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Product FOB Price Min.Order Supply Ability Supplier
AMMonia (ca. 4% in Methanol, ca. 2.0Mol/L)
Cas No: 7664-41-7
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
Factory Supply Ammonia, anhydrous
Cas No: 7664-41-7
No Data 1 1 Ality Chemical Corporation Contact Supplier
AMMonia (ca. 4% in Methanol, ca. 2.0Mol/L) CAS NO.7664-41-7
Cas No: 7664-41-7
USD $ 1.0-3.0 / Kilogram 1 Kilogram 10 Kilogram/Day Hebei yanxi chemical co.,LTD. Contact Supplier
TIANFU-CHEM- Ammonia
Cas No: 7664-41-7
No Data 1 Kilogram 10 Metric Ton/Month Henan Tianfu Chemical Co., Ltd. Contact Supplier
CAS NO.:7664-41-7
Cas No: 7664-41-7
No Data No Data 10000 Metric Ton/Month Henan Wentao Chemical Product Co., Ltd. Contact Supplier
Ammonia
Cas No: 7664-41-7
No Data 1 Kilogram 1 Metric Ton/Day Shandong Hanjiang Chemical Co., Ltd. Contact Supplier
7664-41-7 Liquid Ammonia CAS NO.7664-41-7
Cas No: 7664-41-7
No Data 10 Gram 500 Kilogram/Month Changchun Artel lmport and Export trade company Contact Supplier
Liquid Anhydrous Ammonia for Nitrogen Fetilizer CAS NO.7664-41-7 CAS NO.7664-41-7
Cas No: 7664-41-7
No Data 1 Gram 10 Metric Ton/Month Hebei Guanlang Biotechnology Co., Ltd. Contact Supplier
Manufacture Ammonia CAS NO.7664-41-7
Cas No: 7664-41-7
USD $ 50.0-100.0 / Gram 1 Gram 10000 Metric Ton/Month Wuhan Monad Medicine Tech Co.,LTD Contact Supplier
Ammonia,
Cas No: 7664-41-7
USD $ 1550.0-1600.0 / Kilogram 1 Kilogram 50 Kilogram/Month Career Henan Chemical Co Contact Supplier

7664-41-7 Usage

Safety Profile

A human poison by anunspecified route. Poison experimentally by inhalation. Aneye, mucous membrane, and systemic irritant byinhalation. Mutation data reported. A common aircontaminant. Difficult to ignite. Explosion hazard whenexposed to flame or in
InChI:InChI=1/H3N/h1H3

7664-41-7 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (A1884)  Ammonia (ca. 4% in Methanol, ca. 2.0mol/L)   7664-41-7 500mL 845.00CNY Detail
TCI America (A2236)  Ammonia (ca. 4% in Ethanol, ca. 2.0mol/L)   7664-41-7 500mL 860.00CNY Detail
TCI America (A2237)  Ammonia (ca. 4% in Isopropyl Alcohol, ca. 2.0mol/L)   7664-41-7 500mL 860.00CNY Detail
Alfa Aesar (H27080)  Ammonia, 2M in methanol    7664-41-7 100ml 483.0CNY Detail
Alfa Aesar (H27080)  Ammonia, 2M in methanol    7664-41-7 1000ml 2353.0CNY Detail
Sigma-Aldrich (407666)  Ammoniasolution  0.5 M in dioxane 7664-41-7 407666-100ML 950.04CNY Detail
Sigma-Aldrich (407666)  Ammoniasolution  0.5 M in dioxane 7664-41-7 407666-800ML 3,280.68CNY Detail
Sigma-Aldrich (392685)  Ammoniasolution  2.0 M in ethanol 7664-41-7 392685-100ML 642.33CNY Detail
Sigma-Aldrich (392685)  Ammoniasolution  2.0 M in ethanol 7664-41-7 392685-800ML 2,698.02CNY Detail
Sigma-Aldrich (392693)  Ammoniasolution  2.0 M in isopropanol 7664-41-7 392693-100ML 724.23CNY Detail
Sigma-Aldrich (392693)  Ammoniasolution  2.0 M in isopropanol 7664-41-7 392693-800ML 2,951.91CNY Detail
Aldrich (718939)  Ammoniasolution  0.4 M in THF 7664-41-7 718939-100ML 1,026.09CNY Detail

7664-41-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Ammonia

1.2 Other means of identification

Product number -
Other names Ammonia

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Inorganic substances
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7664-41-7 SDS

