Magnesium octaethylporphyrin

Base Information

• Chemical Name: Magnesium octaethylporphyrin
• CAS No.: 20910-35-4
• Molecular Formula: C36H44 Mg N4
• Molecular Weight: 557.077
• Mol file: 20910-35-4.mol

Synonyms:magnesium octaethylporphyrin;MgOEP

Chemical Property of Magnesium octaethylporphyrin

Chemical Property:

• Vapor Pressure: 6.24E-25mmHg at 25°C
• Boiling Point: 804.9°Cat760mmHg
• Flash Point: 335.1°C
• PSA: 34.58000
• Density: g/cm³
• LogP: 6.13420
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 556.3416391
• Heavy Atom Count: 41
• Complexity: 603

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC1=C(C2=CC3=NC(=CC4=NC(=CC5=C(C(=C([N-]5)C=C1[N-]2)CC)CC)C(=C4CC)CC)C(=C3CC)CC)CC.[Mg+2]

Technology Process of Magnesium octaethylporphyrin

There total 5 articles about Magnesium octaethylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2,3,7,8,12,13,17,18-octaethyl-porphyrin (2683-82-1,106117-28-6,991-75-3) → magnesium(II) 2,3,7,8,12,13,17,18-octaethylporphyrin (20910-35-4)

Guidance literature:

With 2,6-di-t-butyl-4-methylphenoxy magnesium iodide; In diethyl ether; chloroform; at 50 ℃; for 0.05h;

DOI:10.1002/hlca.19800630433

Reference yield:

cation radical of magnesium octaethylporphyrin (56571-41-6) → magnesium(II) 2,3,7,8,12,13,17,18-octaethylporphyrin (20910-35-4)

Guidance literature:

With 2,3-Dimethylaniline; In dichloromethane; at 17 ℃; Rate constant;

DOI:10.1246/cl.1987.2095

Reference yield:

1,4-dinitroanthracene radical anion (100-25-4) + C36H44N4(1-)*Mg(2+) → magnesium(II) 2,3,7,8,12,13,17,18-octaethylporphyrin (20910-35-4)

Guidance literature:

In methanol; water; at 25 ℃; Rate constant; further solvents;

DOI:10.1021/j100230a028

upstream raw materials:

1,4-dinitroanthracene radical anion

cation radical of magnesium octaethylporphyrin

2,3,7,8,12,13,17,18-octaethyl-porphyrin

Downstream raw materials:

5-benzoyloxy-2,3,7,8,12,13,17,18-octaethylporphyrin

2,3,7,8,12,13,17,18-octaethyl-porphyrin

2,3,7,8,12,13,17,18-octaethyl-5-(1-imidazolyl)porphyrin

10-benzoyloxy-2,3,7,8,12,13,17,18-octaethyl-5,15-bis(1-imidazolyl)porphyrin

Refernces

• 1、 Kojo, Shosuke,Morimitsu, Kozo,Tabushi, Iwao. "Electron Transfer Reaction from Dimethylanilines to Cation Radical of Magnesium Octaethylporphyrin". . p. 2095 - 2096. Retrieved 1987.
• 2、 Fuhrhop,Mauzerall. "The one-electron oxidation of metalloporphyrins.". . p. 4174 - 4181. Retrieved 1969.