1H,1H,2H-Perfluoro-1-decene

Base Information

• Chemical Name: 1H,1H,2H-Perfluoro-1-decene
• CAS No.: 21652-58-4
• Molecular Formula: C10H3F17
• Molecular Weight: 446.107
• Hs Code.: 29033990
• European Community (EC) Number: 244-503-5
• UNII: Q8TG27S5YB
• DSSTox Substance ID: DTXSID7074616
• Nikkaji Number: J28.315K
• Wikidata: Q72500471
• Mol file: 21652-58-4.mol

Synonyms:1H,1H,2H-Perfluoro-1-decene;21652-58-4;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodec-1-ene;(Perfluoro-n-octyl)ethylene;1h,1h,2h-perfluorodec-1-ene;(Perfluorooctyl)ethylene;1-Decene, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-1-decene;1H,1H,2H-Heptadecafluoro-1-decene;Q8TG27S5YB;1H,1H,2H-Heptadecafluorodec-1-ene;1H,1H,2H-heptadecafluoro-dec-1-ene;C10H3F17;EINECS 244-503-5;perfluorooctyl ethylene;1h,1h,2h-perfluorodecene;UNII-Q8TG27S5YB;CF3(CF2)7CH=CH2;SCHEMBL312484;1-(Heptadecafluorooctyl)ethene;DTXSID7074616;BCP09463;MFCD00039246;AKOS005063721;FS-4921;1H,1H,2H-perfluoro-1-decene, 98%;1H,1H,2H-Perfluoro-1-decene, 99%;C10 Gamma-Omega Perfluoro Alpha-Alkene;FT-0613989;H0846;D90960;A815581;J-014210;1H,1H,2H-Perfluoro-1-decene, purum, >=95.0% (GC);3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-1-decene #;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecakis(fluoranyl)dec-1-ene

Chemical Property of 1H,1H,2H-Perfluoro-1-decene

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Vapor Pressure: 6.36mmHg at 25°C
• Refractive Index: n20/D 1.301(lit.)
• Boiling Point: 146-147 °C
• Flash Point: >230 °F
• PSA: 0.00000
• Density: 1.677 g/mL at 25 °C(lit.)
• LogP: 6.18180
• Storage Temp.: Refrigerator
• Solubility.: Chloroform (Sparingly), Methanol (Slightly)
• Water Solubility.: Insoluble in water.
• XLogP3: 6.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 17
• Rotatable Bond Count: 7
• Exact Mass: 445.9963289
• Heavy Atom Count: 27
• Complexity: 565

Purity/Quality:

99% ^*data from raw suppliers

1H,1H,2H-Perfluoro-1-decene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=CC(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Uses: 1H,1H,2H-Perfluoro-1-decene is useful in the chemical process of making an electrolyte-phobic surface for next generation nanostructured battery electrodes.

Technology Process of 1H,1H,2H-Perfluoro-1-decene

There total 23 articles about 1H,1H,2H-Perfluoro-1-decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

2-(n-perfluorooctyl)ethyl iodide (2043-53-0,71215-70-8) → 1H,1H,2H-perfluorodecene (21652-58-4)

Guidance literature:

With potassium hydroxide; In methanol; for 6h; Heating;

DOI:10.1016/0022-1139(95)03286-M

Reference yield: 92.0%

dibenzyl 2-bromo-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl phosphate (1277151-43-5) → 1H,1H,2H-perfluorodecene (21652-58-4) + ammonium dibenzyl phosphate (1277151-44-6)

Guidance literature:

With ammonium formate; zinc; In tetrahydrofuran; acetonitrile; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ol2003435

Reference yield: 90.0%

2-(n-perfluorooctyl)ethyl iodide (2043-53-0,71215-70-8) + diethyl malonate (105-53-3) → 1H,1H,2H-perfluorodecene (21652-58-4) + diethyl 2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)malonate (26564-99-8)

Guidance literature:

diethyl malonate; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.333333h;

2-(n-perfluorooctyl)ethyl iodide; In tetrahydrofuran; for 18h; Heating;

DOI:10.1016/S0022-1139(00)00388-2

upstream raw materials:

2-(n-perfluorooctyl)ethyl iodide

trimethyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-iododecyl)silane

malonic acid dimethyl ester

diethyl malonate

Downstream raw materials:

chloro(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane

1-(3'-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene

4-((E)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-dec-1-enyl)-2-methyl-benzoic acid methyl ester

4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decyl)-2-methyl-benzoic acid methyl ester

Refernces

• 1、 Liu, Lin,Pohl, Nicola L. B.. "A fluorous phosphate protecting group with applications to carbohydrate synthesis". supporting information; experimental part. p. 1824 - 1827. Retrieved 2011/06/19.
• 2、 -. "Process for preparing fluorinated alkyl carboxylate esters". Page/Page column 6. . Retrieved 2008/06/13.