1,3-Dichloro-6-(trifluoromethyl)phenanthren-9-carboxaldehyde

Base Information

Chemical Name:1,3-Dichloro-6-(trifluoromethyl)phenanthren-9-carboxaldehyde
CAS No.:38492-84-1
Molecular Formula:C16H7Cl2F3O
Molecular Weight:343.132
Hs Code.:2913000090
European Community (EC) Number:253-972-5
UNII:92M0HG0WF5
DSSTox Substance ID:DTXSID90191815
Nikkaji Number:J294.681E
Wikidata:Q83064393
Mol file:38492-84-1.mol

Synonyms:38492-84-1;1,3-Dichloro-6-(trifluoromethyl)phenanthren-9-carboxaldehyde;92M0HG0WF5;1,3-Dichloro-6-trifluoromethyl-9-phenanthrenecarboxaldehyde;EINECS 253-972-5;1,3-Dichloro-6-(trifluoromethyl)-9-phenanthrenecarbaldehyde;9-Phenanthrenecarboxaldehyde, 1,3-dichloro-6-(trifluoromethyl)-;1,3-dichloro-6-(trifluoromethyl)phenanthrene-9-carbaldehyde;C16H7Cl2F3O;UNII-92M0HG0WF5;SCHEMBL8652241;C16-H7-Cl2-F3-O;DTXSID90191815;1,3-Dichloro-6-(trifluoromethyl)-9-phenanthrenecarbaldehyde #;1,3-DICHLORO-6-(TRIFLUOROMETHYL)-9-PHENANTHRENECARBOXALDEHYDE

Suppliers and Price of 1,3-Dichloro-6-(trifluoromethyl)phenanthren-9-carboxaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 1,3-Dichloro-6-(trifluoromethyl)phenanthren-9-carboxaldehyde

Chemical Property:

Vapor Pressure:9.28E-09mmHg at 25°C
Boiling Point:463.2°C at 760 mmHg
Flash Point:233.9°C
PSA：17.07000
Density:1.513g/cm³
LogP:6.13110
XLogP3:6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:341.9826047
Heavy Atom Count:22
Complexity:428

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC2=C(C=C1C(F)(F)F)C3=C(C=C2C=O)C(=CC(=C3)Cl)Cl

Technology Process of 1,3-Dichloro-6-(trifluoromethyl)phenanthren-9-carboxaldehyde

There total 6 articles about 1,3-Dichloro-6-(trifluoromethyl)phenanthren-9-carboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 38635-85-7
1,3-dichloro-6-(trifluoromethyl)phenanthren-9-carboxylic acid

: 38492-84-1
1,3-dichloro-6-(trifluoromethyl)phenanthren-9-carboxaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: B₂H₆ / tetrahydrofuran

2: Pb(OAc)4, Py

With pyridine; lead(IV) acetate; diborane; In tetrahydrofuran;
DOI:10.1021/jm00277a018

Reference yield:

: 38492-81-8
1,3-dichloro-6-(trifluoromethyl)phenanthren-9-methanol

: 38492-84-1
1,3-dichloro-6-(trifluoromethyl)phenanthren-9-carboxaldehyde

Guidance literature:: With pyridine; lead(IV) acetate;
DOI:10.1021/jm00277a018

Reference yield:

: 874-42-0
2,4-dichlorobenzaldeyhde

: 38492-84-1
1,3-dichloro-6-(trifluoromethyl)phenanthren-9-carboxaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1.1: potassium carbonate / acetic anhydride / 24 h / 65 °C

2.1: iron(II) sulfate; sodium hydroxide / water / 2 h / 100 °C

3.1: isopentyl nitrite; hydrogenchloride / ethanol / 1 h / -5 °C

3.2: 2 h / 40 °C

4.1: diborane; tetrahydrofuran / 12 h / 0 - 20 °C / Inert atmosphere

5.1: manganese(IV) oxide / chloroform / 2 h / 20 - 45 °C

With tetrahydrofuran; hydrogenchloride; manganese(IV) oxide; potassium carbonate; iron(II) sulfate; sodium hydroxide; diborane; isopentyl nitrite; In ethanol; chloroform; water; acetic anhydride; 3.1: |Pschor Arylation / 3.2: |Pschor Arylation;
DOI:10.1021/acs.jmedchem.7b00140