iridium(3+) chloride - {3-(diphenylphosphanyl)-2-[(diphenylphosphanyl)methyl]-2-methylpropyl}(diphenyl)phosphane (1:3:1)

Base Information

• Chemical Name: iridium(3+) chloride - {3-(diphenylphosphanyl)-2-[(diphenylphosphanyl)methyl]-2-methylpropyl}(diphenyl)phosphane (1:3:1)
• CAS No.: 104453-05-6
• Molecular Formula: C₄₁H₃₉Cl₃IrP₃
• Molecular Weight: 923.261
• Mol file: 104453-05-6.mol

Synonyms:Iridium,trichloro[[2-[(diphenylphosphino)methyl]-2-methyl-1,3-propanediyl]bis[diphenylphosphine]-P,P',P'']-,(OC-6-22)-; Phosphine,[2-[(diphenylphosphino)methyl]-2-methyl-1,3-propanediyl]bis[diphenyl-, iridiumcomplex

Chemical Property of iridium(3+) chloride - {3-(diphenylphosphanyl)-2-[(diphenylphosphanyl)methyl]-2-methylpropyl}(diphenyl)phosphane (1:3:1)

Chemical Property:

• Vapor Pressure: 3.5E-19mmHg at 25°C
• Boiling Point: 709.9°Cat760mmHg
• Flash Point: 409.6°C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of iridium(3+) chloride - {3-(diphenylphosphanyl)-2-[(diphenylphosphanyl)methyl]-2-methylpropyl}(diphenyl)phosphane (1:3:1)

There total 6 articles about iridium(3+) chloride - {3-(diphenylphosphanyl)-2-[(diphenylphosphanyl)methyl]-2-methylpropyl}(diphenyl)phosphane (1:3:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

iridium(III) chloride trihydrate + [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] (22031-12-5) → IrCl3(tripod) (104453-05-6,34397-69-8)

Guidance literature:

With NaCl; In 2-methoxy-ethanol; refluxing IrCl3.3H2O and NaCl in soln. for 30 mins., cooling to room temp. and addn. of MeC(CH2PPh2)3, refluxing 16 h (olive-green soln. turned colorless, deposition of white ppt.) ; all operations under N2; cooling to room temp., collection of ppt., extn. with CH2Cl2, removal of CH2l2 in vauo;

Reference yield: 95.0%

[Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)(η(4)-1,5-cyclooctadiene)]Cl (146728-56-5) + chlorine (7782-50-5) → IrCl3(tripod) (104453-05-6,34397-69-8)

Guidance literature:

In dichloromethane; bubbling Cl2 through Ir-complex soln. at room temp., stirring (room temp., 2 h); pptn. on Et2O addn., filtration, washing (Et2O), drying (vac.); elem. anal.;

Reference yield:

IrHCl2(CH3C(CH2P(C6H5)2)3) (104453-06-7) → IrCl3(tripod) (104453-05-6,34397-69-8)

Guidance literature:

With Cl₂; In dichloromethane; N2-atmosphere;

DOI:10.1016/0022-328X(85)80351-X

upstream raw materials:

IrHCl₂(CH₃C(CH₂P(C₆H₅)2)3)

[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]

[Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)(η(4)-1,5-cyclooctadiene)]Cl

chlorine

Downstream raw materials:

IrHCl₂(CH₃C(CH₂P(C₆H₅)2)3)

(1,1,1-tris(diphenylphosphinomethyl)ethane)Ir(H)3

IrH₂Cl(CH₃C(CH₂P(C₆H₅)2)3)

Ir(CH₃C(CH₂P(C₆H₅)2)3)Cl₂(CH₃CN)⁽¹⁺⁾*CF₃SO₃^(1-)=[Ir(CH₃C(CH₂P(C₆H₅)2)3)Cl₂(CH₃CN)]CF₃SO₃

Refernces

• 1、 Suelue, Mustafa,Venanzi, Luigi M.. "The ruthenium and iridium coordination chemistry of the tripodal ligand CH3C{CH2P(m-CF3-C6H4)2}3". . p. 70 - 79. Retrieved 2008/10/08.