Azane;methylsulfinylmethane;ruthenium(3+);trichloride

Base Information

• Chemical Name: Azane;methylsulfinylmethane;ruthenium(3+);trichloride
• CAS No.: 134876-10-1
• Molecular Formula: C₄H₁₅Cl₃NO₂RuS₂
• Molecular Weight: 380.73
• DSSTox Substance ID: DTXSID20928792
• Mol file: 134876-10-1.mol

Synonyms:BBR 2382;BBR-2382;BBR2382;trichlorobisdimethylsulphoxideaminoruthenium (III)

Chemical Property of Azane;methylsulfinylmethane;ruthenium(3+);trichloride

Chemical Property:

• Vapor Pressure: 0.805mmHg at 25°C
• Boiling Point: 189°Cat760mmHg
• Flash Point: 85°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 379.865319
• Heavy Atom Count: 13
• Complexity: 29

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CS(=O)C.CS(=O)C.N.[Cl-].[Cl-].[Cl-].[Ru+3]

Technology Process of Azane;methylsulfinylmethane;ruthenium(3+);trichloride

There total 1 articles about Azane;methylsulfinylmethane;ruthenium(3+);trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

mer-trichlorotris(dimethylsulfoxide)ruthenium(III) (118541-65-4,118541-66-5,131759-89-2,131896-63-4,135972-16-6,30066-43-4,65982-39-0,76647-72-8) + ammonia (7664-41-7) → mer-trichloro-cis-bis(dimethyl sulfoxide)(ammonia)ruthenium(III) (134659-65-7,134876-10-1,147931-16-6)

Guidance literature:

In dichloromethane; dimethyl sulfoxide; dissolving of 1.1 mmol (mer-RuCl3((CH3)2SO)3) in a mixture of CH2CL2 and DMSO; connection of the flask to a vac. line and then to a reservoir of gaseous ammonia; pptn. after a few minutes at room temperature; filtration after 30 min;; washing with cold CH2Cl2 and diethyl ether; drying in vac. at room temperature; elem. anal.;;

DOI:10.1016/S0020-1693(00)81659-X

upstream raw materials:

mer-trichlorotris(dimethylsulfoxide)ruthenium(III)

ammonia