Silane, (1,1-dimethylethyl)fluorodiphenyl-

Base Information

• Chemical Name: Silane, (1,1-dimethylethyl)fluorodiphenyl-
• CAS No.: 113352-65-1
• Molecular Formula: C16H19FSi
• Molecular Weight: 258.411
• DSSTox Substance ID: DTXSID40440067
• Nikkaji Number: J583.022B
• Wikidata: Q82256246
• Mol file: 113352-65-1.mol

Synonyms:Silane, (1,1-dimethylethyl)fluorodiphenyl-;tert-Butylfluorodiphenylsilane;113352-65-1;diphenyl-t-butyl-fluorosilane;tert-Butyldiphenylfluorosilane;SCHEMBL704604;diphenyl-tert-butyl-fluorosilane;DTXSID40440067

Chemical Property of Silane, (1,1-dimethylethyl)fluorodiphenyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 258.12400530
• Heavy Atom Count: 18
• Complexity: 239

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)[Si](C1=CC=CC=C1)(C2=CC=CC=C2)F

Technology Process of Silane, (1,1-dimethylethyl)fluorodiphenyl-

There total 16 articles about Silane, (1,1-dimethylethyl)fluorodiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

C31H42O3SSi2 (133218-79-8,133319-99-0) → (1'R)-2-(methylenecyclopropyl)ethanol (146142-93-0) + tert-butyl diphenylfluorosilane (113352-65-1)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; Heating;

DOI:10.1016/S0040-4039(00)79488-3

Reference yield: 82.0%

1-(tert-Butyl-diphenyl-silanyloxy)-4-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-benzene (96013-92-2) → tert-butyl diphenylfluorosilane (113352-65-1) + 2-[4'-(tert-butyldiphenylsilyloxy)phenyl]ethanol (96013-93-3)

Guidance literature:

With Selectfluor; In acetonitrile; at 150 ℃; for 0.166667h; chemoselective reaction; Microwave irradiation;

DOI:10.1021/jo802494t

Reference yield: 81.0%

tert-butylchlorodiphenylsilane (58479-61-1) → tert-butyl diphenylfluorosilane (113352-65-1)

Guidance literature:

With ammonium hexafluorosilicate; In 1,2-dimethoxyethane; for 120h; Inert atmosphere; Reflux;

DOI:10.1021/jo200991q

upstream raw materials:

C₃₁H₄₂O₃SSi₂

tert-butylchlorodiphenylsilane

t-butyl diphenylsilanol

(2S)-O-(tert-butyldiphenylsilyl)-1,2-epoxybutan-4-ol

Downstream raw materials:

BrH*C₂₀H₂₇NSi

(S)-2-(tert-butyldiphenylsilyl) pyrrolidine

C₂₇H₃₃NO₂SSi

C₂₃H₃₁NSi