(2-Pyridylmethyl)lithium

Base Information

Chemical Name:(2-Pyridylmethyl)lithium
CAS No.:1749-29-7
Molecular Formula:C6H6 N . Li
Molecular Weight:99.0613
Hs Code.:2933399090
European Community (EC) Number:217-134-2
Mol file:1749-29-7.mol

Synonyms:(2-Pyridylmethyl)lithium;EINECS 217-134-2;1749-29-7;lithium;2-methanidylpyridine;picolinyl lithium;2-picolyllithium;2-picolyl lithium;IECQSDZMYBSZAV-UHFFFAOYSA-N

Suppliers and Price of (2-Pyridylmethyl)lithium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 7 raw suppliers

Chemical Property of (2-Pyridylmethyl)lithium

Chemical Property:

Boiling Point:127.5°Cat760mmHg
Flash Point:26.1°C
PSA：12.36000
Density:g/cm³
LogP:0.89310
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:99.06602763
Heavy Atom Count:8
Complexity:56.5

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[Li+].[CH2-]C1=CC=CC=N1
General Description (2-Pyridylmethyl)lithium, also known as 2-picolyllithium, is a reactive organolithium compound characterized by restricted methylene rotation, as evidenced by its high activation energy (~93 kJ mol^-1) and entropy (~95 J K^-1 mol^-1). It serves as a nucleophile in synthetic chemistry, participating in reactions such as nucleophilic addition to imines in the formation of Fe(iv) alkylidene complexes. Additionally, it reacts with vinyl(tert-butyl)acetylene to yield pyridylallene derivatives. Its complexation behavior with lithium salts has been studied in both solid-state and solution phases, revealing dynamic structural changes in coordinating solvents.

Technology Process of (2-Pyridylmethyl)lithium

There total 5 articles about (2-Pyridylmethyl)lithium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%