LITHIUM ACRYLATE

Base Information

• Chemical Name: LITHIUM ACRYLATE
• CAS No.: 13270-28-5
• Molecular Formula: C3H4 O2 . Li
• Molecular Weight: 77.9966
• Mol file: 13270-28-5.mol

Synonyms:2-Propenoicacid, lithium salt (9CI); Acrylic acid, lithium salt (8CI); Lithium acrylate

Chemical Property of LITHIUM ACRYLATE

Chemical Property:

• Vapor Pressure: 3.42mmHg at 25°C
• Boiling Point: 141°Cat760mmHg
• Flash Point: 61.6°C
• PSA: 40.13000
• Density: g/cm³
• LogP: -1.07770

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of LITHIUM ACRYLATE

There total 3 articles about LITHIUM ACRYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethene (74-85-1) + carbon dioxide (124-38-9,18923-20-1) → Lithium acrylate (13270-28-5)

Guidance literature:

ethene; With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; triethylamine; lithium iodide; zinc; 1,2-bis-(dicyclohexylphosphino)ethane; In chlorobenzene; at 25 ℃; for 2.5h; Autoclave;

carbon dioxide; In chlorobenzene; at 50 ℃; for 72h; Reagent/catalyst; Catalytic behavior; Autoclave;

DOI:10.1002/chem.201404082

Reference yield:

{WH(OOCCHCH2)(C2H4)(P(CH3)3)2}2*0.5(C2H5)2O (122214-24-8) + ethene (74-85-1) + trimethylphosphane (594-09-2) → trans-{W(ethylene)2(CO)(P(CH3)3)3} (98720-85-5) + Lithium acrylate (13270-28-5)

Guidance literature:

With n-C₄H₉Li; CO; In benzene; byproducts: n-C4H10; under atmosphere of ethylene, successive addn. of PMe3 and n-C4H9Li (0.9 M in hexane) to soln. of acrylate complex, room temp., stirring, 40-50 min, evapn. of solvent in vac., extg. with petroleum ether (residue: Li acrylate), reacting filtrate with CO; products identified by IR and 1H NMR (Li acrylate) and 31P NMR (intermediate);

Reference yield:

[Mo(H)(P(CH3)3)2(CH2CH2)(CH2CHC(O)O)]2 (97732-43-9) + ethene (74-85-1) + trimethylphosphane (594-09-2) → trans-{Mo(ethylene)2(P(CH3)3)4} (82044-79-9) + Lithium acrylate (13270-28-5)

Guidance literature:

With n-C₄H₉Li; In benzene; byproducts: n-C4H10; under atmosphere of ethylene, successive addn. of PMe3 and n-C4H9Li (0.9 M in hexane) to soln. of acrylate complex, room temp., stirring, 40-50 min, evapn. of solvent in vac., extg. with petroleum ether (residue: Li acrylate); products identified by IR and 1H NMR (Li acrylate) and 31P NMR, resp.;

upstream raw materials:

{WH(OOCCHCH₂)(C₂H₄)(P(CH₃)3)2}2*0.5(C₂H₅)2O

ethene

trimethylphosphane

[Mo(H)(P(CH₃)3)2(CH₂CH₂)(CH₂CHC(O)O)]2

Downstream raw materials:

lithium propanoate

acrylic acid anhydride

Refernces

• 1、 Knopf, Ioana,Courtemanche, Marc-André,Cummins, Christopher C.. "Cobalt Complexes Supported by cis-Macrocyclic Diphosphines: Synthesis, Reactivity, and Activity toward Coupling Carbon Dioxide and Ethylene". . p. 4834 - 4843. Retrieved 2017.
• 2、 -. "NEW CATALYST COMPOUND AND METHOD FOR SYNTHESIZING ACRLYLATE USING THE SAME". Paragraph 120-0125. . Retrieved 2020/05/20.