Silane, chloromethyl-1-naphthalenylphenyl-, (S)-

Base Information

• Chemical Name: Silane, chloromethyl-1-naphthalenylphenyl-, (S)-
• CAS No.: 960-82-7
• Molecular Formula: C17H15ClSi
• Molecular Weight: 282.845
• Mol file: 960-82-7.mol

Synonyms:(+/-)-Methyl-(1)naphthyl-phenyl-chlorsilan;(+/-)-Methyl-(α-naphthyl)-phenyl-chlorsilan;chloro(1-naphthyl)phenylmethylsilane;Chlor-methyl-(1)naphthyl-phenyl-silan;Methyl-α-naphthyl-phenyl-chlor-silan;(+/-)-α-Naphthyl-phenylmethylchlorsilan;

Chemical Property of Silane, chloromethyl-1-naphthalenylphenyl-, (S)-

Chemical Property:

• PSA: 0.00000
• LogP: 3.76810

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, chloromethyl-1-naphthalenylphenyl-, (S)-

There total 11 articles about Silane, chloromethyl-1-naphthalenylphenyl-, (S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

methoxy(methyl)(1-naphthyl)phenylsilane (3553-88-6,16544-83-5,16952-14-0,18544-02-0) → rac-methyl(1-naphthyl)phenylchlorosilane (960-82-7,13132-42-8,51048-23-8,18142-87-5)

Guidance literature:

With iron(III) chloride; acetyl chloride; In 1,2-dichloro-ethane; for 0.75h;

DOI:10.1021/om300066v

Reference yield:

(S)-(-)-α-naphthylphenylmethylsilane (1025-09-8) → (+)-methylphenylnaphthylchlorosilane (960-82-7,13132-42-8,18142-87-5,51048-23-8)

Guidance literature:

With hydrogenchloride; palladium/alumina;

DOI:10.1021/jo01283a025

Reference yield:

(R)-methyl(1-naphthyl)phenylsilane (1025-08-7) → S(-)-methyl-α-naphthyl-phenyl-chlorosilane (960-82-7)

Guidance literature:

With tetrachloromethane; chlorine;

DOI:10.1021/ja01513a071 DOI:10.1021/ja01070a014

upstream raw materials:

naphthalen-1-yl-lithium

dichloromethylphenylsilane

(-)-α-Naphthylphenylmethylchlorosilane

methoxy(methyl)(1-naphthyl)phenylsilane

Downstream raw materials:

chlorotriethylstannane

(S)-methyl(1-naphthyl)phenylsilyltrimethylstannane

(R)-methyl(1-naphthyl)phenylsilyltrimethylstannane

Methoxy-methyl-naphthalen-1-yl-phenyl-silane