7664-41-7Synthetic route

nitric acid
7697-37-2

nitric acid

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
In water Electrolysis; Cu-cathode, in presence of H2SO4;;100%
With aluminium In water at elevated pressure;;0%
With aluminium In water only small amounts of NH3 in dild. HNO3 (5%-20%) at atmospheric pressure;;
barium cyanide

barium cyanide

A

ammonia
7664-41-7

ammonia

B

barium(II) hydroxide

barium(II) hydroxide

Conditions
ConditionsYield
With water byproducts: CO; heating with H2O vapour to 300°C;A 100%
B n/a
With H2O
cis,trans-[WCl2(NNC5H2Me3-2,4,6)(C2H4)(PMe2Ph)2][BF4]
180893-21-4

cis,trans-[WCl2(NNC5H2Me3-2,4,6)(C2H4)(PMe2Ph)2][BF4]

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With KOH In methanol byproducts: 2,4,6-trimethylpyridine; N2-atmosphere; excess KOH, stirring at room temp. for 1 h; collection of pyridine derivative (cold trap), colorimetry of NH3;100%
cis,trans-[WCl2(NNC5H4OMe-4)(C2H4)(PMe2Ph)2][ClO4] * 0.5(CH2Cl2)

cis,trans-[WCl2(NNC5H4OMe-4)(C2H4)(PMe2Ph)2][ClO4] * 0.5(CH2Cl2)

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With KOH In methanol byproducts: 4-methoxypyridine; N2-atmosphere; excess KOH, stirring at room temp. for 1 h; collection of pyridine derivative (cold trap), colorimetry of NH3;100%
C10H15NO9

C10H15NO9

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
Alkaline conditions;100%
Conditions
ConditionsYield
With oxygen In water at 200℃; Catalytic behavior; Temperature; Flow reactor; Inert atmosphere;A 100%
B 100%
(methyl)3boron*NH3

(methyl)3boron*NH3

A

trimethylborane
593-90-8

trimethylborane

B

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
at 130.0°C, 74.1 Torr equilibrium;A 99.6%
B 99.6%
at 130.0°C, 74.1 Torr equilibrium;A 99.6%
B 99.6%
at 54.8°C, 57.6 Torr equilibrium;A 90.8%
B 90.8%
at 54.8°C, 57.6 Torr equilibrium;A 90.8%
B 90.8%
trans-[W(NNH2)(OSO2CF3)(PMe2Ph)4](OSO2CF3)

trans-[W(NNH2)(OSO2CF3)(PMe2Ph)4](OSO2CF3)

hydrogen
1333-74-0

hydrogen

A

ammonia
7664-41-7

ammonia

B

hydrazine
302-01-2

hydrazine

Conditions
ConditionsYield
With [(C5H5)Mo(S2CH2)(S)(SH)Mo(C5H5)](OSO2CF3) In tetrahydrofuran Schlenk techniques; 10 equiv. of Mo complex in THF stirred at 25°C for 5 min under N2; N2 replaced by 1 atm of H2; W complex added portionwise; stirred at 25°C for 24 h and then at 55°C for 24 h; evapd. under reduced pressure; distillate trapped in dilute H2SO4 soln.;residue extd. with H2O, treated with activated charcoal, filtered throu gh Celite;A 99%
B 1%
hydrogen
1333-74-0

hydrogen

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With catalyst: Ni(2+)Y zeolite In neat (no solvent) reduction of very dild. mixt. of NO/NO2 in gas mixt. of N2/H2 on zeolite catalyst (300°C reaction temp.); gas chromy. (dimethylsulfolane coated diatomite);99%
With catalyst: industrial nickel methanation catalyst In neat (no solvent) reduction of very dild. mixt. of NO/NO2 in gas mixt. of N2/H2 on zeolite catalyst (300°C reaction temp.); gas chromy. (dimethylsulfolane coated diatomite);99%
With catalyst: phthalocyanineNiY zeolite In neat (no solvent) reduction of very dild. mixt. of NO/NO2 in gas mixt. of N2/H2 on zeolite catalyst (230°C reaction temp.); gas chromy. (dimethylsulfolane coated diatomite);94%
With catalyst: NiY zeolite In neat (no solvent) reduction of very dild. mixt. of NO/NO2 in gas mixt. of N2/H2 on zeolite catalyst (450°C reaction temp.); gas chromy. (dimethylsulfolane coated diatomite);84%
trans-bis[1,2-bis(diphenylphosphino)ethane]bis(dinitrogen)tungsten(0)

trans-bis[1,2-bis(diphenylphosphino)ethane]bis(dinitrogen)tungsten(0)

[(η5-C5H5)Mo(μ2-S2CH2)(μ-S)(μ-SH)Mo(η5-C5H5)](OSO2CF3)

[(η5-C5H5)Mo(μ2-S2CH2)(μ-S)(μ-SH)Mo(η5-C5H5)](OSO2CF3)

hydrogen
1333-74-0

hydrogen

A

[(η5-C5H5)Mo(μ2-S2CH2)(μ-S)2Mo(η5-C5H5)]

