1-(4-methoxyphenyl)-N-(tritylsulfanyl)methanamine

Base Information

Chemical Name:1-(4-methoxyphenyl)-N-(tritylsulfanyl)methanamine
CAS No.:86864-58-6
Molecular Formula:C27H25NOS
Molecular Weight:411.5585
Hs Code.:

Synonyms:

Suppliers and Price of 1-(4-methoxyphenyl)-N-(tritylsulfanyl)methanamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 5 raw suppliers

Chemical Property of 1-(4-methoxyphenyl)-N-(tritylsulfanyl)methanamine

Chemical Property:

Vapor Pressure:2.24E-12mmHg at 25°C
Boiling Point:555.5°Cat760mmHg
Flash Point:289.7°C
Density:1.153g/cm³

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1-(4-methoxyphenyl)-N-(tritylsulfanyl)methanamine

There total 3 articles about 1-(4-methoxyphenyl)-N-(tritylsulfanyl)methanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 86864-35-9
C₂₇H₂₃NOS

: 86864-58-6
N-(4-Methoxy-benzyl)-S-trityl-thiohydroxylamine

Guidance literature:: With sodium cyanoborohydride; trifluoroacetic acid; In tetrahydrofuran; Ambient temperature; pH 4-5, indicator Bromocresol Green or pH 5-6, indicator Chlorophenol Red;
DOI:10.1021/jo00168a031

Reference yield:

: 3695-77-0
triphenylmethanethiol

: 86864-58-6
N-(4-Methoxy-benzyl)-S-trityl-thiohydroxylamine

Guidance literature:: Multi-step reaction with 4 steps

1: 88 percent / Sulfuryl chloride / toluene; diethyl ether / 2 h / 0 °C

2: 78 percent / 29 percent NH₄OH/H₂O / CH₂Cl₂ / 0 °C

3: 98 percent / Pyridinium p-toluenesulfonate, (PPTS)/anhydr. MgSO₄ / CH₂Cl₂ / 2 h / Ambient temperature

4: 100 percent / NaBH₃CN/1percent CF₃COOH / tetrahydrofuran / Ambient temperature; pH 4-5, indicator Bromocresol Green or pH 5-6, indicator Chlorophenol Red

With ammonium hydroxide; sulfuryl dichloride; water; pyridinium p-toluenesulfonate; sodium cyanoborohydride; magnesium sulfate; trifluoroacetic acid; In tetrahydrofuran; diethyl ether; dichloromethane; toluene;
DOI:10.1021/jo00168a031

Reference yield:

: 24165-03-5
tritylsulfenyl chloride

: 86864-58-6
N-(4-Methoxy-benzyl)-S-trityl-thiohydroxylamine

Guidance literature:: Multi-step reaction with 3 steps

1: 78 percent / 29 percent NH₄OH/H₂O / CH₂Cl₂ / 0 °C

2: 98 percent / Pyridinium p-toluenesulfonate, (PPTS)/anhydr. MgSO₄ / CH₂Cl₂ / 2 h / Ambient temperature

3: 100 percent / NaBH₃CN/1percent CF₃COOH / tetrahydrofuran / Ambient temperature; pH 4-5, indicator Bromocresol Green or pH 5-6, indicator Chlorophenol Red

With ammonium hydroxide; water; pyridinium p-toluenesulfonate; sodium cyanoborohydride; magnesium sulfate; trifluoroacetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00168a031