Dysidin

Base Information

Chemical Name:Dysidin
CAS No.:63079-71-0
Molecular Formula:C16H22Cl3NO4
Molecular Weight:398.7092
Hs Code.:
NSC Number:622169
Wikidata:Q105216412
Metabolomics Workbench ID:167837

Synonyms:Dysidin;63079-71-0;2H-Pyrrol-2-one, 1,5-dihydro-4-methoxy-5-(1-methylethyl)-1-(6,6,6-trichloro-3-methoxy-5-methyl-1-oxo-2-hexenyl)-, [S-[R*,R*-(E)]]-;NSC622169;NSC-622169

Suppliers and Price of Dysidin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Dysidin

Chemical Property:

Vapor Pressure:3.37E-10mmHg at 25°C
Melting Point:127 - 129 °C
Boiling Point:501.8°Cat760mmHg
Flash Point:257.3°C
PSA：55.84000
Density:1.29g/cm³
LogP:3.77470
XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:397.061441
Heavy Atom Count:24
Complexity:552

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Chemical Classes:other linear non-peptide (Polychlorinated Leucines)
Canonical SMILES:CC(C)C1C(=CC(=O)N1C(=O)C=C(CC(C)C(Cl)(Cl)Cl)OC)OC
Isomeric SMILES:C[C@@H](C/C(=C\C(=O)N1[C@H](C(=CC1=O)OC)C(C)C)/OC)C(Cl)(Cl)Cl

Technology Process of Dysidin

There total 14 articles about Dysidin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 133908-08-4
iheyanone

: 1329627-18-0
(5S,E)-6,6,6-trichloro-3-methoxy-5-methylhex-2-enoyl chloride

: 91279-96-8,91279-98-0,95272-90-5,95272-91-6,63079-71-0
dysidin

Guidance literature:: 5-isopropyl-4-methoxy-1,5-dihydro-pyrrol-2-one; With methylmagnesium bromide; In tetrahydrofuran; diethyl ether; at 0 ℃; Inert atmosphere;

(5S,E)-6,6,6-trichloro-3-methoxy-5-methylhex-2-enoyl chloride; In tetrahydrofuran; diethyl ether; at 0 - 25 ℃; for 24h; Inert atmosphere;
DOI:10.1002/asia.201100338

Reference yield:

: 934197-81-6
2-isopropyl-3-methoxy-5-oxo-2,5-dihydro-pyrrole-1-carboxylic acid tert-butyl ester

: 91279-96-8,91279-98-0,95272-90-5,95272-91-6,63079-71-0
dysidin

Guidance literature:: Multi-step reaction with 2 steps

1.1: trifluoroacetic acid / dichloromethane / 0.5 h / 20 - 25 °C / Inert atmosphere

2.1: methylmagnesium bromide / tetrahydrofuran; diethyl ether / 0 °C / Inert atmosphere

2.2: 24 h / 0 - 25 °C / Inert atmosphere

With methylmagnesium bromide; trifluoroacetic acid; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1002/asia.201100338

Reference yield:

: 1207363-08-3
(S)-4,4,4-trichloro-3-methylbutanenitrile

: 91279-96-8,91279-98-0,95272-90-5,95272-91-6,63079-71-0
dysidin

Guidance literature:: Multi-step reaction with 9 steps

1.1: diisobutylaluminium hydride / dichloromethane / 2 h / -78 °C / Inert atmosphere

1.2: 2 h / -78 - 25 °C / Inert atmosphere

2.1: sodium dihydrogenphosphate; sodium chlorite / 2-methyl-but-2-ene; water; tert-butyl alcohol / 3.33 h / 0 - 25 °C / Inert atmosphere

3.1: thionyl chloride; N,N-dimethyl-formamide / dichloromethane / 1 h / Inert atmosphere; Reflux

4.1: pyridine / dichloromethane / 1.5 h / -5 - 25 °C / Inert atmosphere

5.1: 2 h / 65 °C / Inert atmosphere

6.1: N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride / mineral oil / 24 h / 5 - 25 °C / Inert atmosphere

7.1: barium hydroxide octahydrate / methanol / 4 h / Inert atmosphere; Reflux

8.1: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 3 h / 20 - 25 °C / Inert atmosphere

9.1: methylmagnesium bromide / tetrahydrofuran; diethyl ether / 0 °C / Inert atmosphere

9.2: 24 h / 0 - 25 °C / Inert atmosphere

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium chlorite; sodium dihydrogenphosphate; thionyl chloride; oxalyl dichloride; barium hydroxide octahydrate; methylmagnesium bromide; sodium hydride; diisobutylaluminium hydride; N,N-dimethyl-formamide; In tetrahydrofuran; methanol; 2-methyl-but-2-ene; diethyl ether; dichloromethane; water; mineral oil; tert-butyl alcohol;
DOI:10.1002/asia.201100338