Iron, eta4-1,1-dimethylsilole tricarbonyl

Base Information

• Chemical Name: Iron, eta4-1,1-dimethylsilole tricarbonyl
• CAS No.: 85944-69-0
• Molecular Formula: C₉H₁₀FeO₃Si
• Molecular Weight: 250.109
• Mol file: 85944-69-0.mol

Synonyms:

Chemical Property of Iron, eta4-1,1-dimethylsilole tricarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Iron, eta4-1,1-dimethylsilole tricarbonyl

There total 1 articles about Iron, eta4-1,1-dimethylsilole tricarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

diiron nonacarbonyl (15321-51-4) + dimethyl-1,1-silole (18135-88-1) → triiron dodecarbonyl (17685-52-8) + Fe(CO)3(C4H4Si(CH3)2) (85944-69-0)

Guidance literature:

In benzene; stirring (60°C, 3-5 h); filtration, partial evapn. (40 Torr), chromy. (SiO2, hexane/C6H6=4:1); elem. anal.;

DOI:10.1016/0022-328X(85)80300-4

Reference yield: 42.0%

Fe(CO)3(C4H4Si(CH3)2) (85944-69-0) → Fe(CO)2(P(C6H5)3)(C4H4Si(CH3)2) (87640-58-2)

Guidance literature:

With triphenylphosphine; In hexane; Irradiation (UV/VIS); irradiation of the Fe-complex with an equimolar amount of PPh3; chromy. (silica gel, hexane), crystn.; elem. anal.;

DOI:10.1021/om50006a043

Reference yield: 42.0%

Fe(CO)3(C4H4Si(CH3)2) (85944-69-0) + triphenylphosphine (603-35-0) → Fe(CO)2(P(C6H5)3)(C4H4Si(CH3)2) (87640-58-2)

Guidance literature:

In hexane; Irradiation (UV/VIS); (N2); UV irradn. of soln. for 8 h; solvent pumped off; residue chromd. on silica gel with hexane/benzene (1/1); orange-yellow band collected; solvent pumped off; residue crystd. from hexane at -20 °C; elem. anal.;

DOI:10.1021/om00150a005

upstream raw materials:

diiron nonacarbonyl

dimethyl-1,1-silole

Downstream raw materials:

Fe(CO)2(P(C₆H₅)3)(C₄H₄Si(CH₃)2)