[(η5-C5H5)Mo(μ2-S2CH2)(μ-S)2Mo(η5-C5H5)]

trans-bis[1,2-bis(diphenylphosphino)ethane]hydrazido(triflato)tungsten triflate

trans-bis[1,2-bis(diphenylphosphino)ethane]hydrazido(triflato)tungsten triflate

C

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
In tetrahydrofuran Schlenk techniques; 2 equiv. of Mo complex in THF stirred at 25°Cfor 5 min under N2; N2 replaced by 1 atm of H2; W complex added portion wise; stirred at 25°C for 1 h; solvent removed under vac.; dissolved in THF-d8; not isolated; detd. by NMR spectra;A 84%
B 99%
C 0%
Co(C5H4CO2)2(1-)*NH4(1+)*3H2O=[Co(C5H4CO2)2]NH4*3H2O

Co(C5H4CO2)2(1-)*NH4(1+)*3H2O=[Co(C5H4CO2)2]NH4*3H2O

A

Co(III)(η5-C5H4COOH)(η5-C5H4COO)
232598-14-0

Co(III)(η5-C5H4COOH)(η5-C5H4COO)

B

ammonia
7664-41-7

ammonia

C

water
7732-18-5

water

Conditions
ConditionsYield
In neat (no solvent) heated at 373 K for 1 h; XRD;A 99%
B n/a
C n/a
Co(C5H4CO2)2(1-)*NH4(1+)*3.5H2O=[Co(C5H4CO2)2]NH4*3.5H2O

Co(C5H4CO2)2(1-)*NH4(1+)*3.5H2O=[Co(C5H4CO2)2]NH4*3.5H2O

A

Co(III)(η5-C5H4COOH)(η5-C5H4COO)
232598-14-0

Co(III)(η5-C5H4COOH)(η5-C5H4COO)

B

ammonia
7664-41-7

ammonia

C

water
7732-18-5

water

Conditions
ConditionsYield
In neat (no solvent) heated at 373 K for 1 h; XRD;A 99%
B n/a
C n/a
[molybdenum(nitride)(iodide)(2,6-bis(di-tert-butylphosphinomethyl)pyridine)]

[molybdenum(nitride)(iodide)(2,6-bis(di-tert-butylphosphinomethyl)pyridine)]

ethylene glycol
107-21-1

ethylene glycol

A

ammonia
7664-41-7

ammonia

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With samarium diiodide bis(tetrahydrofuran) In tetrahydrofuran at 20℃; under 760.051 Torr; for 2h; Inert atmosphere; Schlenk technique; Glovebox;A 99%
B 47%
nitrogen
7727-37-9

nitrogen

hydrogen
1333-74-0

hydrogen

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
Casale method; at 450-500°C; space velocity 16000-25000; contact time 13.5-19 sec;98.7%
With catalsyt: Fe-Al-cyanides Mont-Cenis method; very pure reactants used; at 90-100 atm, 350-430°C; deep cooling;98%
Casale method; at 450-500°C; space velocity 16000-25000; contact time 13.5-19 sec;98.7%
hydrazine
302-01-2

hydrazine

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
(WC5(CH3)5(CH3)3NH2NH2)(1+) In tetrahydrofuran room temp.; N2 atm., 2 equiv of N2H4;; dependence of yield from aded equiv of N2H4;;98%
(MoC5(CH3)5(CH3)3NH2NH2)(1+) In tetrahydrofuran room temp.; N2 atm., 2 equiv of N2H4;; dependence of yield from added equiv of N2H4;;95%
W(η5-C5Me5)Me3(NNH2) In tetrahydrofuran room temp.; N2 atm., 3 equiv of N2H4;; dependence of yield from added equiv of N2H4;;84%
[Cp*Fe(μ-η2:η2-benzene-1,2-dithiolate)(μ-NH2)FeCp*][BPh4]

[Cp*Fe(μ-η2:η2-benzene-1,2-dithiolate)(μ-NH2)FeCp*][BPh4]

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With cobaltocene; water In tetrahydrofuran at 20℃; for 12h; Reagent/catalyst;98%
1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)-3-quinoline carboxylic acid
70458-96-7

1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)-3-quinoline carboxylic acid

