7,12-bis(acetyloxy)-2,3,9,10-tetramethoxy-5,6-dimethylbenzo[b]phenanthridinium perchlorate

Base Information

• Chemical Name: 7,12-bis(acetyloxy)-2,3,9,10-tetramethoxy-5,6-dimethylbenzo[b]phenanthridinium perchlorate
• CAS No.: 98207-92-2
• Molecular Formula: C₂₇H₂₈NO₈*ClO₄
• Molecular Weight: 593.972
• Mol file: 98207-92-2.mol

Synonyms:7,12-Diacetoxy-5,6-dimethyl-2,3,9,10-tetramethoxybenzo(b)phenanthridinium perchlorate;7,12-Bis(acetyloxy)-5,6-dimethyl-2,3,9,10-tetramethoxybenzo(b)phenanthridinium perchlorate;BENZO(b)PHENANTHRIDINIUM, 7,12-BIS(ACETYLOXY)-5,6-DIMETHYL-2,3,9,10-TETRAMETHOXY;

Chemical Property of 7,12-bis(acetyloxy)-2,3,9,10-tetramethoxy-5,6-dimethylbenzo[b]phenanthridinium perchlorate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 7,12-bis(acetyloxy)-2,3,9,10-tetramethoxy-5,6-dimethylbenzo[b]phenanthridinium perchlorate

There total 8 articles about 7,12-bis(acetyloxy)-2,3,9,10-tetramethoxy-5,6-dimethylbenzo[b]phenanthridinium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(3',4'-dimethoxyphenyl)-6,7-dimethoxy-3-hydroxy-1,4-dihydro-1,4-naphthalenedione (40940-48-5) → 7,12-Diacetoxy-5,6-dimethyl-2,3,9,10-tetramethoxybenzophenanthridinium perchlorate (98207-92-2)

Guidance literature:

Multi-step reaction with 4 steps

1: 0.12 g / diethyl ether / 20 h / 20 °C

2: 83.5 percent / ethanol; H₂O

3: 1.) NaBH₄ / 1.) ethanol, reflux, 2.) heating

4: 1.) POCl₃, 2.) 57percent HClO₄ / 1.) reflux, 2.) room temperature

With sodium tetrahydroborate; perchloric acid; trichlorophosphate; In diethyl ether; ethanol; water;

Reference yield:

ethyl 2-<2'-<1''-(3,4-dimethoxyphenyl)-2''-oxoethyl>-4',5'-dimethoxyphenyl>acetic acid (40940-49-6) → 7,12-Diacetoxy-5,6-dimethyl-2,3,9,10-tetramethoxybenzophenanthridinium perchlorate (98207-92-2)

Guidance literature:

Multi-step reaction with 5 steps

1: 63.2 percent / 20percent NaOH / ethanol / 19 h / 20 °C

2: 0.12 g / diethyl ether / 20 h / 20 °C

3: 83.5 percent / ethanol; H₂O

4: 1.) NaBH₄ / 1.) ethanol, reflux, 2.) heating

5: 1.) POCl₃, 2.) 57percent HClO₄ / 1.) reflux, 2.) room temperature

With sodium hydroxide; sodium tetrahydroborate; perchloric acid; trichlorophosphate; In diethyl ether; ethanol; water;

Reference yield:

2-methoxy-6,7-dimethoxy-3-(3,4-dimethoxyphenyl)-1,4-naphthoquinone (98207-87-5) → 7,12-Diacetoxy-5,6-dimethyl-2,3,9,10-tetramethoxybenzophenanthridinium perchlorate (98207-92-2)

Guidance literature:

Multi-step reaction with 3 steps

1: 83.5 percent / ethanol; H₂O

2: 1.) NaBH₄ / 1.) ethanol, reflux, 2.) heating

3: 1.) POCl₃, 2.) 57percent HClO₄ / 1.) reflux, 2.) room temperature

With sodium tetrahydroborate; perchloric acid; trichlorophosphate; In ethanol; water;

upstream raw materials:

2-(N-Acetyl-N-methylamino)-1,4-diacetoxy-3-(3,4-dimethoxyphenyl)-6,7-dimethoxynaphthalene

(3,4-Dimethoxyphenyl)acetic acid

2-(3',4'-dimethoxyphenyl)-6,7-dimethoxy-3-hydroxy-1,4-dihydro-1,4-naphthalenedione

o-homoveratroylhomoveratric acid