TRIPHENYLMETHANESULFENYL CHLORIDE

Base Information

• Chemical Name: TRIPHENYLMETHANESULFENYL CHLORIDE
• CAS No.: 24165-03-5
• Molecular Formula: C19H15ClS
• Molecular Weight: 310.847
• Hs Code.: 2930909090
• Mol file: 24165-03-5.mol

Synonyms:TRITYLSULFENYL CHLORIDE;TRIPHENYLMETHANESULFENYL CHLORIDE

Chemical Property of TRIPHENYLMETHANESULFENYL CHLORIDE

Chemical Property:

• Vapor Pressure: 6.34E-07mmHg at 25°C
• Melting Point: 137°C
• Boiling Point: 421.5°Cat760mmHg
• Flash Point: 192.8°C
• PSA: 25.30000
• Density: 1.204g/cm³
• LogP: 5.86550
• Storage Temp.: Refrigerator
• Solubility.: Dichloromethane, Ethyl Acetate, Methanol

Purity/Quality:

98% ^*data from raw suppliers

Triphenylmethanesulfenyl Chloride ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Intermediate in the preparation of precursors for cyclic polysulfides.

Technology Process of TRIPHENYLMETHANESULFENYL CHLORIDE

There total 4 articles about TRIPHENYLMETHANESULFENYL CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

triphenylmethanethiol (3695-77-0) → tritylsulfenyl chloride (24165-03-5)

Guidance literature:

With sulfuryl dichloride; In diethyl ether; toluene; at 0 ℃; for 2h;

DOI:10.1021/jo00168a031

Reference yield: 63.0%

triphenylmethyl-thiolate (78601-58-8) → tritylsulfenyl chloride (24165-03-5)

Guidance literature:

With 2-chloro-2-nitro-propane; In methanol; Irradiation;

DOI:10.1016/S0040-4039(01)90375-2

Reference yield:

sulfuryl dichloride (7791-25-5) + diethyl ether (60-29-7,927820-24-4) + triphenylmethanethiol (3695-77-0) → tritylsulfenyl chloride (24165-03-5)

Guidance literature:

upstream raw materials:

triphenylmethanethiol

triphenylmethyl-thiolate

sulfuryl dichloride

diethyl ether

Downstream raw materials:

ditrityl disulfide

triphenyl-methanesulfenic acid phenyl ester

Triphenylmethanesulfenamide

N-Tritylsulfenyl-Gly-OMe