Silanol, (1,1-dimethylethyl)diphenyl-

Base Information

• Chemical Name: Silanol, (1,1-dimethylethyl)diphenyl-
• CAS No.: 93547-88-7
• Molecular Formula: C16H20OSi
• Molecular Weight: 256.42
• Mol file: 93547-88-7.mol

Synonyms:

Chemical Property of Silanol, (1,1-dimethylethyl)diphenyl-

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silanol, (1,1-dimethylethyl)diphenyl-

There total 46 articles about Silanol, (1,1-dimethylethyl)diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tert-butylchlorodiphenylsilane (58479-61-1) → t-butyl diphenylsilanol (93547-88-7)

Guidance literature:

With potassium hydroxide; In methanol; diethyl ether; water; at 25 ℃; for 24h;

DOI:10.1021/jo00257a009

Reference yield: 99.0%

tert-butyldiphenylsilane (33729-92-9) → t-butyl diphenylsilanol (93547-88-7)

Guidance literature:

With oxygen; In water; acetone; at 30 ℃; for 8h; under 760.051 Torr;

DOI:10.1246/cl.150379

Reference yield: 99.0%

3-phenyl-2-propenyl-t-butyldiphenylsilane → t-butyl diphenylsilanol (93547-88-7)

Guidance literature:

With 18-crown-6 ether; potassium tert-butylate; dimethyl sulfoxide; at 20 ℃; for 1.33333h;

DOI:10.1246/bcsj.81.623

upstream raw materials:

1,1,3,3,5,5-hexaphenylcyclotrisiloxane

tert.-butyl lithium

(S)-3-(tert-butyl-diphenyl-silanyloxy)-2-methyl-propionic acid methyl ester

methyl 8R-tert-butyldiphenylsilyloxy-9S,11R-dihydroxy-9,11-O-isopropylidene-eicosa-5Z,12E,14Z-trienoate

Downstream raw materials:

[N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediamino](diphenyl-tert-butylsiloxy)scandium(III)

[N,N'-bis(3,5-di-tert-butylsalicylidene)-2,2-dimethylpropylenediamino](diphenyl-tert-butylsiloxy)scandium(III)

NMo(OSi(C₆H₅)2C(CH₃)3)3

benzyl tert-butyldiphenylsilyl ether

Refernces

• 1、 Zhu, Jiefeng,Chen, Shuyou,He, Chuan. "Catalytic Enantioselective Dehydrogenative Si-O Coupling to Access Chiroptical Silicon-Stereogenic Siloxanes and Alkoxysilanes". supporting information. p. 5301 - 5307. Retrieved 2021/05/04.
• 2、 Luo, Nianhua,Liao, Jianhua,Ouyang, Lu,Wen, Huiling,Zhong, Yuhong,Liu, Jitian,Tang, Weiping,Luo, Renshi. "Highly Selective Hydroxylation and Alkoxylation of Silanes: One-Pot Silane Oxidation and Reduction of Aldehydes/Ketones". . p. 165 - 171. Retrieved 2020/01/21.