A

formaldehyd
50-00-0

formaldehyd

B

ammonia
7664-41-7

ammonia

C

6-fluoro-7-amino-1-ethyl-1,4-dihydro-4-oxo-3-quinolinecarboxylic acid
75001-63-7

6-fluoro-7-amino-1-ethyl-1,4-dihydro-4-oxo-3-quinolinecarboxylic acid

Conditions
ConditionsYield
With potassium permanganate; cetyltrimethylammonim bromide; acetic acid In water; acetonitrile at 24.84℃; Kinetics; Catalytic behavior; Mechanism; Thermodynamic data; Activation energy; Temperature; Concentration; Solvent; UV-irradiation;A n/a
B n/a
C 98%
hydrogen
1333-74-0

hydrogen

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

A

nitrogen
7727-37-9

nitrogen

B

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With catalyst: industrial nickel methanation catalyst In neat (no solvent) reduction of mixt. of NO/NO2 in gas mixt. of N2/H2 on zeolite catalyst (pretreated in H2 at 550°C, 200°C reaction temp.); gas chromy. (dimethylsulfolane coated diatomite);A 96%
B 0%
With catalyst: industrial nickel methanation catalyst In neat (no solvent) reduction of mixt. of NO/NO2 in gas mixt. of N2/H2 on zeolite catalyst (pretreated in H2 at 300°C, 200°C reaction temp.); gas chromy. (dimethylsulfolane coated diatomite);A 92.5%
B 7.5%
With catalyst: industrial nickel methanation catalyst In neat (no solvent) reduction of mixt. of NO/NO2 in gas mixt. of N2/H2 on zeolite catalyst (pretreated in H2 at 300°C, 150°C reaction temp.); gas chromy. (dimethylsulfolane coated diatomite);A 91%
B 0%
C88H109Cl2Fe4K2N10

C88H109Cl2Fe4K2N10

water
7732-18-5

water

A

C44H56Fe2N4O2

C44H56Fe2N4O2

B

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
In tetrahydrofuran at -96 - 20℃;A n/a
B 96%
sodium azide

sodium azide

A

nitrogen

nitrogen

B

ammonia
7664-41-7

ammonia

C

hydrazine
302-01-2

hydrazine

Conditions
ConditionsYield
With hydrogenchloride; tin(ll) chloride In waterA n/a
B 94%
C 0%
With HCl; SnCl2 In waterA n/a
B 94%
C 0%
nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With hydrogen at 700°C, with 3% Pd;94%
With hydrogen at 400°C, with 3% Pd;83%
With hydrogen at 600°C, with 3% Pd;78%
cis,trans-[WCl2(NNC5H4OMe-4)(CO)(PMe2Ph)2][ClO4]
225245-55-6

cis,trans-[WCl2(NNC5H4OMe-4)(CO)(PMe2Ph)2][ClO4]

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With KOH In methanol byproducts: 4-methoxypyridine; N2-atmosphere; excess KOH, stirring at room temp. for 1 h; collection of pyridine derivative (cold trap), colorimetry of NH3;94%
cis,trans-[WCl2(NNC5H2Me3-2,4,6)(CO)(PMe2Ph)2][BF4]
180893-19-0

cis,trans-[WCl2(NNC5H2Me3-2,4,6)(CO)(PMe2Ph)2][BF4]

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With KOH In methanol byproducts: 2,4,6-trimethylpyridine; N2-atmosphere; excess KOH, stirring at room temp. for 1 h; collection of pyridine derivative (cold trap), colorimetry of NH3;94%
magnesium silicide

magnesium silicide

ammonium chloride

ammonium chloride

silicon nitride

silicon nitride

B

ammonia
7664-41-7

ammonia

C

hydrogen
1333-74-0

hydrogen

D

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In neat (no solvent) High Pressure; mixed, sealed in autoclave under Ar, heated at 450, 500, 550, and 600 °C for 10 h; washed with water, dried in vac. at 70 °C for 12 h; powder XRD;A 93%
B n/a
C n/a
D n/a
(WC5(CH3)5(CH3)3NH2NH2)(1+)*(OSO2CF3)(1-)

(WC5(CH3)5(CH3)3NH2NH2)(1+)*(OSO2CF3)(1-)

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With CoCp; 2,6-lutidine hydrochloride In tetrahydrofuran THF, room temp., N2 atm.; 12 equiv of CoCp2 and 16 equiv of lutidine hydrichloride; mixt. was stirred for approx. 15 h;; The ammonia was quantified by the indophenol method;;92%
{W(η5-C5Me5)Me3(η1-NNH2)}

