n',n'-Dimethyl-p,p-diphenylphosphinous hydrazide

Base Information

Chemical Name:n',n'-Dimethyl-p,p-diphenylphosphinous hydrazide
CAS No.:3999-13-1
Molecular Formula:C₁₄H₁₇N₂P
Molecular Weight:244.276
Hs Code.:
NSC Number:117297
DSSTox Substance ID:DTXSID70297682
Nikkaji Number:J2.150.258H
Wikidata:Q82038963
Mol file:3999-13-1.mol

Synonyms:3999-13-1;n',n'-dimethyl-p,p-diphenylphosphinous hydrazide;NSC117297;DTXSID70297682;NSC-117297;1-dimethylphosphino-2,2-dimethylhydrazine

Suppliers and Price of n',n'-Dimethyl-p,p-diphenylphosphinous hydrazide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of n',n'-Dimethyl-p,p-diphenylphosphinous hydrazide

Chemical Property:

Boiling Point:340.1°Cat760mmHg
Flash Point:159.5°C
Density:g/cm³
XLogP3:3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:244.112935548
Heavy Atom Count:17
Complexity:190

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN(C)NP(C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of n',n'-Dimethyl-p,p-diphenylphosphinous hydrazide

There total 1 articles about n',n'-Dimethyl-p,p-diphenylphosphinous hydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3999-13-1
2-diphenylphosphino-1,1-dimethylhydrazine

Guidance literature:: unsym. Dimethylhydrazin, Chlordiphenylphosphin;
DOI:10.1002/9780470132395.ch20

Reference yield: 84.0%

: cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate

: 3999-13-1
2-diphenylphosphino-1,1-dimethylhydrazine

: 917601-59-3
[Ru(C5H5)[κ1-((C6H5)2PNHN(CH3)2)(CH3CN)2]][PF6]

Guidance literature:: In acetonitrile; under Ar, Schlenk techniques, ligand added to soln. of Ru compd. (1:1 molar ratio), stirred for 2 h at room temp.; concd., pptd. (Et2O), filtered off, washed (Et2O), dried (vac.), elem. anal.;
DOI:10.1002/ejic.200500942

Reference yield: 80.0%

: 1270-98-0
cyclopentadienyl titanium(IV) trichloride

: 3999-13-1
2-diphenylphosphino-1,1-dimethylhydrazine

: 849371-31-9
[(C₅H₅)TiCl₂(Ph₂PNNMe₂)]

Guidance literature:: In diethyl ether; byproducts: [Ph2PNHNHMe2]Cl; under N2; to a soln. of a ligand (2.05 mmol) in Et2O Ti-contg. compd. (1.03 mmol) was added; the mixt. was stirred at room temp. for 2 h, cooledto -78°C and stirred for 2 h; the ppt. was removed by filtration at -18°C; Et2O soln. was left to stand and the remaining Et2O soln. was evapd. to dryness; elem. anal.;
DOI:10.1039/b417068g