(1R-endo)-3-amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one hydrochloride

Base Information

Chemical Name:(1R-endo)-3-amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one hydrochloride
CAS No.:31638-54-7
Molecular Formula:C10H17 N O . Cl H
Molecular Weight:203.712
Hs Code.:2922399090
Mol file:31638-54-7.mol

Synonyms:2-Bornanone,3-amino-, hydrochloride, (1R,3S,4S)- (8CI); (1R)-3-endo-Aminocamphorhydrochloride; 3-endo-Amino-D-camphor hydrochloride;D-endo-(+)-3-Amino-2-bornanone hydrochloride

Suppliers and Price of (1R-endo)-3-amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one hydrochloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(1R)-3-endo-AminocamphorHydrochloride
500mg
$ 165.00

Total 5 raw suppliers

Chemical Property of (1R-endo)-3-amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one hydrochloride

Chemical Property:

Vapor Pressure:0.00263mmHg at 25°C
Melting Point:234 - 236 °C
Boiling Point:282.1°Cat760mmHg
Flash Point:124.4°C
PSA：43.09000
Density:g/cm³
LogP:2.84120

Purity/Quality:

99% ^*data from raw suppliers

(1R)-3-endo-AminocamphorHydrochloride ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses (1R-endo)-3-amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one hydrochloride is used as a reactant for the synthesis of alpha-amino ketones.

Technology Process of (1R-endo)-3-amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one hydrochloride

There total 1 articles about (1R-endo)-3-amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 33162-63-9
3-endo-aminobornan-2-one

: 31638-54-7
(1R,3S,4S)-(+)-3-amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one hydrochloride

Guidance literature:: With hydrogenchloride; In diethyl ether;
DOI:10.1055/s-0030-1258355

Reference yield:

: 31638-54-7
(1R,3S,4S)-(+)-3-amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one hydrochloride

: 29900-93-4
(1R,2R,3S,4S)-3-Amino-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydroxide / water / 0.02 h / 0 °C / pH 10

2: lithium aluminium tetrahydride / diethyl ether / 0 - 20 °C

With lithium aluminium tetrahydride; sodium hydroxide; In diethyl ether; water;
DOI:10.1055/s-0030-1258355

Reference yield:

: 6964-73-4,24271-65-6,26126-99-8,31638-54-7
(1S,3R,4R)-3-Amino-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one; hydrochloride

: 17206-50-7
2-Isopropyl-2-methyl-cyclohexanon

Guidance literature:: Multi-step reaction with 3 steps

1: aq. NaNO₂, H₂SO₄

2: Zn, AcOH

3: H₂ / Pd-C / aq. ethanol

With sulfuric acid; hydrogen; acetic acid; zinc; sodium nitrite; palladium on activated charcoal; In ethanol;
DOI:10.1139/v63-218