2,4,6-Triisopropylbenzenesulfonyl azide

Base Information

Chemical Name:2,4,6-Triisopropylbenzenesulfonyl azide
CAS No.:36982-84-0
Molecular Formula:C15H23N3O2S
Molecular Weight:309.433
Hs Code.:29350090
European Community (EC) Number:609-323-7
NSC Number:646156
DSSTox Substance ID:DTXSID80327323
Nikkaji Number:J145.100F
Wikipedia:2,4,6-Triisopropylbenzenesulfonyl_azide
ChEMBL ID:CHEMBL1995382
Mol file:36982-84-0.mol

Synonyms:36982-84-0;2,4,6-triisopropylbenzenesulfonyl azide;2,4,6-Triisopropylbenzene-sulfonyl azide;Trisyl azide;NSC646156;2,4,6-Tris(1-methylethyl)-benzenesulfonyl azide;N-diazo-2,4,6-tri(propan-2-yl)benzenesulfonamide;Benzenesulfonyl azide, 2,4,6-tris(1-methylethyl)-;2,4,6-tris(propan-2-yl)benzene-1-sulfonyl azide;2,4,6-triisopropyl-benzenesulfonyl azide;N-diazo-2,4,6-triisopropyl-benzenesulfonamide;SCHEMBL1500382;CHEMBL1995382;DTXSID80327323;2,4,6-Triisopropylbenzenesulfonyl azide, stab. with ca 10% water;MFCD00859286;AKOS015889937;2,4,6-Triisopropylbenzenesulfonylazide;2,4,6-triisopropylphenyl-sulfonylazide;AB92859;AC-6473;NSC-646156;2,4,6-triisopropylbenzene sulfonylazide;2,4,6-triisopropylbenzenesulphonyl azide;2,4,6-triisopropyl benzenesulfonyl azide;2,4,6-triisopropylbenzenesulfonyl azide?;AM803790;AS-11082;NCI60_015891;2,4,6-triisopropylbenzene -sulfonyl azide;FT-0609883;T3434;EN300-1070022;2,4,6-TRIISOPROPYLBENZENE-SULFONYL AZIDE,;J-507078;1-((2,4,6-Triisopropylphenyl)sulfonyl)-2.lambda.~5~-1,2-triazadiene;2,4,6-TRIISOPROPYLBENZENESULFONYL AZIDE (WETTED WITH CA. 10% WATER);2,4,6-Triisopropylbenzenesulfonyl azide contains 15 wt. % water as stabilizer;2,4,6-Triisopropylbenzenesulfonyl azide, contains 15 wt. % water as stabilizer, 97%;2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis)

Suppliers and Price of 2,4,6-Triisopropylbenzenesulfonyl azide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
2,4,6-Triisopropylbenzenesulfonyl azide
5g
$ 375.00

TRC
2,4,6-Triisopropylbenzenesulfonyl azide
10g
$ 225.00

TRC
2,4,6-Triisopropylbenzenesulfonyl azide
2.5g
$ 80.00

TRC
2,4,6-Triisopropylbenzenesulfonyl azide
1g
$ 50.00

TCI Chemical
2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis) >98.0%(HPLC)
1g
$ 37.00

TCI Chemical
2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis) >98.0%(HPLC)
5g
$ 149.00

Sigma-Aldrich
2,4,6-Triisopropylbenzenesulfonyl azide solution 10%±2% in toluene, ≥98% (HPLC)
25g
$ 223.00

Sigma-Aldrich
2,4,6-Triisopropylbenzenesulfonyl azide contains 15wt. % water as stabilizer, 97%
5g
$ 176.00

Oakwood
2,4,6-Triisopropylbenzenesulfonyl azide contains 15 wt. % water as stabilizer
5g
$ 25.00

Oakwood
2,4,6-Triisopropylbenzenesulfonyl azide contains 15 wt. % water as stabilizer
1g
$ 10.00

Total 84 raw suppliers

Chemical Property of 2,4,6-Triisopropylbenzenesulfonyl azide

Chemical Property:

Melting Point:40-42 °C
Refractive Index:n20/D1.499
Flash Point:4℃
PSA：92.27000
LogP:5.58936
Storage Temp.:2-8°C
Water Solubility.:Insoluble in water.
XLogP3:5.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:309.15109816
Heavy Atom Count:21
Complexity:470

Purity/Quality:

99% ^*data from raw suppliers

2,4,6-Triisopropylbenzenesulfonyl azide ^*data from reagent suppliers

Safty Information:

Pictogram(s): R36/37/38:Irritating to eyes, respiratory system and skin.;
Hazard Codes:T,Xn,F
Statements: 36/37/38-25-67-65-48/20-38-22-11-63-5
Safety Statements: 15-26-36-45-62-36/37-16-37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC(C)C1=CC(=C(C(=C1)C(C)C)S(=O)(=O)N=[N+]=[N-])C(C)C
Uses 2,4,6-Triisopropylbenzenesulfonyl azide is used as a reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ?-diazo ketones than other methods. It is also used for azide transfer to potassium enolates (KHMDS) to form the ?-azido derivatives. Reagent for:? ;Stereoselective diversity-oriented synthesis of functionalized saccharides1? ;Meyer′s lactamization2Reagent for synthesis of:? ;Antidote to anthrax lethal factor intoxication3? ;Bacterial RNA polymerase inhibitor4? ;Bicyclic extended dipeptide surrogates5? ;Single enantiomers of mycobacterial keomycolic acids6

Technology Process of 2,4,6-Triisopropylbenzenesulfonyl azide

There total 3 articles about 2,4,6-Triisopropylbenzenesulfonyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%