{W(η5-C5Me5)Me3(η1-NNH2)}

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With zinc amalgam; 2,6-lutidinium chloride; HCl In tetrahydrofuran inert atmosphere; cold (-40°C) THF addn. to mixt. of W-complex, zinc amalgam and proton source in Schlenk flask, stirring vigorously, soln. allowing to stand ca. 20 h at 25°C; HCl addn., solvent removal (vac.), residue treating with NaOH soln. in closed system under argon and soln. distn. into H2SO4 soln., or residue extn. with H2O, soln. filtration (Millipore); chem. anal.;92%
With Zn#Hg; H2; HCl In tetrahydrofuran nitrogen atmosphere; cold (-40°C) THF addn. to mixt. of W-complex, Zn#Hg and proton source in Schlenk flask, stirring vigorously, soln. allowing to stand ca. 20 h at 25°C; HCl addn., solvent removal (vac.), residue treating with NaOH soln. in closed system under argon and soln. distn. into H2SO4 soln., or residue extn. with H2O, soln. filtration (Millipore); chem. anal.;71%
With zinc amalgam; phenol; HCl In tetrahydrofuran inert atmosphere; cold (-40°C) THF addn. to mixt. of W-complex, zinc amalgam and proton source in Schlenk flask, stirring vigorously, soln. allowing to stand ca. 20 h at 25°C; HCl addn., solvent removal (vac.), residue treating with NaOH soln. in closed system under argon and soln. distn. into H2SO4 soln., or residue extn. with H2O, soln. filtration (Millipore); chem. anal.;65%
With zinc amalgam; 2,3,5-triisopropylbenzenethiol; HCl In tetrahydrofuran inert atmosphere; cold (-40°C) THF addn. to mixt. of W-complex, zinc amalgam and proton source in Schlenk flask, stirring vigorously, soln. allowing to stand ca. 20 h at 25°C; HCl addn., solvent removal (vac.), residue treating with NaOH soln. in closed system under argon and soln. distn. into H2SO4 soln., or residue extn. with H2O, soln. filtration (Millipore); chem. anal.;60%
{W(η5-C5Me5)Me3(η2-NH2NH2)}(OSO2CF3)

{W(η5-C5Me5)Me3(η2-NH2NH2)}(OSO2CF3)

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With cobaltocene; 2,6-lutidinium chloride; HCl In tetrahydrofuran inert atmosphere; cold (-40°C) THF addn. to mixt. of W-complex, cobaltocene and 2,6-lutidinium chloride in Schlenk flask, stirring vigorously, soln. allowing to stand ca. 20 h at 25°C; HCl addn., solvent removal (vac.), residue treating with NaOH soln. in closed system under argon and soln. distn. into H2SO4 soln., or residue extn. with H2O, soln. filtration (Millipore); chem. anal.;92%
With zinc amalgam; 2,6-lutidinium chloride; HCl In tetrahydrofuran inert atmosphere; cold (-40°C) THF addn. to mixt. of W-complex, zinc amalgam and 2,6-lutidinium chloride in Schlenk flask, stirring vigorously, soln. allowing to stand ca. 20 h at 25°C; HCl addn., solvent removal (vac.), residue treating with NaOH soln. in closed system under argon and soln. distn. into H2SO4 soln., or residue extn. with H2O, soln. filtration (Millipore); chem. anal.;91%
With zinc amalgam; phenol; HCl In tetrahydrofuran inert atmosphere; cold (-40°C) THF addn. to mixt. of W-complex, zinc amalgam and phenol in Schlenk flask, stirring vigorously, soln. allowing to stand ca. 20 h at 25°C; HCl addn., solvent removal (vac.), residue treating with NaOH soln. in closed system under argon and soln. distn. into H2SO4 soln., or residue extn. with H2O, soln. filtration (Millipore); chem. anal.;88%
With zinc amalgam; H2; HCl In tetrahydrofuran inert atmosphere; cold (-40°C) THF addn. to mixt. of W-complex, zinc amalgam and hydrogen as proton source in Schlenk flask, stirring vigorously, soln. allowing to stand ca. 20 h at 25°C; HCl addn., solvent removal (vac.), residue treating with NaOH soln. in closed system under argon and soln. distn. into H2SO4 soln., or residue extn. with H2O, soln. filtration (Millipore); chem. anal.;57%
With SnCl2; 2,6-lutidinium chloride; HCl In tetrahydrofuran inert atmosphere; cold (-40°C) THF addn. to mixt. of W-complex, SnCl2 and 2,6-lutidinium chloride in Schlenk flask, stirring vigorously, soln. allowing to stand ca. 20 h at 25°C; HCl addn., solvent removal (vac.), residue treating with NaOH soln. in closed system under argon and soln. distn. into H2SO4 soln., or residue extn. with H2O, soln. filtration (Millipore); chem. anal.;45%
cis,mer-[WBr2(NNC5H4OMe-4)(PMe2Ph)3][PF6]
225245-35-2

cis,mer-[WBr2(NNC5H4OMe-4)(PMe2Ph)3][PF6]

