2-[(Prop-2-en-1-yl)oxy]cyclohexan-1-one

Base Information

• Chemical Name: 2-[(Prop-2-en-1-yl)oxy]cyclohexan-1-one
• CAS No.: 94532-07-7
• Molecular Formula: C9H14O2
• Molecular Weight: 154.209
• DSSTox Substance ID: DTXSID60537226
• Mol file: 94532-07-7.mol

Synonyms:94532-07-7;2-[(Prop-2-en-1-yl)oxy]cyclohexan-1-one;DTXSID60537226

Chemical Property of 2-[(Prop-2-en-1-yl)oxy]cyclohexan-1-one

Chemical Property:

• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 154.099379685
• Heavy Atom Count: 11
• Complexity: 152

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCOC1CCCCC1=O

Technology Process of 2-[(Prop-2-en-1-yl)oxy]cyclohexan-1-one

There total 10 articles about 2-[(Prop-2-en-1-yl)oxy]cyclohexan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

allyl alcohol (107-18-6) + cyclohexanone-2-ol (533-60-8) → α-(prop-2-enyloxy)cyclohexanone (94532-07-7)

Guidance literature:

With Amberlyst 15; In dichloromethane; at 40 ℃; for 48h; chemoselective reaction; Green chemistry;

DOI:10.1039/c7ob02545a

Reference yield: 65.0%

trans-2-hydroxycyclohexyl allyl ether (64832-99-1,81189-45-9) → α-(prop-2-enyloxy)cyclohexanone (94532-07-7)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane; at 20 ℃; for 30h;

DOI:10.1021/jo00377a015

Reference yield: 60.0%

sodium allyloxide (20907-32-8) + 1-nitrocyclohexene oxide (109314-65-0) → α-(prop-2-enyloxy)cyclohexanone (94532-07-7)

Guidance literature:

In various solvent(s); for 0.0333333h; Ambient temperature;

DOI:10.1016/S0040-4020(01)81002-4

upstream raw materials:

trans-2-hydroxycyclohexyl allyl ether

sodium allyloxide

1-nitrocyclohexene oxide

2-(2-bromoprop-2-enyloxy)cyclohexan-1-one

Downstream raw materials:

allyl 2-methylenecyclohexyl ether