Tris[2-(diphenylphosphino)ethyl]phosphine

Base Information

Chemical Name:Tris[2-(diphenylphosphino)ethyl]phosphine
CAS No.:23582-03-8
Molecular Formula:C42H42P4
Molecular Weight:670.691
Hs Code.:29310099
European Community (EC) Number:245-754-3
NSC Number:164875
DSSTox Substance ID:DTXSID30178221
Nikkaji Number:J229.007C
Wikidata:Q72507971
ChEMBL ID:CHEMBL65725
Mol file:23582-03-8.mol

Synonyms:23582-03-8;Tris[2-(diphenylphosphino)ethyl]phosphine;Tris(2-(diphenylphosphino)ethyl)phosphine;tris(2-diphenylphosphanylethyl)phosphane;Phosphine, tris[2-(diphenylphosphino)ethyl]-;EINECS 245-754-3;Tetraphos-Li;NSC164875;CHEMBL65725;SCHEMBL1617138;DTXSID30178221;C42H42P4;MFCD00010009;AKOS015910684;tris(2-diphenylphosphinoethyl)phosphine;NSC 164875;NSC-164875;CS-0085922;FT-0652155;Tris[2-(diphenylphosphino)ethyl]phosphine, 97%;J-015156;5-(Methoxycarbonyl)-1-methyl-1H-pyrazole-3-carboxylicacid;P(CCP(CCP(c1ccccc1)c2ccccc2)CCP(c3ccccc3)c4ccccc4)(c5ccccc5)c6ccccc6

Suppliers and Price of Tris[2-(diphenylphosphino)ethyl]phosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE 95.00%
1G
$ 730.68

Arctom
Tris(2-(diphenylphosphino)ethyl)phosphine 98%
1g
$ 196.00

Arctom
Tris(2-(diphenylphosphino)ethyl)phosphine 98%
100mg
$ 53.00

Arctom
Tris(2-(diphenylphosphino)ethyl)phosphine 98%
250mg
$ 79.00

Sigma-Aldrich
Tris[2-(diphenylphosphino)ethyl]phosphine 97%
1g
$ 132.00

Strem Chemicals
Tris[2-(diphenylphosphino)ethyl]phosphine, 98% PP3
250mg
$ 41.00

Strem Chemicals
Tris[2-(diphenylphosphino)ethyl]phosphine, 98% PP3
1g
$ 100.00

Total 17 raw suppliers

Chemical Property of Tris[2-(diphenylphosphino)ethyl]phosphine

Chemical Property:

Appearance/Colour:white to light yellow crystal powder
Vapor Pressure:6.83E-21mmHg at 25°C
Melting Point:134-135 °C(lit.)
Boiling Point:740.1 °C at 760 mmHg
Flash Point:429.4 °C
PSA：54.36000
LogP:8.86700
XLogP3:8.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:15
Exact Mass:670.22369933
Heavy Atom Count:46
Complexity:623

Purity/Quality:

98%,99%, ^*data from raw suppliers

TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 20/21/22-36/37/38
Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(CCP(CCP(C2=CC=CC=C2)C3=CC=CC=C3)CCP(C4=CC=CC=C4)C5=CC=CC=C5)C6=CC=CC=C6
Uses Ligand used in iron-catalyzed, greener reduction of aldehydes to alcohols under transfer hydrogenation conditions.Fast and selective iron-catalyzed transfer hydrogenations of aldehydes

Technology Process of Tris[2-(diphenylphosphino)ethyl]phosphine

There total 4 articles about Tris[2-(diphenylphosphino)ethyl]phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: tris(2-chloroethyl)phosphine hydrochloride

: 829-85-6
diphenylphosphane

: 23582-03-8
tris(2-diphenylphosphinoethyl)phosphine

Guidance literature:: diphenylphosphane; With potassium tert-butylate; In tetrahydrofuran; for 0.5h; Inert atmosphere;

tris(2-chloroethyl)phosphine hydrochloride; In tetrahydrofuran; at 80 ℃; for 20h; Inert atmosphere;
DOI:10.1039/c7cc02584j

Reference yield:

: C₄₂H₄₂Cl₄P₄⁽⁴⁺⁾*4Cl^(1-)

: 23582-03-8
tris(2-diphenylphosphinoethyl)phosphine

Guidance literature:: With hexachlorodisilane; In dichloromethane-d2; at 20 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1021/acs.organomet.0c00788

Reference yield:

: 23725-53-3
(Ph₂P(O)CH₂CH₂)3PO

: 23582-03-8
tris(2-diphenylphosphinoethyl)phosphine

Guidance literature:: Multi-step reaction with 2 steps

1: oxalyl dichloride / dichloromethane / 1 h / 20 °C / Schlenk technique; Inert atmosphere; Sealed tube

2: hexachlorodisilane / dichloromethane-d2 / 0.08 h / 20 °C / Inert atmosphere; Schlenk technique; Glovebox

With oxalyl dichloride; hexachlorodisilane; In dichloromethane; dichloromethane-d2;
DOI:10.1021/acs.organomet.0c00788