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With KOH In methanol byproducts: 4-methoxypyridine; N2-atmosphere; excess KOH, stirring at room temp. for 1 h; collection of pyridine derivative (cold trap), colorimetry of NH3;92%
nitrogen
7727-37-9

nitrogen

2,4,6-trimethylpyridinium trifluoromethanesulfonate

2,4,6-trimethylpyridinium trifluoromethanesulfonate

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With bis(pentamethylcyclopentadienyl)cobalt(II); [Mo(N)Cl(bis(di-tert-butylphosphinoethyl)phenylphosphine)] In toluene at 20℃; under 760.051 Torr; for 20h; Schlenk technique;92%
With bis(pentamethylcyclopentadienyl)cobalt(II); C25H44I3MoN2P2 In toluene at 20℃; under 760.051 Torr; for 20h; Catalytic behavior; Reagent/catalyst; Time; Inert atmosphere; Glovebox; Schlenk technique;82%
With bis(pentamethylcyclopentadienyl)cobalt(II); C40H65FeMoN7P2*C4H10O In toluene at 20℃; under 760.051 Torr; for 20h; Glovebox; Schlenk technique;
With bis(pentamethylcyclopentadienyl)cobalt(II); [molybdenum(iodide)3(2,6-bis(di-tert-butylphosphinomethyl)pyridine)] In toluene at 20℃; under 760.051 Torr; for 20h; Reagent/catalyst; Solvent; Concentration; Glovebox; Schlenk technique;91 %Spectr.
With bis(pentamethylcyclopentadienyl)chromium; C21H41Cl3MoN3P2 In toluene at 20℃; for 19h;
(η5-C5Me4SiMe3)2Ti(Cl)NH2

(η5-C5Me4SiMe3)2Ti(Cl)NH2

hydrogen
1333-74-0

hydrogen

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
With (η5-C5Me5)Rh(2-pyridylphenyl)H In tetrahydrofuran at 23℃; under 3040.2 Torr; for 120h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique;92%
ammonia
7664-41-7

ammonia

Cu[Au(CN)2]2(NH3)4

Cu[Au(CN)2]2(NH3)4

Conditions
ConditionsYield
Product distribution / selectivity;100%
sodium hypochlorite
7681-52-9

sodium hypochlorite

ammonia
7664-41-7

ammonia

ammonium chloride
12125-02-9

ammonium chloride

chloroamine
12190-75-9

chloroamine

Conditions
ConditionsYield
In water at -11 - -8℃; pH=~ 10;100%
In water at -15 - -7℃; pH=~ 10; Product distribution / selectivity;100%
In diethyl ether; water at -20 - -10℃; for 0.5h;
ammonium carbonate

ammonium carbonate

ammonia
7664-41-7

ammonia

sodium chloride
7647-14-5

sodium chloride

sodium carbonate
497-19-8

sodium carbonate

Conditions
ConditionsYield
In water NH3 passed into a soln. of (NH4)2CO3-NaCl until satn.; product free of Cl and NH3;100%
In water NH3 passed into a soln. of (NH4)2CO3-NaCl until satn.; product free of Cl and NH3;100%
nitrogen
7727-37-9

nitrogen

ammonia
7664-41-7

ammonia

benzene
71-43-2

benzene

hydrogen cyanide
74-90-8

hydrogen cyanide

Conditions
ConditionsYield
With catalyst: Pt-oxide at 1000°C;100%
platinum at 1000°C;100%
platinum at 800°C;62.8%
With catalyst: Pt-oxide at 800°C;62.8%
ammonia
7664-41-7

ammonia

rubidium

rubidium

rubidium amide

rubidium amide

Conditions
ConditionsYield
In ammonia byproducts: H2; react. of Rb in liq. NH3 at room temp. for 6-10 h;;100%
In ammonia byproducts: H2; NH3 (liquid); react. of Rb in liq. NH3 at room temp. for 6-10 h;;100%
ammonia
7664-41-7

ammonia

ytterbium

ytterbium

ytterbium(II) amide

ytterbium(II) amide

Conditions
ConditionsYield
Autoclave; Glovebox; Inert atmosphere; Schlenk technique;100%
at 50℃; for 72h; Autoclave; High pressure;56%
In neat (no solvent) Yb dissolved in liq. ammonia; soln. left to stand at 273 K for 1-12 h; ppt.;
In ammonia NH3 (liquid); (N2); Yb dissolved in liquid NH3;; soln. stand at 273 K; ppt.; ammonia removed; XRD;
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

ammonia
7664-41-7

ammonia

silicon nitride

silicon nitride

Conditions
ConditionsYield
Prepd. by laser chemical vapor pptn. at atmospheric pressure.;100%
In gas under Ar, in a low-pressure flow reactor;
thin film deposited on SiO2 substrate at 500-900 K, 1-10 Torr; AFM;
ammonia
7664-41-7

ammonia

Dichlorosilane
4109-96-0

Dichlorosilane

silicon nitride

silicon nitride

Conditions
ConditionsYield
Prepd. by laser chemical vapor pptn. at atmospheric pressure.;100%
In neat (no solvent) Kinetics; under Ar, in a low-pressure flow reactor at various condns.;
low pressure chemical vapor deposition at 820 °C;
ammonia
7664-41-7

