ethyl (2Z)-3-(4-methylphenyl)but-2-enoate

Base Information

Chemical Name:ethyl (2Z)-3-(4-methylphenyl)but-2-enoate
CAS No.:6305-61-9
Molecular Formula:C₁₃H₁₆O₂
Molecular Weight:204.269
Hs Code.:
Nikkaji Number:J1.974.163J
NSC Number:41166
Mol file:6305-61-9.mol

Synonyms:SCHEMBL14499482;6305-61-9;NSC41166;NSC-41166;ethyl (2Z)-3-(4-methylphenyl)but-2-enoate;EN300-1460175;115819-11-9

Suppliers and Price of ethyl (2Z)-3-(4-methylphenyl)but-2-enoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of ethyl (2Z)-3-(4-methylphenyl)but-2-enoate

Chemical Property:

Vapor Pressure:0.00156mmHg at 25°C
Boiling Point:295.1°C at 760 mmHg
Flash Point:155.4°C
PSA：26.30000
Density:1.005g/cm³
LogP:2.96140
XLogP3:3.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:204.115029749
Heavy Atom Count:15
Complexity:235

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C=C(C)C1=CC=C(C=C1)C
Isomeric SMILES:CCOC(=O)/C=C(/C)\C1=CC=C(C=C1)C

Technology Process of ethyl (2Z)-3-(4-methylphenyl)but-2-enoate

There total 31 articles about ethyl (2Z)-3-(4-methylphenyl)but-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 6305-61-9,115819-11-9,94853-53-9
ethyl (E)-3-p-tolylbut-2-enoate

: 6305-61-9,94853-53-9,115819-11-9
(Z)-ethyl 3-(4'-methylphenyl)-2-butenoate

Guidance literature:: With riboflavin; In acetonitrile; at 20 ℃; for 24h; diastereoselective reaction; Irradiation;
DOI:10.1021/jacs.5b07136

Reference yield: 93.0%

: 867-13-0
diethoxyphosphoryl-acetic acid ethyl ester

: 122-00-9
para-methylacetophenone

: 6305-61-9,115819-11-9,94853-53-9
ethyl (E)-3-p-tolylbut-2-enoate

Guidance literature:: With sodium hydride; In ethanol; for 20h; Reflux;
DOI:10.1016/j.tetasy.2012.05.016

Reference yield: 88.0%

: 4341-76-8
Ethyl 2-butynoate

: 5720-05-8
4-methylphenylboronic acid

: 6305-61-9,115819-11-9,94853-53-9
ethyl (E)-3-p-tolylbut-2-enoate

Guidance literature:: With water; palladium diacetate; triethylphosphonium tetrafluoroborate; caesium carbonate; In toluene; at 23 ℃; for 18h; regioselective reaction; Inert atmosphere;
DOI:10.1016/j.tet.2009.08.029