1-methyl-4-(1-methylethylidene)-2-(1-methylvinyl)-1-vinylcyclohexane

Base Information

Chemical Name:1-methyl-4-(1-methylethylidene)-2-(1-methylvinyl)-1-vinylcyclohexane
CAS No.:3242-08-8
Molecular Formula:C15H24
Molecular Weight:204.356
Hs Code.:2902199090
European Community (EC) Number:221-812-3
DSSTox Substance ID:DTXSID70954182
Nikkaji Number:J101.613J
Wikidata:Q82933272
Mol file:3242-08-8.mol

Synonyms:o-Menth-8-ene,4-isopropylidene-1-vinyl- (8CI); 1-Ethenyl-1-methyl-2-(1-methylethenyl)-4-(1-methylethylidene)-cyclohexane;Elixene

Suppliers and Price of 1-methyl-4-(1-methylethylidene)-2-(1-methylvinyl)-1-vinylcyclohexane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 8 raw suppliers

Chemical Property of 1-methyl-4-(1-methylethylidene)-2-(1-methylvinyl)-1-vinylcyclohexane

Chemical Property:

Vapor Pressure:0.0225mmHg at 25°C
Boiling Point:258.2°Cat760mmHg
Flash Point:101.3°C
PSA：0.00000
Density:0.876g/cm³
LogP:4.89130
XLogP3:5.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:204.187800766
Heavy Atom Count:15
Complexity:302

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=C1CCC(C(C1)C(=C)C)(C)C=C)C

Technology Process of 1-methyl-4-(1-methylethylidene)-2-(1-methylvinyl)-1-vinylcyclohexane

There total 6 articles about 1-methyl-4-(1-methylethylidene)-2-(1-methylvinyl)-1-vinylcyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1273149-94-2
(+)-(5S,10S)-elema-1,3,7,11⁽¹²⁾-tetraene

: 3242-08-8,29873-99-2,30824-67-0,32663-56-2,38906-87-5,57172-50-6,58865-70-6,73246-02-3
γ–elemene

Guidance literature:: (+)-(5S,10S)-elema-1,3,7,11⁽¹²⁾-tetraene; With ammonia; sodium; In tetrahydrofuran; at -78 ℃; for 0.416667h;

With tert-butyl alcohol; In tetrahydrofuran; for 0.0833333h;
DOI:10.1039/c0ob00467g

Reference yield:

: 6902-91-6
germacrone

: 3242-08-8,29873-99-2,30824-67-0,32663-56-2,38906-87-5,57172-50-6,58865-70-6,73246-02-3
γ–elemene

Guidance literature:: Multi-step reaction with 3 steps

1.1: (3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydro-2H-pyrrolo[2,1-e]azaborole; borane-THF / tetrahydrofuran; toluene / Cooling with ice; Inert atmosphere

2.1: bis(benzonitrile)palladium(II) dichloride / toluene / 1.75 h / Inert atmosphere; Reflux

3.1: ammonia; sodium / tetrahydrofuran / 0.42 h / -78 °C

3.2: 0.08 h

With bis(benzonitrile)palladium(II) dichloride; borane-THF; (3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydro-2H-pyrrolo[2,1-e]azaborole; ammonia; sodium; In tetrahydrofuran; toluene; 2.1: Cope rearrangement;
DOI:10.1039/c0ob00467g

Reference yield:

: 90988-53-7
(3E,7E)-3,7-dimethyl-10-(1-methylethylidene)-3,7-cyclodecanedien-1-ol

: 3242-08-8,29873-99-2,30824-67-0,32663-56-2,38906-87-5,57172-50-6,58865-70-6,73246-02-3
γ–elemene

Guidance literature:: Multi-step reaction with 2 steps

1.1: bis(benzonitrile)palladium(II) dichloride / toluene / 1.75 h / Inert atmosphere; Reflux

2.1: ammonia; sodium / tetrahydrofuran / 0.42 h / -78 °C

2.2: 0.08 h

With bis(benzonitrile)palladium(II) dichloride; ammonia; sodium; In tetrahydrofuran; toluene; 1.1: Cope rearrangement;
DOI:10.1039/c0ob00467g