Technology Process of 2-methyl-6-(p-tolyl)-3,3-bisphenylthioheptan-4-ol
There total 6 articles about 2-methyl-6-(p-tolyl)-3,3-bisphenylthioheptan-4-ol which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.) sodium hydride / 1.) dimethoxyethane, 30 min, room temperature 2.) reflux, 5 h, dimethoxy ethane
2: 96 percent / hydrogen / 5percent palladium on charcoal / ethanol / 6 h / 760 Torr
3: 85 percent / lithium aluminium hydride / tetrahydrofuran / 0.5 h
4: 57 percent / pyridinium chlorochromate / CH2Cl2 / 1.5 h / other reagent
5: 1.) n-butyl-lithium, TMEDA 2.) n-butyl-lithium / 1.) hexane, THF, 0 deg C, 15 min 2.) 30 min, hexane, THF
With
lithium aluminium tetrahydride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; hydrogen; sodium hydride; pyridinium chlorochromate;
palladium on activated charcoal;
In
tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1039/P19850001237
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 96 percent / hydrogen / 5percent palladium on charcoal / ethanol / 6 h / 760 Torr
2: 85 percent / lithium aluminium hydride / tetrahydrofuran / 0.5 h
3: 57 percent / pyridinium chlorochromate / CH2Cl2 / 1.5 h / other reagent
4: 1.) n-butyl-lithium, TMEDA 2.) n-butyl-lithium / 1.) hexane, THF, 0 deg C, 15 min 2.) 30 min, hexane, THF
With
lithium aluminium tetrahydride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; hydrogen; pyridinium chlorochromate;
palladium on activated charcoal;
In
tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1039/P19850001237
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 57 percent / pyridinium chlorochromate / CH2Cl2 / 1.5 h / other reagent
2: 1.) n-butyl-lithium, TMEDA 2.) n-butyl-lithium / 1.) hexane, THF, 0 deg C, 15 min 2.) 30 min, hexane, THF
With
n-butyllithium; N,N,N,N,-tetramethylethylenediamine; pyridinium chlorochromate;
In
dichloromethane;
DOI:10.1039/P19850001237