Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,2-tetrafluoro-2-(fluorosulfonyl)ethoxy)propoxy)-

Base Information

• Chemical Name: Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,2-tetrafluoro-2-(fluorosulfonyl)ethoxy)propoxy)-
• CAS No.: 4089-58-1
• Deprecated CAS: 64346-22-1
• Molecular Formula: C8F16O5S
• Molecular Weight: 512.125
• Hs Code.: 2914790090
• European Community (EC) Number: 223-824-4
• DSSTox Substance ID: DTXSID40863318
• Nikkaji Number: J26.704J
• Mol file: 4089-58-1.mol

Synonyms:4089-58-1;8-Fluorosulfonylperfluoro(2,5-dimethyl-3,6-dioxaoctanoyl) fluoride;Propionyl fluoride, tetrafluoro-2-(hexafluoro-2-(tetrafluoro-2-(fluorosulfonyl)ethoxy)propoxy)-;Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,2-tetrafluoro-2-(fluorosulfonyl)ethoxy)propoxy)-;2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)propoxy]propanoyl fluoride;EINECS 223-824-4;8-Fluorosulfonylperfluoro(2,5-dimethyl-3,6-dioxaoctanoyl)fluoride;Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,2-tetrafluoro-2-(fluorosulfonyl)ethoxy]propoxy]-;2,3,3,3-Tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,2-tetrafluoro-2-(fluorosulphonyl)ethoxy)propoxy)propionyl fluoride;2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,2-tetrafluoro-2-(fluorosulphonyl)ethoxy]propoxy]propionyl fluoride;C8F16O5S;SCHEMBL15851510;DTXSID40863318;C8-F16-O5-S;MFCD16621332;AKOS007930385;MS-20252;8-Fluorosulfonylperfluoro-2,5-dimethyl-3,6-dioxaoctanoyl fluoride;8-Fluorosulphonylperfluoro(2,5-dimethyl-3,6-dioxaoctanoyl) fluoride;2,5-Bis(trifluoromethyl)-8-(fluorosulfonyl)nonafluoro-3,6-dioxaoctan-1-one

Chemical Property of Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,2-tetrafluoro-2-(fluorosulfonyl)ethoxy)propoxy)-

Chemical Property:

• Vapor Pressure: 0.0135mmHg at 25°C
• Boiling Point: 138.5-141℃
• Flash Point: 110.3°C
• PSA: 78.05000
• Density: 1.835g/cm³
• LogP: 5.13040
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 21
• Rotatable Bond Count: 8
• Exact Mass: 511.9210949
• Heavy Atom Count: 30
• Complexity: 764

Purity/Quality:

99% ^*data from raw suppliers

8-Fluorosulfonylperfluoro(2,5-dimethyl-3,6-dioxaoctanoyl) fluoride 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(C(C(F)(F)F)(OC(C(C(F)(F)F)(OC(C(F)(F)S(=O)(=O)F)(F)F)F)(F)F)F)F

Technology Process of Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,2-tetrafluoro-2-(fluorosulfonyl)ethoxy)propoxy)-

There total 3 articles about Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,2-tetrafluoro-2-(fluorosulfonyl)ethoxy)propoxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Hexafluoropropene oxide (428-59-1,25038-02-2) + fluorosulfonyldifluoroacetyl fluoride (677-67-8) → 5-fluorosulfonylpentafluoro-2-trifluormethyl-3-oxapentanoyl fluoride (4089-57-0) + 8-fluorosulfonyl-2,5-bis(trifluoromethyl)octafluoro-3,6-dioxaoctanoyl fluoride (4089-58-1) + 11-fluorosulfonyl-2,5,8-tris(trifluoromethyl)undecafluoro-3,6,9-trioxaundecanoyl fluoride (4628-44-8)

Guidance literature:

With cesium fluoride; In various solvent(s); at -15 ℃; for 8h; under 750 Torr; Title compound not separated from byproducts;

DOI:10.1016/j.jfluchem.2004.05.009

Reference yield:

Hexafluoropropene oxide (428-59-1,25038-02-2) + fluorosulfonyldifluoroacetyl fluoride (677-67-8) + cesium fluoride (13400-13-0) → 8-fluorosulfonyl-2,5-bis(trifluoromethyl)octafluoro-3,6-dioxaoctanoyl fluoride (4089-58-1) + 11-fluorosulfonyl-2,5,8-tris(trifluoromethyl)undecafluoro-3,6,9-trioxaundecanoyl fluoride (4628-44-8)

Guidance literature:

In diethylene glycol dimethyl ether; byproducts: FSO2CF2CF2O{CF(CF3)CF2O}(n)CF(CF3)C(O)F n:3-12;; 25-35°C, 4 h, excess of epoxide, the residue is a polymer mixture; distn.;

Reference yield:

→ 8-fluorosulfonyl-2,5-bis(trifluoromethyl)octafluoro-3,6-dioxaoctanoyl fluoride (4089-58-1)

Guidance literature:

d. Epoxid, FSO2-R-Verb.;

upstream raw materials:

Hexafluoropropene oxide

fluorosulfonyldifluoroacetyl fluoride

cesium fluoride

Downstream raw materials:

perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride

Refernces