Cyclooctene, homopolymer

Base Information

• Chemical Name: Cyclooctene, homopolymer
• CAS No.: 25267-51-0
• Molecular Formula: C8H14
• Molecular Weight: 0
• Mol file: 25267-51-0.mol

Synonyms:

Chemical Property of Cyclooctene, homopolymer

Chemical Property:

• Melting Point: 17 °C
• PSA: 0.00000
• LogP: 2.89680

Purity/Quality:

99.0%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclooctene, homopolymer

There total 332 articles about Cyclooctene, homopolymer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

trans-1,2-dibromocyclooctane (29974-69-4,34969-65-8) → (E)-cyclooctene (931-89-5,25267-51-0)

Guidance literature:

With sodium tetrahydroborate; nickel dichloride; In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1139/V06-125

Reference yield: 88.0%

cis-Cyclooctene (931-88-4,931-87-3,25267-51-0) → (E)-cyclooctene (931-89-5,25267-51-0)

Guidance literature:

With diethyl isophthalate; In pentane; at 20 ℃; for 42h; UV-irradiation; Inert atmosphere;

DOI:10.1246/cl.170937

Reference yield: 58.0%

(trans-2-hydroxycyclooctyl)diphenylphosphine oxide (38202-37-8) → (E)-cyclooctene (931-89-5,25267-51-0)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; for 1h; Ambient temperature;

DOI:10.1021/ja00034a042

upstream raw materials:

phthalic anhydride

cyclooctanol

1,5-cis,cis-cyclooctadiene

(E)-cyclooctene

Downstream raw materials:

1-phenyl-(3ar,9ac)-3a,4,5,6,7,8,9,9a-octahydro-1H-cyclooctatriazole

1-phenyl-(3ar,9at)-3a,4,5,6,7,8,9,9a-octahydro-1H-cyclooctatriazole

cis-bicyclo[6.1.0]nonane

trans-bicyclo<6.1.0>nonane

Refernces

• 1、 Bumgardner. "". . p. 1035. Retrieved 1962.
• 2、 Barton, Derek H. R.,Beviere, Stephane D.,Hill, David R.. "The functionalization of saturated hydrocarbons part XXIX. Application of tert-butyl hydroperoxide and dioxygen using soluble Fe(III) and Cu(II) chelates". . p. 2665 - 2670. Retrieved 1994.
• 3、 Renkema, Kenton B.,Kissin, Yury V.,Goldman, Alan S.. "Mechanism of alkane transfer-dehydrogenation catalyzed by a pincer-ligated iridium complex". . p. 7770 - 7771. Retrieved 2003.
• 4、 Gupta, Mukta,Hagen, Chrystel,Flesher, Robert J.,Kaska, William C.,Jensen, Craig M.. "A highly active alkane dehydrogenation catalyst: Stabilization of dihydrido rhodium and iridium complexes by a P-C-P pincer ligand". . p. 2083 - 2084. Retrieved 1996.
• 5、 Gao, Fang,Li, Run-Hua,Compton, Robert N.,Pagni, Richard M.. "The photochemistry of optically active (E)-cyclooctene: Lamp versus laser". . p. 297 - 299. Retrieved 2004.
• 6、 Matikonda, Siddharth S.,Orsi, Douglas L.,Staudacher, Verena,Jenkins, Imogen A.,Fiedler, Franziska,Chen, Jiayi,Gamble, Allan B.. "Bioorthogonal prodrug activation driven by a strain-promoted 1,3-dipolar cycloaddition". . p. 1212 - 1218. Retrieved 2015.
• 7、 Wada, Takehiko,Sugahara, Norimitsu,Kawano, Mahito,Inoue, Yoshihisa. "First asymmetric photochemistry with nucleosides and DNA: Enantiodifferentiating Z-E photoisomerization of cyclooctene". . p. 1174 - 1175. Retrieved 2000.
• 8、 Fukuhara, Gaku,Mori, Tadashi,Wada, Takehiko,Inoue, Yoshihisa. "Entropy-controlled supramolecular photochirogenesis: Enantiodifferentiating Z-E photoisomerization of cyclooctene included and sensitized by permethylated 6-0-modified β-cyclodextrins". . p. 8233 - 8243. Retrieved 2006.
• 9、 Weinstock et al.. "-". . p. 6072,6075. Retrieved 1956.
• 10、 Miller, Joseph A.,Knox, Linda K.. "Efficient and Selective Catalytic Dehydrogenation of Alkanes using Rhodium(I) Arsine Complexes". . p. 1449 - 1450. Retrieved 1994.