2-amino-N-[(3-nitrophenyl)methylideneamino]benzamide

Base Information

• Chemical Name: 2-amino-N-[(3-nitrophenyl)methylideneamino]benzamide
• CAS No.: 28461-50-9
• Molecular Formula: C14H12 N4 O3
• Molecular Weight: 284.2701
• European Community (EC) Number: 668-722-4
• Wikidata: Q76306200
• Mol file: 28461-50-9.mol

Synonyms:28461-50-9;2-amino-N-[(3-nitrophenyl)methylideneamino]benzamide;N'1-(3-nitrobenzylidene)-2-aminobenzene-1-carbohydrazide;MLS003373824;SMR002048620;cid_350423;BDBM95938;2-amino-N-[(E)-(3-nitrophenyl)methylideneamino]benzamide;AKOS003855382;2-amino-N-[(3-nitrobenzylidene)amino]benzamide;2-azanyl-N-[(3-nitrophenyl)methylideneamino]benzamide;2-amino-N'-[(E)-(3-nitrophenyl)methylidene]benzohydrazide

Chemical Property of 2-amino-N-[(3-nitrophenyl)methylideneamino]benzamide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: 1.35g/cm³
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 3
• Exact Mass: 284.09094026
• Heavy Atom Count: 21
• Complexity: 408

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)C(=O)NN=CC2=CC(=CC=C2)[N+](=O)[O-])N
• Isomeric SMILES: C1=CC=C(C(=C1)C(=O)N/N=C/C2=CC(=CC=C2)[N+](=O)[O-])N

Technology Process of 2-amino-N-[(3-nitrophenyl)methylideneamino]benzamide

There total 2 articles about 2-amino-N-[(3-nitrophenyl)methylideneamino]benzamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-nitro-benzaldehyde (99-61-6) + anthranilic acid hydrazide (1904-58-1) → 2-amino-benzoic acid (3-nitro-benzylidene)-hydrazide (28461-50-9)

Guidance literature:

With 1-n-butyl-3-methylimidazolim bromide; at 0 ℃; for 2h;

DOI:10.1021/co1000713

Reference yield:

→ 2-amino-benzoic acid (3-nitro-benzylidene)-hydrazide (28461-50-9)

Guidance literature:

/BRN= 2117903/;

Reference yield: 92.0%

m-bromobenzoic aldehyde (3132-99-8) + 2-amino-benzoic acid (3-nitro-benzylidene)-hydrazide (28461-50-9) → C21H15BrN4O3

Guidance literature:

With iodine; 1-n-butyl-3-methylimidazolim bromide; at 50 ℃; for 3h;

DOI:10.1021/co1000713

upstream raw materials:

3-nitro-benzaldehyde

anthranilic acid hydrazide

Downstream raw materials:

2-(3-nitro-phenyl)-2,3-dihydro-[1,3,4]thiadiazolo[2,3-b]quinazolin-5-one