Allyl methyl sulfone

Base Information

• Chemical Name: Allyl methyl sulfone
• CAS No.: 16215-14-8
• Molecular Formula: C4H8 O2 S
• Molecular Weight: 120.172
• Hs Code.: 2904100000
• European Community (EC) Number: 683-350-2
• NSC Number: 403680
• UNII: GRG7826ENB
• DSSTox Substance ID: DTXSID10167315
• Nikkaji Number: J646G
• Wikidata: Q83036664
• Mol file: 16215-14-8.mol

Synonyms:Allyl methyl sulfone;16215-14-8;3-(Methylsulphonyl)-1-propene;3-methylsulfonylprop-1-ene;3-methanesulfonylprop-1-ene;3-(Methylsulfonyl)prop-1-ene;Sulfone, allyl methyl;1-Propene, 3-(methylsulfonyl)-;NSC-403680;3-(Methylsulfonyl)-1-propene;allylmethyl sulfone;methyl allyl sulfone;Allyl methyl sulphone;Sulfone, allyl methy;3-Methanesulfonyl-propene;3-methylsulonylprop-1-ene;Allyl methyl sulfone, 96%;GRG7826ENB;SCHEMBL92901;SCHEMBL12689707;DTXSID10167315;CHEBI:193618;MFCD16295422;NSC403680;AKOS015948434;AT10470;NSC 403680;BS-21628;3,3-DIETHYLBENZIDINEDIHYDROCHLORIDE;CS-0208295;EN300-1987691

Chemical Property of Allyl methyl sulfone

Chemical Property:

• Vapor Pressure: 0.0477mmHg at 25°C
• Melting Point: 87-88 °C(Solv: ethyl acetate (141-78-6))
• Refractive Index: n20/D 1.472
• Boiling Point: 244.3°C at 760 mmHg
• Flash Point: >110°C
• PSA: 42.52000
• Density: 1.171g/mLat 25℃
• LogP: 1.29780
• XLogP3: 0.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 120.02450067
• Heavy Atom Count: 7
• Complexity: 138

Purity/Quality:

98%,99%, ^*data from raw suppliers

Allyl methyl sulfone 96% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 43
• Safety Statements: 36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CS(=O)(=O)CC=C

Technology Process of Allyl methyl sulfone

There total 20 articles about Allyl methyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

allylmethyl sulfide (10152-76-8) → allyl methyl sulfone (16215-14-8)

Guidance literature:

With silica gel; magnesium monoperoxyphthalate hexahydrate; In dichloromethane; for 0.833333h; Heating;

DOI:10.1080/00397919808004877

Reference yield: 92.0%

allylmethylsulfoxide (21892-75-1) → allyl methyl sulfone (16215-14-8)

Guidance literature:

With n-C₄F₉; perfluoro-cis-2,3-dialkyloxaziridine; n-C₃F₇; In chloroform; trichlorofluoromethane; at -20 ℃; for 0.25h;

DOI:10.1021/jo00089a020

Reference yield: 87.0%

allylmethyl sulfide (10152-76-8) → allylmethylsulfoxide (21892-75-1) + allyl methyl sulfone (16215-14-8)

Guidance literature:

With tert.-butylhydroperoxide; [MoO3(2,2′-bipyridine)]_n; In decane; dichloromethane; at 20 ℃; for 1h;

DOI:10.1016/j.catcom.2017.09.022

upstream raw materials:

allylmethyl sulfide

allylmethylsulfoxide

(Z)-methyl 1-propenyl sulfone

methylsulphonylpropyl-1-en

Downstream raw materials:

1-methanesulfonyl-propane-2-sulfonic acid ; sodium-salt

(Z)‐1‐(prop‐2‐enyldisulfanyl)prop‐1‐en

(E)-1-allyl-2-(prop-1-en-1-yl) disulfane

acetaldehyde