ammonia

oxygen
80937-33-3

oxygen

A

nitrogen
7727-37-9

nitrogen

B

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

C

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
With oxygen In neat (no solvent) Fe-ZSM-5 catalyst prepared by ion exchange and heat-treated at 400, 425or 450 °C, 100 % NH3 conversion, 100 % N2 selectivity, 1000 ppm NH3 in 2 % O2-contg. He;A 100%
B 0%
C 0%
With catalyst:Fe-mordenite In neat (no solvent) Fe-mordenite catalyst prepared by ion exchange and heat-treated at 425 °C, 92 % NH3 conversion, 99 % N2 selectivity, 1000 ppm NH3 in 2 %O2-contg. He;A 92%
B n/a
C 0%
With catalyst:Fe-ZSM-5 In neat (no solvent) Fe-ZSM-5 catalyst prepared by ion exchange and heat-treated at 375 °C, 90 % NH3 conversion, 99 % N2 selectivity, 1000 ppm NH3 in 2 % O2-contg. He;A 90%
B n/a
C 0%
ammonia
7664-41-7

ammonia

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
byproducts: N2; red heat;100%
decompn., heated porcelain pipe, 1100.degreeC;75.7%
With catalyst: Ru/SiC In gas Kinetics; byproducts: N2; NH3 decompd. in integrated ceramic microreactor at 450-1000°C; analyzed by gas chromatograph (Porapak N, TCD detector);
phosphorus(V) nitride

phosphorus(V) nitride

ammonia
7664-41-7

ammonia

phosphorus(V) nitride imide
22722-08-3

phosphorus(V) nitride imide

Conditions
ConditionsYield
In neat (no solvent) 550°C, p(NH3)=6 kbar, 14 d; elem. anal.;100%
In neat (no solvent) heating (10-250 atm NH3, 870°C, several days);
hydriodic acid
7782-68-5

hydriodic acid

ammonia
7664-41-7

ammonia

ammonium dihydrogen trisiodate

ammonium dihydrogen trisiodate

Conditions
ConditionsYield
In water by evapn. soln. of 3 mol HIO3 + 1 mol NH3;100%
In water by evapn. soln. of 3 mol HIO3 + 1 mol NH3;100%
In water concd. HIO3 soln. (50%);
In water concd. HIO3 soln. (50%);
rubidium hydride

rubidium hydride

ammonia
7664-41-7

ammonia

rubidium amide
12141-27-4

rubidium amide

Conditions
ConditionsYield
In ammonia byproducts: H2; pressure: 1 atm (min.);;100%
In ammonia byproducts: H2; NH3 (liquid); pressure: 1 atm (min.);;100%
In neat (no solvent) byproducts: H2; react. of RbH and gaseous NH3 at ambient temp.;;
{NiCl2(Tri-{n-butyl}-phosphin)2}
19615-74-8, 30759-83-2, 15274-43-8, 16610-41-6

{NiCl2(Tri-{n-butyl}-phosphin)2}

ammonia
7664-41-7

ammonia

hexaamminenickel (II) chloride

hexaamminenickel (II) chloride

Conditions
ConditionsYield
In diethyl ether; ammonia byproducts: PBu3; absence of moisture; condensation of liquid NH3 into Ni-complex soln. (in ether), stirring (2 h); evapn. of NH3, filtration, distn. off of ether;100%
sulfur
10544-50-0

sulfur

sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

ammonia
7664-41-7

ammonia

ammonia borane complex
10043-11-5

ammonia borane complex

Conditions
ConditionsYield
In ammonia to NaBH4 in a flask at -40°C NH3 is condensed, then slowly S8 isadded (5 h), to the mixt. (after 3 h) CH2Cl2 is added, then the mixt. is warmed to room temp.; residue is extd. with CH2Cl2, the soln. is evapd., elem. anal.;100%
triisopropylborane
1776-66-5

triisopropylborane

ammonia
7664-41-7

ammonia

triisopropylborane-ammonia (1/1)

triisopropylborane-ammonia (1/1)

Conditions
ConditionsYield
In neat (no solvent) to triisopropyl borane added NH3 with vigorous stirring and cooling under dry Ar; mixt. stirred for 3 h; NMR;100%
bis(triphenylphosphine)dithiocyanatonickel(II)

bis(triphenylphosphine)dithiocyanatonickel(II)

ammonia
7664-41-7

ammonia

nickel(II) thiocyanate * 4 NH3

nickel(II) thiocyanate * 4 NH3

Conditions
ConditionsYield
In diethyl ether; ammonia byproducts: PPh3; absence of moisture; condensation of liquid NH3 into Ni-complex soln. (in ether), stirring (2 h); evapn. of NH3, filtration, distn. off of ether;100%
bis(2,4-pentanedionato)diaquonickel(II)

