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829-85-6

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manufacturer of Diphenylphosphine
Cas No: 829-85-6
No Data 100 Gram 800 Kilogram/Month Puyang Huicheng Electronic Material Co., Ltd Contact Supplier
Diphenylphosphine
Cas No: 829-85-6
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Hangzhou Dayangchem Co., Ltd. Contact Supplier
Diphenylphosphine
Cas No: 829-85-6
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 500 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
Diphenylphosphine
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No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
High purity Various Specifications Diphenylphosphine CAS:829-85-6
Cas No: 829-85-6
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Diphenylphosphine
Cas No: 829-85-6
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
Phosphine,diphenyl-
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USD $ 500.0-500.0 / Kilogram 1 Kilogram 100 Kilogram/Month Henan DaKen Chemical CO.,LTD. Contact Supplier
Diphenylphosphine
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No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Diphenylphosphine
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No Data No Data Metric Ton/Day Beijing Greenchem Technology Co.,Ltd.(Qingdao Greenchem international Trading Co.,Ltd) Contact Supplier
Diphenylphosphine 829-85-6
Cas No: 829-85-6
No Data 100 Kilogram 300 Kilogram/Month HENAN SUNLAKE ENTERPRISE CORPORATION Contact Supplier

829-85-6 Usage

Uses

Diphenylphosphine is used in the synthesis of aminophosphines for application as catalysts. It is also used in the preparation of chiral palladacycles with N-heterocyclic carbene ligands as catalysts.

Organophosphorus compound

Diphenylphosphine is commonly used in laboratory as organic phosphorus compound, it is unpleasant odor colorless liquid, and it is pungent, it is easily oxidized in air and can cause spontaneous combustion, it is sensitive to air and light, it need the protection of nitrogen. It can be used as precursor to synthesize some organic phosphine ligand. By deprotonation, it can be converted to diphenylphosphine compound: Ph2PH + nBuLi → Ph2PLi + nBuH, such as 1,2-bis (diphenylphosphino) ethane and 1,3-bis (diphenylphosphino) propane phosphine ligands etc, Wittig-Horner reagents and the synthesis of quaternary phosphonium salt is usually by means of diphenylphosphino alkylation to achieve.
Diphenylphosphine such as sodium and lithium diphenylphosphine and diphenylphosphine compound can add to carbon heteroatom double bond as nucleophile. For example, in the condition of concentrated hydrochloric acid at 100℃, diphenylphosphine can add to aldehyde carbon atoms of benzaldehyde: Ph2PH + PhCHO → Ph2P (O) CH2Ph, when compares with tertiary phosphine, alkalinity of diphenylphosphine is weaker. The pKa of conjugate acid diphenylphosphine is 0.03: Ph2PH2 + → Ph2PH + H +
Preparation: Lithium diphenylphosphine can generated by inexpensive triphenylphosphine and the with the cancellation of water can obtain diphenylphosphine: (1) PPh3 + 2 Li → LiPPh2 + LiPh (2) LiPPh2 + H2O → Ph2PH + LiOH.
The above information is edited by the chemicalbook of Wang Xiaodong.

Uses

It can be used the intermediates of organic, catalysts.

Chemical Properties

Clear colorless to slightly yellow liquid

Uses

suzuki reaction
InChI:InChI=1/C12H11P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10,13H

829-85-6 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (56169)  Diphenylphosphine    829-85-6 50g 1852.0CNY Detail
Alfa Aesar (56169)  Diphenylphosphine    829-85-6 10g 504.0CNY Detail

829-85-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name Diphenylphosphine

1.2 Other means of identification

Product number -
Other names diphenylphosphane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:829-85-6 SDS

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