1-[(ethoxycarbonyl)amino]-4-methylpyridinium

Base Information

• Chemical Name: 1-[(ethoxycarbonyl)amino]-4-methylpyridinium
• CAS No.: 22928-85-4
• Molecular Formula: C₉H₁₂N₂O₂
• Molecular Weight: 180.206
• Mol file: 22928-85-4.mol

Synonyms:4-Picolinium,1-(carboxyamino)-, hydroxide, inner salt, ethyl ester (8CI);1-Ethoxycarbonylimino-4-methylpyridinium ylide; NSC 126676

Chemical Property of 1-[(ethoxycarbonyl)amino]-4-methylpyridinium

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-[(ethoxycarbonyl)amino]-4-methylpyridinium

There total 1 articles about 1-[(ethoxycarbonyl)amino]-4-methylpyridinium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 4-Methyl-1-ethoxycarbonyliminopyridiniumylid (22928-85-4)

Guidance literature:

4-Picolin, N3-COOC2H5;

DOI:10.1021/jo00819a012

Reference yield: 75.0%

4-Methyl-1-ethoxycarbonyliminopyridiniumylid (22928-85-4) → ethyl 5-methyl-1H-1,2-diazepine-1-carboxylate (22928-91-2)

Guidance literature:

In acetone; at 10 - 15 ℃; Irradiation;

DOI:10.3987/COM-92-6073

Reference yield:

4-Methyl-1-ethoxycarbonyliminopyridiniumylid (22928-85-4) → 8-methyl-3-(2,4,6-trimethyl-phenyl)-9aH-[1,2,4]oxadiazolo[4,5-b][1,2]diazepine-5-carboxylic acid ethyl ester (64762-39-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 75 percent / acetone / 10 - 15 °C / Irradiation

2: CHCl₃ / 48 h / 50 - 60 °C

In chloroform; acetone;

DOI:10.3987/COM-92-6073

Downstream raw materials:

ethyl 5-methyl-1H-1,2-diazepine-1-carboxylate

8-methyl-3-(2,4,6-trimethyl-phenyl)-9aH-[1,2,4]oxadiazolo[4,5-b][1,2]diazepine-5-carboxylic acid ethyl ester

N'-[(Z)-3-[3-(2,6-Dimethyl-phenyl)-isoxazol-4-yl]-but-2-en-(E)-ylidene]-hydrazinecarboxylic acid ethyl ester

3-(2,6-Dimethyl-phenyl)-8-methyl-9aH-[1,2,4]oxadiazolo[4,5-b][1,2]diazepine-5-carboxylic acid ethyl ester