Antimony(3+) tritetradecane-1-thiolate

Base Information

• Chemical Name: Antimony(3+) tritetradecane-1-thiolate
• CAS No.: 7148-21-2
• Molecular Formula: C42H87S3Sb
• Molecular Weight: 810.0952
• DSSTox Substance ID: DTXSID50991914
• Mol file: 7148-21-2.mol

Synonyms:antimony(3+) tritetradecane-1-thiolate;DTXSID50991914

Chemical Property of Antimony(3+) tritetradecane-1-thiolate

Chemical Property:

• Vapor Pressure: 0.00135mmHg at 25°C
• Boiling Point: 307°Cat760mmHg
• Flash Point: 120.9°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 36
• Exact Mass: 808.50080
• Heavy Atom Count: 46
• Complexity: 102

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCC[S-].CCCCCCCCCCCCCC[S-].CCCCCCCCCCCCCC[S-].[Sb+3]

Technology Process of Antimony(3+) tritetradecane-1-thiolate

There total 1 articles about Antimony(3+) tritetradecane-1-thiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-tetradecanethiol (2079-95-0) → trithioantimonous acid tritetradecyl ester (7148-21-2)

Guidance literature:

With chloroform; antimony(III) chloride;

DOI:10.1021/ja01187a041

upstream raw materials:

1-tetradecanethiol

Refernces

Cross-coupling reaction of allylic and benzylic carbonates with organo[2-(hydroxymethyl)phenyl]dimethylsilanes

10.1246/cl.2007.606

The research discusses a novel cross-coupling reaction involving allylic and benzylic carbonates with organo[2-(hydroxymethyl)phenyl]dimethylsilanes, facilitated by a palladium catalyst without the need for any activator. The purpose of this study was to develop a more stable and non-toxic alternative to conventional cross-coupling reactions for synthesizing 1,4-diene and diarylmethane products, which are common in natural products and pharmaceuticals. The researchers found that a variety of functional groups were tolerated, leading to a diverse range of products with high chemoselectivity. Key chemicals used in the process include organo[2-(hydroxymethyl)phenyl]dimethylsilanes (1), allylic and benzylic carbonates (2 and 5), Pd2(dba)3 as the palladium catalyst, and (2-thienyl)3P as a ligand.