Dicyclohexyldiazene 1,2-dioxide

Base Information

• Chemical Name: Dicyclohexyldiazene 1,2-dioxide
• CAS No.: 3378-45-8
• Molecular Formula: C₁₂H₂₂N₂O₂
• Molecular Weight: 226.319
• Mol file: 3378-45-8.mol

Synonyms:nitrosocyclohexane dimer;Azocyclohexane,dioxide;N,N'-dicyclohexyldiazene N,N'-dioxide;dicyclohexyldiazene 1,2-dioxide;(E)-Dicyclohexyl-diazen-N,N'-dioxid;Diazene,dicyclohexyl-,1,2-dioxide;CYCLOHEXYL-(CYCLOHEXYL-OXIDO-AMINO)-OXO-AZANIUM;Azocyclohexane N,N'-dioxide;dimeres Nitrosocyclohexan;trans-nitrosocyclohexane dimer;(E)-dicyclohexyl-diazene-N,N'-dioxide;

Chemical Property of Dicyclohexyldiazene 1,2-dioxide

Chemical Property:

• PSA: 57.50000
• LogP: 4.17100

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Dicyclohexyldiazene 1,2-dioxide

There total 15 articles about Dicyclohexyldiazene 1,2-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

cyclohexylamine (108-91-8,157973-60-9) → N,N'-dicyclohexyldiazene N,N'-dioxide (3378-45-8,17606-86-9,26049-06-9)

Guidance literature:

With sodium percarbonate; N,N,N',N'-tetraacetylethylenediamine; sodium hydrogencarbonate; In dichloromethane; water; for 3h; Ambient temperature;

Reference yield: 80.0%

1-nitrocyclohexane (1122-60-7) → N,N'-dicyclohexyldiazene N,N'-dioxide (3378-45-8,17606-86-9,26049-06-9)

Guidance literature:

With sodium hydrogen telluride;

DOI:10.1246/cl.1983.1373

Reference yield: 48.0%

cyclohexane (110-82-7,25012-93-5) → cyclohexanone-oxime (100-64-1) + N,N'-dicyclohexyldiazene N,N'-dioxide (3378-45-8,17606-86-9,26049-06-9)

Guidance literature:

With tert.-butylnitrite; at 50 ℃; for 0.166667h; Temperature; Time; Reagent/catalyst; Flow reactor; UV-irradiation;

DOI:10.1055/s-0040-1707281

upstream raw materials:

cyclohexane

cyclohexylamine

N-cyclohexyl-hydroxylamine

nitromethane

Downstream raw materials:

(Z)-Cyclohexylmethyldiazen-1-oxid

(Z)-Methylcyclohexyldiazen-1-oxid

(Z)-Dicyclohexyldiazen-1-oxid

N-(1-Chloro-cyclohexyl)-N'-cyclohexyl-diazene N-oxide