bis(2,4-pentanedionato)diaquonickel(II)

ammonia
7664-41-7

ammonia

nickel(II) bis(acetylacetonate) diamine

nickel(II) bis(acetylacetonate) diamine

Conditions
ConditionsYield
In benzene byproducts: H2O;100%
With sodium hydroxide In neat (no solvent) byproducts: H2O; keeping in dry NH3 atmosphere in the presence of NaOH to remove H2O;
dibromobis(triphenylphosphine)nickel(II)
36673-36-6, 111408-20-9, 14126-37-5, 54053-52-0

dibromobis(triphenylphosphine)nickel(II)

ammonia
7664-41-7

ammonia

hexaamminenickel(II) bromide

hexaamminenickel(II) bromide

Conditions
ConditionsYield
In diethyl ether; ammonia byproducts: PPh3; absence of moisture; condensation of liquid NH3 into Ni-complex soln. (in ether), stirring (2 h); evapn. of NH3, filtration, distn. off of ether;100%
bis(triphenylphosphine)nickel(II) diiodide
787624-20-8, 14057-03-5

bis(triphenylphosphine)nickel(II) diiodide

ammonia
7664-41-7

ammonia

hexamminenickel(II) iodide

hexamminenickel(II) iodide

Conditions
ConditionsYield
In diethyl ether; ammonia byproducts: PPh3; absence of moisture; condensation of liquid NH3 into Ni-complex soln. (in ether), stirring (2 h); evapn. of NH3, filtration, distn. off of ether;100%
bis(triphenylphosphine)nickel(II) chloride
14264-16-5, 53996-95-5, 62075-39-2, 39716-73-9

bis(triphenylphosphine)nickel(II) chloride

ammonia
7664-41-7

ammonia

hexaamminenickel (II) chloride

hexaamminenickel (II) chloride

Conditions
ConditionsYield
In diethyl ether; ammonia byproducts: PPh3; absence of moisture; condensation of liquid NH3 into Ni-complex soln. (in ether), stirring (2 h); evapn. of NH3, filtration, distn. off of ether;100%
S-(1-ferrocenylethyl)thioglycolic acid

S-(1-ferrocenylethyl)thioglycolic acid

ammonia
7664-41-7

ammonia

1-ferrocenylethylamine
1085568-96-2

1-ferrocenylethylamine

Conditions
ConditionsYield
With ammonium chloride; mercury dichloride In ammonia room temp.;100%
With HgCl2; NH4Cl In ammonia aq. ammonia=NH3; room temp.;100%
ammonia
7664-41-7

ammonia

{Coa6}{Co(CO)4}2

{Coa6}{Co(CO)4}2

Conditions
ConditionsYield
In petroleum ether 709mg Co2(CO)8 in 20ml petroleum ether are treated with NH3;;100%
In not given
In water byproducts: H2O; NH3 reacts with intermediates;;
mesitylcopper(I)
75732-01-3

mesitylcopper(I)

ammonia
7664-41-7

ammonia

A

amino-copper
77590-45-5

amino-copper

B

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

Conditions
ConditionsYield
In tetrahydrofuran THF, ambient temp., excess of NH3;; evapd. or filtered; elem. anal.;;A n/a
B 100%
tris(trimethylsilyl)aluminium * Et2O
65343-66-0

tris(trimethylsilyl)aluminium * Et2O

ammonia
7664-41-7

ammonia

{((CH3)3Si)2AlNH2}2
111290-98-3

{((CH3)3Si)2AlNH2}2

Conditions
ConditionsYield
In neat (no solvent) byproducts: (CH3)3SiH, (C2H5)2O; evacuating Schlenk vessel loaded with ((CH3)3Si)3Al*(C2H5)2O (glovebag, N2-atmosphere); condensing NH3 into flask at -196°C; warming slowly to room temp. (vigorous react.); stirring at 25°C for 48 h;; pptn.; removing volatile byproducts into trap cooled to -196°C; elem. anal.;;100%
undecacarbonyl(acetonitrile)triosmium
133869-39-3, 65702-94-5

undecacarbonyl(acetonitrile)triosmium

ammonia
7664-41-7

ammonia

Os3(CO)11(NH3)
170212-37-0, 74344-99-3

Os3(CO)11(NH3)

Conditions
ConditionsYield
In neat (no solvent) NH3-atmosphere; 80°C (24 h);100%
Os3(CO)11(C2H4)
65772-73-8

Os3(CO)11(C2H4)

ammonia
7664-41-7

ammonia

Os3(CO)11(NH3)
170212-37-0, 74344-99-3

Os3(CO)11(NH3)

Conditions
ConditionsYield
In neat (no solvent) NH3-atmosphere; 80°C (24 h);100%
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