Technology Process of (E)-hexadec-11-enal
There total 13 articles about (E)-hexadec-11-enal which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
oxalyl dichloride; dimethyl sulfoxide;
In
dichloromethane;
at -60 ℃;
for 0.25h;
DOI:10.1021/jo00376a043
- Guidance literature:
-
11-hexadecene-1-ol;
With
oxalyl dichloride; dimethyl sulfoxide;
In
dichloromethane;
at -78 ℃;
for 0.25h;
With
triethylamine;
In
dichloromethane;
Overall yield = 95 %; Overall yield = 0.20 g;
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1.) ThxBHCl*Me2S, 2.) KIPBH, 3.) NaOMe, 4.) AcOH
2: 97 percent / 20percent aq. NaOH / aq. ethanol / 0.5 h / Ambient temperature
3: 98 percent / oxalyl chloride, Me2SO / CH2Cl2 / 0.25 h / -60 °C
With
sodium hydroxide; potassium tri(isopropoxy)borohydride; oxalyl dichloride; thexylchloroborane*methyl sulfide; sodium methylate; acetic acid; dimethyl sulfoxide;
In
ethanol; dichloromethane;
DOI:10.1021/jo00376a043
