no

The CAS Registry Mumber 14898-67-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,8,9 and 8 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 14898-67:
(7*1)+(6*4)+(5*8)+(4*9)+(3*8)+(2*6)+(1*7)=150
150 % 10 = 0
So 14898-67-0 is a valid CAS Registry Number.
InChI:InChI=1S/ClH.xH2O.Ru/h1H;3*1H2;/q;;;;+3/p-1

14898-67-0 Well-known Company Product Price

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  • Alfa Aesar

  • (43364)  Ruthenium(III) chloride hydrate, Premion?, 99.99% (metals basis)   

  • 14898-67-0

  • 2g

  • 1509.0CNY

  • Detail
  • Alfa Aesar

  • (43364)  Ruthenium(III) chloride hydrate, Premion?, 99.99% (metals basis)   

  • 14898-67-0

  • 10g

  • 6625.0CNY

  • Detail
  • Aldrich

  • (463779)  Ruthenium(III)chloridehydrate  99.98% trace metals basis

  • 14898-67-0

  • 463779-1G

  • 804.96CNY

  • Detail
  • Aldrich

  • (463779)  Ruthenium(III)chloridehydrate  99.98% trace metals basis

  • 14898-67-0

  • 463779-5G

  • 2,782.26CNY

  • Detail
  • Aldrich

  • (206229)  Ruthenium(III)chloridehydrate  ReagentPlus®

  • 14898-67-0

  • 206229-1G

  • 590.85CNY

  • Detail
  • Aldrich

  • (206229)  Ruthenium(III)chloridehydrate  ReagentPlus®

  • 14898-67-0

  • 206229-5G

  • 1,691.82CNY

  • Detail
  • Aldrich

  • (206229)  Ruthenium(III)chloridehydrate  ReagentPlus®

  • 14898-67-0

  • 206229-25G

  • 5,823.09CNY

  • Detail
  • Aldrich

  • (84050)  Ruthenium(III)chloridehydrate  38.0-42.0% Ru basis

  • 14898-67-0

  • 84050-1G-F

  • 1,297.53CNY

  • Detail
  • Aldrich

  • (84050)  Ruthenium(III)chloridehydrate  38.0-42.0% Ru basis

  • 14898-67-0

  • 84050-5G-F

  • 4,154.67CNY

  • Detail

14898-67-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Ruthenium(III) chloride hydrate

1.2 Other means of identification

Product number -
Other names Ruthenium trichloride Trichlororuthenium hydrate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14898-67-0 SDS

14898-67-0Relevant articles and documents

Accelerated photorelease of NO from {Ru-NO}6 nitrosyls containing carboxamido-N and carboxylato-O donors: Syntheses, structures, and photochemistry

Halpenny, Genevieve M.,Mascharak, Pradip K.

, p. 1490 - 1497 (2009)

Three ruthenium nitrosyls, namely, [(Me2bpb)Ru(NO)(OAc)], [(Me2bpb)Ru(NO)(OBz)] (1), and [(Me2Qb)Ru-(NO)(qca)] (BF4) (2), have been synthesized from designed ligands with carboxamido-N donors. In all three compl

Ruthenium(0) nanoclusters stabilized by a nanozeolite framework: Isolable, reusable, and green catalyst for the hydrogenation of neat aromatics under mild conditions with the unprecedented catalytic activity and lifetime

Zahmakiran, Mehmet,Tonbul, Yalcin,Oezkar, Saim

, p. 6541 - 6549 (2010)

The hydrogenation of aromatics is a ubiquitous chemical transformation used in both the petrochemical and specialty industry and is important for the generation of clean diesel fuels. Reported herein is the discovery of a superior heterogeneous catalyst, superior in terms of catalytic activity, selectivity, and lifetime in the hydrogenation of aromatics in the solvent-free system under mild conditions (at 25 °C and 42 ± 1 psig initial H2 pressure). Ruthenium(0) nanoclusters stabilized by a nanozeolite framework as a new catalytic material is reproducibly prepared from the borohydride reduction of a colloidal solution of ruthenium(III)-exchanged nanozeolites at room temperature and characterized by using ICP-OES, XRD, XPS, DLS, TEM, HRTEM, TEM/EDX, mid-IR, far-IR, and Raman spectroscopy. The resultant ruthenium(0) nanoclusters hydrogenate neat benzene to cyclohexane with 100% conversion under mild conditions (at 25 °C and 42 ± 1 psig initial H2 pressure) with record catalytic activity (initial TOF = 5430 h-1) and lifetime (TTO = 177 200). They provide exceptional catalytic activity not only in the hydrogenation of neat benzene but also in the solvent-free hydrogenation of methyl substituted aromatics such as toluene, o-xylene, and mesitylene under otherwise identical conditions. Moreover, they are an isolable, bottleable, and reusable catalyst in the hydrogenation of neat aromatics. When the isolated ruthenium(0) nanoclusters are reused, they retain 92% of their initial catalytic activity even for the third run in the hydrogenation of neat benzene under the same conditions as those of the first run. The work reported here also includes (i) far-infrared spectroscopic investigation of nanozeolite, ruthenium(III)-exchanged-nanozeolite, and ruthenium(0) nanoclusters stabilized by a nanozeolite framework, indicating that the host framework remains intact after the formation of a nanozeolite framework stabilized ruthenium(0) nanoclusters; (ii) the poisoning experiments performed by using tricyclohexylphosphine (P(C6H11)3) and 4-ethyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane PC6H 11O3 to examine whether the ruthenium(0) nanoclusters are encapsulated in the cages or supported on the external surface of nanozeolite; (iii) a summary section detailing the main findings for the green chemistry ; and (iv) a review of the extensive literature of benzene hydrogenation, which is also tabulated as part of the Supporting Information.

Synthesis and characterisation of some Ru(II) complexes of 2-carbamoylpyridine derivatives

Dutta, Sujit,Pal, Sarbani,Bhattacharya, Pabitra K.

, p. 2157 - 2162 (2008/10/09)

p-Substituted N-phenyl derivatives of 2-carbamoylpyridine (L) have been prepared by the reaction of pyridine-2-carboxylic acid with p-substituted aniline. Five complexes of the type [Ru(L)(DMSO)2Cl2] have been synthesized by the reaction of [Ru(DMSO)4Cl2] with L. The amide ligands have been characterized by elemental analysis, infra red and 1H NMR spectral studies. The complexes are diamagnetic and show intense absorptions due to metal to ligand charge transfer (MLCT) transitions in the UV-visible spectra. The IR spectra of the complexes show that the amide ligands coordinate to the ruthenium (II) ion as a bidentate ligand coordinating from pyridyl nitrogen and from the carbonyl oxygen of the amide group. The complexes undergo a reversible ruthenium (II)-ruthenium (III) oxidation near 0.55 V in acetonitrile solution. The ruthenium (II)-ruthenium (III) oxidation potentials of the complexes are found to be sensitive to the nature of the substituent on the ligand. Elsevier Science Ltd.

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