Tris(3-chlorophenyl)phosphine

Base Information

• Chemical Name: Tris(3-chlorophenyl)phosphine
• CAS No.: 29949-85-7
• Molecular Formula: C18H12 Cl3 P
• Molecular Weight: 365.626
• Hs Code.: 2931900090
• European Community (EC) Number: 249-970-9
• UNII: DCA2EAP83P
• DSSTox Substance ID: DTXSID40184055
• Nikkaji Number: J249.894D
• Wikidata: Q72515020
• Mol file: 29949-85-7.mol

Synonyms:Tris(3-chlorophenyl)phosphine;29949-85-7;tris(3-chlorophenyl)phosphane;tri(m-Chlorophenyl)phosphine;TRI(3-CHLOROPHNYL)PHOSPHINE;tri-(3-Chlorophenyl)phosphine;Phosphine, tris(3-chlorophenyl)-;EINECS 249-970-9;Phosphine, tris[3-chlorophenyl]-;DCA2EAP83P;SCHEMBL197486;DTXSID40184055;MFCD00013632;AKOS016009863;CS-W009776;SC11124;AS-59810;FT-0638891;F17187;A876343;TRI(3-CHLOROPHENYL)PHOSPHINE;TRI(M-CHLOROPHENYL)PHOSPHINE;TRIS(3-CHLOROPHENYL)PHOSPHINE

Chemical Property of Tris(3-chlorophenyl)phosphine

Chemical Property:

• Vapor Pressure: 5.99E-08mmHg at 25°C
• Melting Point: 64-66°C
• Boiling Point: 452.5°Cat760mmHg
• Flash Point: 227.4°C
• PSA: 13.59000
• Density: g/cm³
• LogP: 5.40500
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: air sensitive, store cold
• XLogP3: 6.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 363.974220
• Heavy Atom Count: 22
• Complexity: 299

Purity/Quality:

97% ^*data from raw suppliers

Tri(m-chlorophenyl)phosphine, min. 97% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC(=CC(=C1)Cl)P(C2=CC(=CC=C2)Cl)C3=CC(=CC=C3)Cl

Technology Process of Tris(3-chlorophenyl)phosphine

There total 3 articles about Tris(3-chlorophenyl)phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-bromo-3-chlorobenzene (108-37-2) → tri(m-chlorophenyl)-phosphine (29949-85-7)

Guidance literature:

1-bromo-3-chlorobenzene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;

With phosphorus trichloride; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

Reference yield:

→ tri(m-chlorophenyl)-phosphine (29949-85-7)

Guidance literature:

With diethyl ether; hydrogen; phosphorus trichloride;

DOI:10.1039/jr9370000527

Reference yield:

→ tri(m-chlorophenyl)-phosphine (29949-85-7)

Guidance literature:

upstream raw materials:

1-bromo-3-chlorobenzene

Downstream raw materials:

tris-(3-chloro-phenyl)-phosphine oxide

C₁₈H₁₂Cl₃PS

diphenyldisulfane

[RhCl(η(4)-1,5-cyclooctadiene)(P(3-ClC6H4)3)]