1,7-Dimethyl-9,10-dihydrophenanthrene-2,6-diol

Base Information

Chemical Name:1,7-Dimethyl-9,10-dihydrophenanthrene-2,6-diol
CAS No.:54278-83-0
Molecular Formula:C16H16O2
Molecular Weight:240.3
Hs Code.:
DSSTox Substance ID:DTXSID70415824
Nikkaji Number:J12.366H
Wikidata:Q82224838
Mol file:54278-83-0.mol

Synonyms:1,7-dimethyl-9,10-dihydrophenanthrene-2,6-diol;54278-83-0;Micandrol B;DTXSID70415824;InChI=1/C16H16O2/c1-9-7-11-3-4-12-10(2)15(17)6-5-13(12)14(11)8-16(9)18/h5-8,17-18H,3-4H2,1-2H

Suppliers and Price of 1,7-Dimethyl-9,10-dihydrophenanthrene-2,6-diol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 1,7-Dimethyl-9,10-dihydrophenanthrene-2,6-diol

Chemical Property:

PSA：40.46000
LogP:3.48020
XLogP3:3.9
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:240.115029749
Heavy Atom Count:18
Complexity:304

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC2=C(C=C1O)C3=C(CC2)C(=C(C=C3)O)C

Technology Process of 1,7-Dimethyl-9,10-dihydrophenanthrene-2,6-diol

There total 9 articles about 1,7-Dimethyl-9,10-dihydrophenanthrene-2,6-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 54278-82-9
micandrol-A

: 54278-83-0
micandrol-B

Guidance literature:: With hydrogen; palladium on activated charcoal; In acetic acid;
DOI:10.1016/0031-9422(74)80119-6

Reference yield:

: 40794-04-5
1-chloro-3-methoxy-4-methylbenzene

: 54278-83-0
micandrol-B

Guidance literature:: Multi-step reaction with 8 steps

1: 71.1 g / HCl (gas), zinc chloride, sodium chloride / diethyl ether; H₂O / 1.) 22 - 23 deg C, 2.) 12 h

2: 74.0 g / dimethylformamide / 17 h / 80 °C

3: 58.1 g / sodium hydroxide / H₂O; methanol / 1.5 h / 0 °C

4: manganese dioxide / benzene / 17 h / Heating

5: methanol; dimethylformamide / 0.5 h / 90 °C

6: 420 mg / magnesium / tetrahydrofuran / 17 h / Heating

7: 146 mg / hydrogen / palladized charcoal / ethyl acetate / 120 h

8: 110 mg / boron tribromide / CH₂Cl₂ / 2.5 h

With hydrogenchloride; manganese(IV) oxide; sodium hydroxide; hydrogen; boron tribromide; magnesium; sodium chloride; zinc(II) chloride; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; benzene;

Reference yield:

: 54331-31-6
2,6-dimethoxy-1,7-dimethylphenanthrene

: 54278-83-0
micandrol-B

Guidance literature:: Multi-step reaction with 2 steps

1: 146 mg / hydrogen / palladized charcoal / ethyl acetate / 120 h

2: 110 mg / boron tribromide / CH₂Cl₂ / 2.5 h

With hydrogen; boron tribromide; palladium on activated charcoal; In dichloromethane; ethyl acetate;