Dodecahydro-1,4,7,10-benzotetraoxacyclododecine

Base Information

Chemical Name:Dodecahydro-1,4,7,10-benzotetraoxacyclododecine
CAS No.:17454-42-1
Molecular Formula:C12H22O4
Molecular Weight:230.3007
Hs Code.:
DSSTox Substance ID:DTXSID50938526
Wikidata:Q82914852
Mol file:17454-42-1.mol

Synonyms:DTXSID50938526;Dodecahydro-1,4,7,10-benzotetraoxacyclododecine

Suppliers and Price of Dodecahydro-1,4,7,10-benzotetraoxacyclododecine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 8 raw suppliers

Chemical Property of Dodecahydro-1,4,7,10-benzotetraoxacyclododecine

Chemical Property:

Vapor Pressure:0.000128mmHg at 25°C
Refractive Index:1.4815 (estimate)
Boiling Point:344.8°Cat760mmHg
Flash Point:129°C
PSA：36.92000
Density:1.005g/cm³
LogP:1.37760
XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:230.15180918
Heavy Atom Count:16
Complexity:166

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC2C(C1)OCCOCCOCCO2
Isomeric SMILES:C1CC[C@H]2[C@H](C1)OCCOCCOCCO2

Technology Process of Dodecahydro-1,4,7,10-benzotetraoxacyclododecine

There total 5 articles about Dodecahydro-1,4,7,10-benzotetraoxacyclododecine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 14174-08-4
benzo-12-crown-4

: 17454-42-1,125279-92-7,125356-38-9
(4aR,14aS)-Dodecahydro-5,8,11,14-tetraoxa-benzocyclododecene

Guidance literature:: With hydrogen; (PAA)6RhCl; In water; isopropyl alcohol; under 760 Torr;

Reference yield: 30.0%

: 74262-29-6
1,2-cyclohexano-3,6,9-trioxaundecane-1,11-diol

: 17454-42-1,125279-92-7,125356-38-9
Cyclohexano-12-crown-4

Guidance literature:: With sodium hydroxide; p-toluenesulfonyl chloride; In 1,4-dioxane; at 60 ℃; for 20h;
DOI:10.1021/jo01314a030

Reference yield:

: 286-20-4
cyclohexane-1,2-epoxide

: 17454-42-1,125279-92-7,125356-38-9
Cyclohexano-12-crown-4

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH (oil-suspended) / 1.) dioxane, 20 deg C, 2.) 24 h, reflux

2: 30 percent / NaOH, p-toluenesulfonyl chloride / dioxane / 20 h / 60 °C

With sodium hydroxide; sodium hydride; p-toluenesulfonyl chloride; In 1,4-dioxane;
DOI:10.1021/jo01314a030