1,6-Dihydroxy-trans,trans-2,4-hexadiene

Base Information

• Chemical Name: 1,6-Dihydroxy-trans,trans-2,4-hexadiene
• CAS No.: 107550-83-4
• Molecular Formula: C6H10 O2
• Molecular Weight: 114.144
• Nikkaji Number: J1.249.086K,J481.393F
• Mol file: 107550-83-4.mol

Synonyms:CCRIS 7059;1,6-Dihydroxy-trans,trans-2,4-hexadiene;(2E,4E)-hexa-2,4-diene-1,6-diol;107550-83-4;trans,trans-1,6-Dihydroxy-2,4-hexadiene;2,4-HEXADIENE-1,6-DIOL;SCHEMBL1077458;(2E,4E)-2,4-Hexadiene-1,6-diol;LS-188954;EN300-1700520

Chemical Property of 1,6-Dihydroxy-trans,trans-2,4-hexadiene

Chemical Property:

• Vapor Pressure: 0.000751mmHg at 25°C
• Boiling Point: 273.1°C at 760 mmHg
• Flash Point: 137.1°C
• Density: 1.039g/cm³
• XLogP3: -0.2
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 114.068079557
• Heavy Atom Count: 8
• Complexity: 72.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C=CC=CCO)O
• Isomeric SMILES: C(O)/C=C/C=C/CO

Technology Process of 1,6-Dihydroxy-trans,trans-2,4-hexadiene

There total 8 articles about 1,6-Dihydroxy-trans,trans-2,4-hexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

diethyl (2E,4E)-2,4-hexadienedioate (6032-74-2) → (2E,4E)-hexa-2,4-diene-1,6-diol (107550-83-4)

Guidance literature:

With diisobutylaluminium hydride; In hexane; dichloromethane; at -78 ℃; for 1h;

DOI:10.1016/S0040-4020(96)00934-9

Reference yield: 93.0%

Hexa-2,4-diyne-1,6-diol (3031-68-3) → (2E,4E)-hexa-2,4-diene-1,6-diol (107550-83-4)

Guidance literature:

With sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; toluene; for 12h; Ambient temperature;

DOI:10.1021/jo970960c

Reference yield: 89.0%

(E,E)-hexa-2,4-dienedioic acid dimethyl ester (1119-43-3) → (2E,4E)-hexa-2,4-diene-1,6-diol (107550-83-4)

Guidance literature:

With diisobutylaluminium hydride; In dichloromethane;

DOI:10.3987/COM-18-S(T)84

upstream raw materials:

Hexa-2,4-diyne-1,6-diol

diethyl (2E,4E)-2,4-hexadienedioate

diethyl ether

(E,E)-muconic acid dichloride

Downstream raw materials:

(2E,4E)-1,6-bis(benzyloxy)hexa-2,4-diene

(2E,4E)-6-(tert-Butyl-diphenyl-silanyloxy)-hexa-2,4-dien-1-ol

all-trans-Octa-1,3,5,7-tetraen-1,8-dicarbonsaeure-diethylester

C₃₈H₄₆O₂Si₂